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[ CAS No. 2648079-79-0 ]

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Cat. No.: {[proInfo.prAm]}
2D
Chemical Structure| 2648079-79-0
Chemical Structure| 2648079-79-0
Structure of 2648079-79-0 *Storage: {[proInfo.prStorage]}
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Quality Control of [ 2648079-79-0 ]

Related Doc. of [ 2648079-79-0 ]

SDS
Alternatived Products of [ 2648079-79-0 ]
Alternatived Products of [ 2648079-79-0 ]

Product Details of [ 2648079-79-0 ]

CAS No. :2648079-79-0MDL No. :N/A
Formula : C14H8F6O3S3 Boiling Point : -
Linear Structure Formula :-InChI Key :N/A
M.W :434.39Pubchem ID :-
Synonyms :

Computed Properties of [ 2648079-79-0 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 2648079-79-0 ]

Signal Word:WarningClass:N/A
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340+P312-P305+P351+P338-P332+P313-P337+P313-P403+P233-P405-P501UN#:N/A
Hazard Statements:H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 2648079-79-0 ]

  • Downstream synthetic route of [ 2648079-79-0 ]

[ 2648079-79-0 ] Synthesis Path-Downstream   1~10

  • 1
  • [ 1945-84-2 ]
  • [ 873-55-2 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-2-(3,3,3-trifluoro-1-(phenylsulfonyl)prop-1-en-1-yl)pyridine [ No CAS ]
YieldReaction ConditionsOperation in experiment
35% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
  • 2
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-4-(2-(4-((1-(4-acetylphenyl)-3,3,3-trifluoroprop-1-en-1-yl)sulfonyl)phenoxy)ethyl)morpho-lin-4-ium [ No CAS ]
  • 3
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-1-(3-(4-((1-(4-acetylphenyl)-3,3,3-trifluoroprop-1-en-1-yl)sulfonyl)phenoxy)propyl)-4-methylpiperazin-1-ium chloride [ No CAS ]
  • 4
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • C23H24F3NO5S*ClH [ No CAS ]
  • 5
  • [ 42472-69-5 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • sodium p-iodobenzenesulfinate [ No CAS ]
  • (E)-1-(4-(3,3,3-trifluoro-1-((4-iodophenyl)sulfonyl)prop-1-en-1-yl)phenyl)ethan-1-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
20% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
  • 6
  • [ 42472-69-5 ]
  • [ 34176-08-4 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-1-(4-(1-((4-bromophenyl)sulfonyl)-3,3,3-trifluoroprop-1-en-1-yl)phenyl)ethan-1-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
29% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
  • 7
  • [ 42472-69-5 ]
  • [ 14752-66-0 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-1-(4-(1-((4-chlorophenyl)sulfonyl)-3,3,3-trifluoroprop-1-en-1-yl)phenyl)ethan-1-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
48% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
  • 8
  • [ 42472-69-5 ]
  • [ 824-80-6 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-1-(4-(3,3,3-trifluoro-1-((4-fluorophenyl)sulfonyl)prop-1-en-1-yl)phenyl)ethan-1-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
88% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
  • 9
  • [ 42472-69-5 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • [ 824-79-3 ]
  • (E)-1-(4-(3,3,3-trifluoro-1-tosylprop-1-en-1-yl)phenyl)ethan-1-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
84% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
  • 10
  • [ 42472-69-5 ]
  • [ 873-55-2 ]
  • S-(trifluoromethyl)thianthrenium triflate [ No CAS ]
  • (E)-1-(4-(3,3,3-trifluoro-1-(phenylsulfonyl)prop-1-en-1-yl)phenyl)ethan-1-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
74% In dimethyl sulfoxide; at 25℃; for 12h;Inert atmosphere; General procedure: To a test tube was added 1-(4-ethynylphenyl)ethan-1-one 1(0.2 mmol, 1.0 equiv.), trifluoromethyl thianthrenium triflate 2(0.4 mmol, 2.0 equiv.) and sodium sulfinate 3 (0.4 mmol, 2.0 equiv.).Then the tube was purged with argon for 3 times. DMSO (2.0 mL)was added by a syringe and the tube was stirred at 25 C for 12 h.After the scheduled time, the mixture was quenched with waterand extracted with EtOAc (20 mL * 3). The combined organic phaseswere washed with brine and dried over anhydrous Na2SO4. The solvent was then evaporated under reduced pressure and the residuewas purified directly by flash column chromatography toafford the corresponding product 4 as white solids.
Historical Records

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[ 2648079-79-0 ]

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