[ CAS No. 3739-64-8 ] {[proInfo.proName]}

Name: 3739-64-8|1-(Allyloxy)butane|98%
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SKU: A270792
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Quality Control of [ 3739-64-8 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

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Product Details of [ 3739-64-8 ]

CAS No. :	3739-64-8	MDL No. :	MFCD00009460
Formula :	C₇H₁₄O	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	IBTLFDCPAJLATQ-UHFFFAOYSA-N
M.W :	114.19	Pubchem ID :	77332
Synonyms :

Safety of [ 3739-64-8 ]

Signal Word:	Danger	Class:	3
Precautionary Statements:	P501-P240-P210-P233-P243-P241-P242-P264-P280-P370+P378-P337+P313-P305+P351+P338-P362+P364-P303+P361+P353-P332+P313-P403+P235	UN#:	3271
Hazard Statements:	H315-H319-H225	Packing Group:	Ⅱ
GHS Pictogram:

Application In Synthesis of [ 3739-64-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 3739-64-8 ]

[ 3739-64-8 ] Synthesis Path-Downstream 1~88

1
[ 107-18-6 ]
[ 71-36-3 ]
[ 3739-64-8 ]

Reference： [1]Applied Organometallic Chemistry,2011,vol. 25,p. 212 - 219
[2]Journal of Organic Chemistry,1958,vol. 23,p. 1666
[3]Justus Liebigs Annalen der Chemie,1951,vol. 572,p. 23,56

2
[ 106-95-6 ]
[ 2372-45-4 ]
[ 3739-64-8 ]

Reference： [1]Journal of the American Chemical Society,1951,vol. 73,p. 3528

3
[ 557-40-4 ]
[ 71-36-3 ]
[ 3739-64-8 ]

Reference： [1]Applied Organometallic Chemistry,2011,vol. 25,p. 212 - 219
[2]Patent: US2847478,1956,A

4
[ 3739-64-8 ]
[ 29043-89-8 ]

Reference： [1]Chemical Communications,2015,vol. 51,p. 5456 - 5459
[2]Synthesis,1979,p. 202 - 204

5
[ 106-95-6 ]
[ 71-36-3 ]
[ 3739-64-8 ]

Reference： [1]Journal of applied chemistry of the USSR,1982,vol. 55,p. 1050 - 1053
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation),1982,vol. 55,p. 1135 - 1138
[2]Synthesis,1979,p. 202 - 204

6
[ 107-05-1 ]
[ 71-36-3 ]
[ 3739-64-8 ]

Yield	Reaction Conditions	Operation in experiment
73.2%	With sodium butanolate; at 95 - 105℃; for 4h;	After stirring apparatus equipped with a dropping funnel, a thermometer and a reflux condenser 1000ml flask placed in a water bath, was added butanol 500g, with stirring, a solution of sodium n-butoxide 190g, until complete dissolution of sodium n-butoxide, control of the reaction temperature between 95 ~ 105C , uniform solution of allyl chloride 115g, the addition was complete within 1 hour incubation stirring for 3 hours after sampling, by gas chromatography, when allyl chloride content is less than 0.3% for the end of the reaction.The reaction was heated to distill, wherein the separated sodium chloride produced by the reaction and small amounts of incomplete reaction of solid sodium butoxide, the butanol distilled off and allyl butyl ether mixture and then fractionating distillation column, when the tower when the top temperature is higher than 118 , distillation is completed, no distillate was cooled to room temperature after the recovery of butanol can be used as re-used in the next reaction; distillate was washed with water, remove the alcohol, and then drying agent after the content was greater than 98% allyl butyl ether finished 126g, yield 73.2%.

Reference： [1]Tetrahedron,1988,vol. 44,p. 6677 - 6680
[2]Organic Preparations and Procedures International,1998,vol. 30,p. 427 - 432
[3]Patent: CN105399610,2016,A .Location in patent: Paragraph 0062-0064
[4]Journal of Organic Chemistry,1961,vol. 26,p. 1389 - 1394

7
[ 67-56-1 ]
[ 3739-64-8 ]
[ 6044-68-4 ]
[ 106521-18-0 ]

Reference： [1]Tetrahedron,1987,vol. 43,p. 5797 - 5806

8
[ 3739-64-8 ]
trans-chrotonyl chloride [ No CAS ]
[ 591-63-9 ]
[ 55409-19-3 ]

