[ CAS No. 341556-86-3 ] {[proInfo.proName]}

Name: 341556-86-3|(2E,2'E)-3,3'-(Anthracene-9,10-diyl)diacrylic acid|97%
Brand: Ambeed
SKU: A299388
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2D 3D

Structure of 341556-86-3 * Storage: {[proInfo.prStorage]}

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Quality Control of [ 341556-86-3 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 341556-86-3 ]

Product Details of [ 341556-86-3 ]

CAS No. :	341556-86-3	MDL No. :	MFCD06205370
Formula :	C₂₀H₁₄O₄	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	QGJNKGPCTYCXLD-WGDLNXRISA-N
M.W :	318.32	Pubchem ID :	10734306
Synonyms :

Safety of [ 341556-86-3 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P264-P271-P273-P280-P302+P352-P304+P340+P312-P305+P351+P338-P332+P313-P337+P313-P403+P233-P405-P501	UN#:
Hazard Statements:	H315-H319-H335-H413	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 341556-86-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 341556-86-3 ]

[ 341556-86-3 ] Synthesis Path-Downstream 1~10

1
[ 108366-06-9 ]
[ 341556-86-3 ]

Yield	Reaction Conditions	Operation in experiment
96%	With potassium hydroxide In ethanol for 1h; Heating;
		R.18 Reference Example 18 STR68 In a similar manner, 161 mg (96%) of 3,3'-(9,10-anthracenediyl)diacrylic acid was obtained from 200 mg (0.53 mmol) of ethyl 3,3'-(9,10-anthracenediyl)diacrylate. Melting point 310.5°-319.0° C. (decomposed) High resolution mass spectrum as C20 H14 O4; Calculated: 318.0892; Found: 318.0915

Reference： [1]Fukuda; Seto; Furuta; Ebisu; Oomori; Terashima [Journal of Medicinal Chemistry, 2001, vol. 44, # 9, p. 1396 - 1406]
[2]Current Patent Assignee: KYORIN HOLDINGS, INC.; SAGAMI CHEMICAL RESEARCH INSTITUTE - US5786486, 1998, A

2
(S)-8-Chloromethyl-4-hydroxy-2-trifluoromethyl-3,6,7,8-tetrahydro-pyrrolo[3,2-e]indole-1-carboxylic acid methyl ester; hydrochloride [ No CAS ]
[ 341556-86-3 ]
C₄₈H₃₄Cl₂F₆N₄O₈ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
25%	With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃;

Reference： [1]Fukuda; Seto; Furuta; Ebisu; Oomori; Terashima [Journal of Medicinal Chemistry, 2001, vol. 44, # 9, p. 1396 - 1406]

3
[ 523-27-3 ]
[ 341556-86-3 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 94 percent / Et₃N; 1,3-(diphenylphosphino)propane; Pd(OAc)2 / dimethylformamide / 10 h / 100 °C 2: 96 percent / KOH / ethanol / 1 h / Heating

Reference： [1]Fukuda; Seto; Furuta; Ebisu; Oomori; Terashima [Journal of Medicinal Chemistry, 2001, vol. 44, # 9, p. 1396 - 1406]

Yield	Reaction Conditions	Operation in experiment
		2 Example 2 STR30 To 13.5 mg (30 μmol) of methyl (S)-3-t-butoxycarbonyl-1-chloromethyl-5-hydroxy-7-trifluoromethyl-1,2,3,6-tetrahydropyrrolo[3,2-e]indole-8-carboxylate, was added 0.43 mL of 3M hydrogen chloride-ethyl acetate. The mixture was stirred at room temperature for 2 hours. Then the solvent was removed by distillation. The resulting residue was stirred with 4.8 mg (15 μmol) of 3,3'-(9,10-anthracenediyl)diacrylic acid and 17.3 mg (90 μmol) of 1-(3-dimethylaminopropyl) -3-ethylcarbodiimide hydrochloride in 0.3 mL of anhydrous dimethylformamide under an argon stream overnight. Water was added to the reaction mixture, and the resulting precipitate was purified by silica gel column chromatography (tetrahydrofuran:chloroform=2:1) to obtain 3.7 mg (25%) of (S,S)-3,3'-[3,3'-(9,10-anthracenediyl)diacryloyl]-bis›1-chloromethyl-5-hydroxy-7-trifluoromethyl-1,2,3,6-tetrahydropyrrolo [3,2-e]indole-8-methoxycarbonyl! in a yellow crystal state. [α]D29 =-144° (c=0.20, tetrahydrofuran); NMR (DMSO d6) δ: 3.56(2H,t,J=10 Hz), 3.79-3.85(2H,m), 3.87(6H,s), 4.22-4.29(2H,m), 4.33-4.47(4H,m), 7.05(2H,d,J=16 H) z), 7,66(4H,dd,J=4 and 7 Hz), 8.22(2H,s), 8.37(4H,dd,J=7 and 4 Hz), 8.55(2H,d,J=16 Hz), 10.64(2H,s), 13.11(2H,s).

