Alternatived Products of [ 32195-55-4 ]
Product Details of [ 32195-55-4 ]
| CAS No. : | 32195-55-4 |
MDL No. : | MFCD00012153 |
| Formula : |
C44H28ClMnN4
|
Boiling Point : |
- |
| Linear Structure Formula : | - |
InChI Key : | MIUMWNDEIWVIEG-UHFFFAOYSA-M |
| M.W : |
703.11
|
Pubchem ID : | 91864721 |
| Synonyms : |
|
Application In Synthesis of [ 32195-55-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 32195-55-4 ]
- 1
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[ 32195-55-4 ]
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[ 71963-77-4 ]
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Acetic acid (1R,3S,4R,4aS,7R,8S,8aR)-8a-hydroxy-3-methoxy-4,7-dimethyl-8-[2-((4Z,10Z,15Z,19Z)-(S)-5,10,15,20-tetraphenyl-2,3,22,24-tetrahydro-porphin-2-yl)-ethyl]-octahydro-isochromen-1-yl ester
[ No CAS ]
- 2
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[ 32195-55-4 ]
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[ 94161-44-1 ]
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[ 76077-77-5 ]
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[ 1119-46-6 ]
- 3
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[ 132-16-1 ]
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[ 56413-47-9 ]
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[ 90-13-1 ]
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[ 34557-72-7 ]
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(μ-nitrido)[((tetraphenylporphyrinato)manganese)((phthalocyaninato)iron)]
[ No CAS ]
- 4
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[ 917-23-7 ]
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manganese(ll) chloride
[ No CAS ]
-
[ 34557-72-7 ]
| Yield | Reaction Conditions | Operation in experiment |
| 80% |
With cadmium(II) chloride; In N,N-dimethyl-formamide; for 0.333333h;Reflux; |
General procedure: a. A mixture of 0.02 g (0.0325 mol) of compound I in 40 mL of DMF and 0.082 g (0.650 mol) of MnCl2 was boiled during 80 min. The mixture was cooled down to ambient, diluted with water, and solid NaCl was added. The precipitate was filtered off, washed with water, and dried. Yield 0.0175 g (0.0249 mmol, 77%), Rf 0.76. b. A mixture of 0.02 g (0.0325 mmol) of compound I and 0.06 g (0.325 mmol) of CdCl2 in 40 mL of DMF was heated to boiling, and then 0.082 g (0.650 mmol) of MnCl2 was added. The mixture was boiled during 20 min and then treated as described in procedure a. Yield 0.018 g (0.0256 mmol, 80%), Rf 0.76. 1H NMR spectrum, delta, ppm: 8.30 br.s (16H, Ho,m, C6H5), 7.75 br.s (4H, Hp, C6H5). Found, %: C 74.95; H 3.94; N 7.88. C44H28ClMnN4. Calculated, %: 75.16; 4.01;N 7.97. (Cl)Mn(III) porphyrinates V and VI were prepared similarly. |
| 68% |
In N,N-dimethyl-formamide;Reflux; |
This precursor wasprepared according to the literature procedure of Feng et al.(2012). TPP (1.0 g, 1.6 mmol) was dissolved in DMF andMnCl2 (3.0 g, 24 mmol) was added. The reaction was refluxedovernight, then stopped and allowed to cool to roomtemperature. Water was added to the reaction mixture and agreen powder was filtered off. The resulting powder wasdissolved in chloroform and washed with 1 M HCl solution(3) and water (2). The resulting organic layer was driedover anhydrous sodium sulfate for 1 h (yield 68%). |
Reference：
[1]Russian Journal of General Chemistry,2015,vol. 85,p. 1132 - 1135
Zh. Obshch. Khim.,2015,vol. 85,p. 838 - 841,4
[2]Acta Crystallographica Section C: Structural Chemistry,2019,vol. 75,p. 304 - 312
[3]Journal of Porphyrins and Phthalocyanines,2016,vol. 20,p. 318 - 330
[4]Chemical Communications,2018,vol. 54,p. 5586 - 5589
- 5
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manganese(II) chloride hexahydrate
[ No CAS ]
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[ 917-23-7 ]
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[ 34557-72-7 ]
| Yield | Reaction Conditions | Operation in experiment |
| 70% |
In N,N-dimethyl-formamide; at 150.0℃; for 1h; |
Meso-tetraphenylporphyrin 1 (0.5 g, 0.813 mmol) was dissolved in 80 mL DMF solution of MnCl2. 6H2O (1.9 g, 8.13 mmol) and refluxed at 150 0C for 1 h. The solvent mixture was removed from the crude product by distillation. It was later dissolved in 50 mL CH2Cl2, washed with distilled water (50 x 3) and dried over anhydrous Na2SO4. The product was purified by column chromatography using Al2O3 with CH2Cl2/methanol (95:5 V: V) as the eluent and dried under vacuum for 2-3 h. The yield found was 70 % (0.40 g). |
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