* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Reference:
[1] Journal of the Chemical Society, Dalton Transactions, 2000, # 16, p. 2817 - 2822
[2] Journal of Heterocyclic Chemistry, 1991, vol. 28, # 1, p. 7 - 11
[3] Chemistry - A European Journal, 2016, vol. 22, # 8, p. 2682 - 2690
2
[ 3248-05-3 ]
[ 31301-31-2 ]
Reference:
[1] Journal of the Chemical Society, Dalton Transactions, 2000, # 16, p. 2817 - 2822
[2] European Journal of Inorganic Chemistry, 2009, # 9, p. 1256 - 1267
[cis-{bis(2,2'-bipyridin-5-yl)ethyne}tetrakis(4,7-dicarboxy-1,10-phenanthroline)tetrakis(thiocyanato)]ruthenium(II)[ No CAS ]
Yield
Reaction Conditions
Operation in experiment
88%
General procedure: dichloro(p-cymene)ruthenium(II) dimer (122.4 mg,0.20 mmol) and 66.8 mg 5-(2-[2,2'-bipyridin]-5-ylethynyl)-2,2'-bipyridine (0.20 mmol) were dissolved in 50 mm3 of DMF under nitrogen gas. The solution was heated at 80C with vigorous stirring for 4 h in the dark under a nitrogen atmosphere.The ligand (0.40 mmol, L = 4,4'-dicarboxy-2,2'-bipyridine, 4,4'-bis(E-carboxyvinyl)-2,2'-bipyridine, <strong>[31301-31-2]4,7-dicarboxy-1,10-phenanthroline</strong>, or 4,7-bis(E-carboxyvinyl)-1,10-phenanthroline) was then added and the solution was heated at 140C for 4 h.NH4NCS(121.8 mg, 1.60 mmol)was then added, and the resulting mixture was heated at 140C for an additional 4 h. After the evaporation of DMF, the resulting residue was suspended in water, filtered under suction, and dried. accordingly, the acid form of ruthenium complexes was obtained.