5
(2E,2'E)-dimethyl 3,3'-(anthracene-9,10-diyl)diacrylate [ No CAS ]
[ 341556-86-3 ]

Yield	Reaction Conditions	Operation in experiment
65.4%	With water In tetrahydrofuran; methanol at 60℃; Alkaline conditions;

Reference： [1]Wang, Rongming; Liu, Xiaobin; Huang, Ao; Wang, Wen; Xiao, Zhenyu; Zhang, Liangliang; Dai, Fangna; Sun, Daofeng [Inorganic Chemistry, 2016, vol. 55, # 4, p. 1782 - 1787]

6
barium(II) nitrate [ No CAS ]
[ 64-17-5 ]
[ 7732-18-5 ]
[ 33513-42-7 ]
[ 341556-86-3 ]
5C₂₀H₁₂O₄^(2-)*5Ba⁽²⁺⁾*2C₂H₆O*3H₂O*5C₃H₇NO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	at 30 - 90℃; for 66h; Sealed tube; High pressure;

Reference： [1]Wang, Rongming; Liu, Xiaobin; Huang, Ao; Wang, Wen; Xiao, Zhenyu; Zhang, Liangliang; Dai, Fangna; Sun, Daofeng [Inorganic Chemistry, 2016, vol. 55, # 4, p. 1782 - 1787]

7
[ 33513-42-7 ]
lead(II) chloride [ No CAS ]
[ 341556-86-3 ]
[Pb(adda)(DMF)]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With water In ethanol at 90℃; for 72h; High pressure;	1-2 Example 1 Preparation of crystalline material [Pb(adda)(DMF)]_n Put 0.15mmolPbCl2 and 0.15mmol (2E,2′E)-3,3′-(anthracen-9,10-diyl)diacrylic acid into a glass vial with a capacity of 20mL, Then a mixed solvent of 3 mL DMF, 2 mL ethanol and 1 mL water was added to perform a solvothermal reaction. The reaction temperature was 90° C., and the reaction time was 3 days. After the reaction, it was cooled to room temperature, filtered and washed to obtain yellow-green flake crystals [Pb(adda)(DMF)]n. Through X-ray single crystal diffraction analysis, the crystal was determined to be [Pb(adda)(DMF)]n.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES; MINDU INNOVATION LABORATORY - CN112625061, 2021, A Location in patent: Paragraph 0056-0065

8
lead(II) nitrate [ No CAS ]
[ 33513-42-7 ]
[ 341556-86-3 ]
[Pb(adda)(DMF)]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With water In ethanol at 90℃; for 72h; High pressure;	Example 1 Preparation of crystalline material [Pb(adda)(DMF)]_n General procedure: Put 0.15mmolPbCl2 and 0.15mmol (2E,2′E)-3,3′-(anthracen-9,10-diyl)diacrylic acid into a glass vial with a capacity of 20mL, Then a mixed solvent of 3 mL DMF, 2 mL ethanol and 1 mL water was added to perform a solvothermal reaction. The reaction temperature was 90° C., and the reaction time was 3 days. After the reaction, it was cooled to room temperature, filtered and washed to obtain yellow-green flake crystals [Pb(adda)(DMF)]n. Through X-ray single crystal diffraction analysis, the crystal was determined to be [Pb(adda)(DMF)]n.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES; MINDU INNOVATION LABORATORY - CN112625061, 2021, A Location in patent: Paragraph 0056-0065

9
[ 301-04-2 ]
[ 33513-42-7 ]
[ 341556-86-3 ]
[Pb(adda)(DMF)]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With water In ethanol at 120℃; for 72h; High pressure;	Example 1 Preparation of crystalline material [Pb(adda)(DMF)]_n General procedure: Put 0.15mmolPbCl2 and 0.15mmol (2E,2′E)-3,3′-(anthracen-9,10-diyl)diacrylic acid into a glass vial with a capacity of 20mL, Then a mixed solvent of 3 mL DMF, 2 mL ethanol and 1 mL water was added to perform a solvothermal reaction. The reaction temperature was 90° C., and the reaction time was 3 days. After the reaction, it was cooled to room temperature, filtered and washed to obtain yellow-green flake crystals [Pb(adda)(DMF)]n. Through X-ray single crystal diffraction analysis, the crystal was determined to be [Pb(adda)(DMF)]n.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES; MINDU INNOVATION LABORATORY - CN112625061, 2021, A Location in patent: Paragraph 0056-0065

10
lead(II) bromide [ No CAS ]
[ 33513-42-7 ]
[ 341556-86-3 ]
[Pb(adda)(DMF)]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With water In ethanol at 100℃; for 72h; High pressure;	Example 1 Preparation of crystalline material [Pb(adda)(DMF)]_n General procedure: Put 0.15mmolPbCl2 and 0.15mmol (2E,2′E)-3,3′-(anthracen-9,10-diyl)diacrylic acid into a glass vial with a capacity of 20mL, Then a mixed solvent of 3 mL DMF, 2 mL ethanol and 1 mL water was added to perform a solvothermal reaction. The reaction temperature was 90° C., and the reaction time was 3 days. After the reaction, it was cooled to room temperature, filtered and washed to obtain yellow-green flake crystals [Pb(adda)(DMF)]n. Through X-ray single crystal diffraction analysis, the crystal was determined to be [Pb(adda)(DMF)]n.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES; MINDU INNOVATION LABORATORY - CN112625061, 2021, A Location in patent: Paragraph 0056-0065

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P222	Do not allow contact with air.
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P230	Keep wetted
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P233	Keep container tightly closed.
P234	Keep only in original container.
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Response
Code	Phrase
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P304	IF INHALED:
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P315	Get immediate medical advice/attention.
P320
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P321
P322
P330	Rinse mouth.
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P334	Immerse in cool water/wrap n wet bandages.
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P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
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P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
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P391	Collect spillage. Hazardous to the aquatic environment
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P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 341556-86-3 ] {[proInfo.proName]}

Quality Control of [ 341556-86-3 ]

Related Doc. of [ 341556-86-3 ]

Product Details of [ 341556-86-3 ]

Safety of [ 341556-86-3 ]

Application In Synthesis of [ 341556-86-3 ]

[ 341556-86-3 ] Synthesis Path-Downstream 1~10

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

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