Reference： [1]Tetrahedron,1991,vol. 47,p. 3155 - 3170

9
[ 3739-64-8 ]
[ 760-32-7 ]
[ 201230-82-2 ]
(E)-4-Butoxy-1-(diethyl-methyl-silanyl)-1-(diethyl-methyl-silanyloxy)-but-1-ene [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1992,vol. 114,p. 9710 - 9711

10
[ 3739-64-8 ]
[ 17094-21-2 ]
[ 95151-37-4 ]

Reference： [1]Journal of Organometallic Chemistry,1989,vol. 359,p. 139 - 142

11
[ 3739-64-8 ]
[ 1950-78-3 ]
[ 139450-02-5 ]

Reference： [1]Tetrahedron,1991,vol. 47,p. 9463 - 9488

12
[ 3739-64-8 ]
C₅H₉Mg^(1-) [ No CAS ]
[ 6443-93-2 ]

Reference： [1]Journal of Organic Chemistry USSR (English Translation),1985,vol. 21,p. 230 - 235
Zhurnal Organicheskoi Khimii,1985,vol. 21,p. 259 - 265

13
[ 3739-64-8 ]
C₁₅H₂₅Mg^(1-) [ No CAS ]
[ 98238-60-9 ]

Reference： [1]Journal of Organic Chemistry USSR (English Translation),1985,vol. 21,p. 230 - 235
Zhurnal Organicheskoi Khimii,1985,vol. 21,p. 259 - 265

14
[ 3739-64-8 ]
[ 2426-08-6 ]

Yield	Reaction Conditions	Operation in experiment
	With dihydrogen peroxide;[(tmtacn)MnIV(μ-O)3MnIV(tmtacn)](CH3COO)2; In water; at 5℃; for 2.8h;Aqueous oxalate buffer;	Example 1 Catalytic epoxidation of <strong>[3739-64-8]allyl n-butyl ether</strong> can be carried out with [(TmTacn)2 Μη^μ- 0)3]2+(CH3COO")2 as catalyst at 5C in a four necked glass reactor facilitated with a mechanical stirrer, cooling jacket and a bottom valve.The ratio of catalyst: co-catalysts can be 1 : 60. Thus, about 23 μιηο of catalyst can be added in 100 mL of water followed by the addition of 0.675 mmol of sodium oxalate and 0.675 mmol of oxalic acid into the glass reactor under stirring conditions. The reaction can be initiated with the addition of dilute H202 as oxidant. Total 300 mmol of oxidant should be added, for instance with a flow rate of 10 mL/h into the reaction solution. Dosing of oxidant can be completed within the first 2.8 h and the reaction can be continued for a short period thereafter. After the reaction the aqueous solution in the reactor may be analyzed to determine the residual level of H202. The unreacted hydrogen peroxide in the reactor can be killed with Na2S03. Then the aqueous and organic solution in the reactor can be analyzed by GC to determine the amount of epoxidation of the reaction.

Reference： [1]Catalysis Today,2012,vol. 185,p. 157 - 161
[2]Recueil des Travaux Chimiques des Pays-Bas,1991,vol. 110,p. 167 - 170
[3]Agricultural and Biological Chemistry,1988,vol. 52,p. 2911 - 2918
[4]Advanced Synthesis and Catalysis,2003,vol. 345,p. 389 - 392
[5]Chemistry - A European Journal,2011,vol. 17,p. 7549 - 7559
[6]Patent: WO2011/95293,2011,A1 .Location in patent: Page/Page column 14
[7]Advanced Synthesis and Catalysis,2014,vol. 356,p. 3443 - 3450
[8]Organic Letters,2019,vol. 21,p. 10115 - 10119

15
[ 3739-64-8 ]
[ 187737-37-7 ]
[ 15921-15-0 ]

Reference： [1]Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie,1986,vol. 41,p. 455 - 466

16
[ 3739-64-8 ]
1-(prop-1-en-1-yloxy)butane [ No CAS ]
1-(prop-1-en-1-yloxy)butane [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); at 100℃; for 3h;Inert atmosphere;	General procedure: O-Allyl substrate was heated with catalyst ([RuClH(CO)(PPh3)3] or [RuH2(CO)(PPh3)3]) and solvent (if used) under argon atmosphere in screw-capped ampoules, under predetermined temperature (+/-0.1 C), within appropriate time, with intense stirring on a magnetic plate. Reaction time, temperature and the proportions of the substrate, the catalyst and the solvent are presented in Table 1. After removal of the solvent (if used) on a rotary evaporator, the obtained dipolarophile ROCHCHCH3 was used in the cycloaddition without removal of [Ru].
	With ruthenium(II)(2,5-norbornadiene)Cl2; tris(2-methoxyethoxy)silane; In neat (no solvent); at 60℃; for 1h;Inert atmosphere;	General procedure: A 6 mL screw vial equipped with a magnetic stir bar was charged with CH2=CHCH2(OCH2CH2)2OMe (1a) (80 mg, 0.50 mmol), [RuCl2(nbd)]n (1.3 mg, 0.0050 mmol/M), and HSi(OMe)3 (2a) (61 mg, 0.50 mmol) were sequentially added to the solution. The reaction mixture was stirred at 60 C for 1 h. After reaction, mesitylene (60 mg, 0.5 mmol) was added to the mixture and the NMR yields of >99% for 3a was determined based on the integral intensity of the signal at 1.80 ppm (the SiCH2 group). The resulting mixture was filtered with a syringe filter (PTFE, 0.2 m), and all the volatiles were removed under vacuum to afford 3a as a colorless oil (134 mg, 0.47 mmol, 95%).

Reference： [1]Tetrahedron Letters,1987,vol. 28,p. 3249 - 3252
[2]Journal of the Chemical Society. Chemical communications,1980,p. 980 - 981
[3]Tetrahedron,2012,vol. 68,p. 6018 - 6031
[4]Tetrahedron Letters,2019,vol. 60

17
[ 3739-64-8 ]
[ 1471-15-4 ]
(R)-3-(Butoxy)-1,2-epoxypropane [ No CAS ]
[ 121906-41-0 ]

Yield	Reaction Conditions	Operation in experiment
	With oxygen at 30℃; for 12h; P₁ medium for bacteria growth; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

Reference： [1]Fu, Hong; Shen, Gwo-Jenn; Wong, Chi-Huey [Recueil des Travaux Chimiques des Pays-Bas, 1991, vol. 110, # 5, p. 167 - 170]

18
[ 3739-64-8 ]
[ 98-88-4 ]
[ 136-60-7 ]

Reference： [1]Chemistry Letters,1987,p. 953 - 956

19
[ 3739-64-8 ]
[ 98-88-4 ]
[ 136-60-7 ]
[ 134-81-6 ]

Reference： [1]Tetrahedron,1991,vol. 47,p. 3155 - 3170

20
[ 3739-64-8 ]
[ 75-36-5 ]
[ 123-86-4 ]

Reference： [1]Chemistry Letters,1987,p. 953 - 956

21
[ 3739-64-8 ]
[ 75-36-5 ]
[ 123-86-4 ]
[ 431-03-8 ]

Reference： [1]Tetrahedron,1991,vol. 47,p. 3155 - 3170

22
[ 109-65-9 ]
[ 107-18-6 ]
[ 3739-64-8 ]

Reference： [1]Journal of Organic Chemistry USSR (English Translation),1991,vol. 27,p. 1398 - 1402
Zhurnal Organicheskoi Khimii,1991,vol. 27,p. 1600 - 1604

23
[ 3739-64-8 ]
[ 7605-28-9 ]
[ 125263-27-6 ]
2-allyl-2-benzenesulfonyl-4-pentenonitrile [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1989,vol. 359,p. 139 - 142

24
[ 3739-64-8 ]
[ 557-18-6 ]
C₁₁H₂₄MgO [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,1985,vol. 285,p. 43 - 52

25
[ 3739-64-8 ]
[ 13641-16-2 ]
4-Butoxymethyl-1-methyl-1,2,3,4-tetrahydro-quinoline [ No CAS ]

Reference： [1]Journal of the Chemical Society. Chemical communications,1995,p. 2137 - 2138

26
[ 3739-64-8 ]
[ 75-61-6 ]
[ 182154-53-6 ]

Reference： [1]Journal of Organic Chemistry,1996,vol. 61,p. 6252 - 6255

27
[ 3739-64-8 ]
[ 75-25-2 ]
1,1-Dibromo-2-butoxymethyl-cyclopropane [ No CAS ]

Reference： [1]Helvetica Chimica Acta,1997,vol. 80,p. 2486 - 2501

28
[ 3739-64-8 ]
[ 23418-85-1 ]
(Z)-toluene-4-sulfonic acid 6-butoxy-3-methylene-hex-4-enyl ester [ No CAS ]
(E)-toluene-4-sulfonic acid 6-butoxy-3-methylene-hex-4-enyl ester [ No CAS ]

Reference： [1]Organic Letters,2003,vol. 5,p. 1855 - 1858

29
[ 3739-64-8 ]
[ 88159-06-2 ]
(Z)-(5-butoxy-2-methylene-pent-3-enyloxy)-tert-butyl-diphenyl-silane [ No CAS ]
(E)-(5-butoxy-2-methylene-pent-3-enyloxy)-tert-butyl-diphenyl-silane [ No CAS ]

Reference： [1]Organic Letters,2003,vol. 5,p. 1855 - 1858

30
[ 3739-64-8 ]
[ 100-51-6 ]
[(1-butoxypropoxy)methyl]benzene [ No CAS ]

Reference： [1]Synlett,2004,p. 1203 - 1206
[2]Monatshefte fur Chemie,2011,vol. 142,p. 1241 - 1247

31
[ 591-87-7 ]
[ 71-36-3 ]
[ 3739-64-8 ]

Reference： [1]Journal of Organic Chemistry,2004,vol. 69,p. 3474 - 3477

32
[ 104-92-7 ]
[ 3739-64-8 ]
(E)-3-butoxy-1-(4-methoxyphenyl)propene [ No CAS ]
1-((Z)-3-Butoxy-allyl)-4-methoxy-benzene [ No CAS ]
1-((E)-3-Butoxy-allyl)-4-methoxy-benzene [ No CAS ]
1-(1-butoxymethyl-vinyl)-4-methoxy-benzene [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2005,p. 1367 - 1377

33
[ 3739-64-8 ]
[ 3972-65-4 ]
1-(3-butoxy-allyl)-4-tert-butyl-benzene [ No CAS ]
1-(3-butoxy-allyl)-4-tert-butyl-benzene [ No CAS ]
(E)-3-butoxy-1-(4-tert-butylphenyl)propene [ No CAS ]
1-(1-butoxymethyl-vinyl)-4-tert-butyl-benzene [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2005,p. 1367 - 1377

34
[ 3739-64-8 ]
[ 576-83-0 ]
1-((Z)-3-Butoxy-allyl)-4-methoxy-benzene [ No CAS ]
1-((E)-3-Butoxy-allyl)-4-methoxy-benzene [ No CAS ]
1-(1-butoxymethyl-vinyl)-4-methoxy-benzene [ No CAS ]
(E)-3-butoxy-1-(2,4,6-trimethylphenyl)propene [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2005,p. 1367 - 1377

35
[ 3739-64-8 ]
[ 99-90-1 ]
1-[4-((Z)-3-Butoxy-allyl)-phenyl]-ethanone [ No CAS ]
1-[4-((E)-3-Butoxy-allyl)-phenyl]-ethanone [ No CAS ]
(E)-1-(4-acetylphenyl)-3-butoxypropene [ No CAS ]
1-[4-(1-butoxymethyl-vinyl)-phenyl]-ethanone [ No CAS ]

Reference： [1]European Journal of Organic Chemistry,2005,p. 1367 - 1377

36
[ 3739-64-8 ]
[ 124-70-9 ]
((E)-3-Butoxy-propenyl)-dichloro-methyl-silane [ No CAS ]

Reference： [1]Journal of Organometallic Chemistry,2005,vol. 690,p. 5912 - 5921

37
[ 3739-64-8 ]
[ 603133-20-6 ]
3-((E)-2-Chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid butyl ester [ No CAS ]

Reference： [1]Tetrahedron Letters,2005,vol. 46,p. 8493 - 8495

38
[ 3739-64-8 ]
[ 874-60-2 ]
[ 19277-56-6 ]

Reference： [1]Tetrahedron Letters,2005,vol. 46,p. 8493 - 8495

39
[ 3739-64-8 ]
[ 60-12-8 ]
[ 7748-07-4 ]
[2-(1-butoxy-propoxy)-ethyl]-benzene [ No CAS ]

Reference： [1]Tetrahedron Letters,2007,vol. 48,p. 137 - 140

40
[ 3739-64-8 ]
[ 108-95-2 ]
1-n-butoxy-1-phenoxypropane [ No CAS ]

Reference： [1]Tetrahedron Letters,2007,vol. 48,p. 137 - 140

41
[ 104-53-0 ]
[ 3739-64-8 ]
[ 60340-28-5 ]