Name: 220593-43-1|1,1,1-[(2,4,6-Trimethyl-1,3,5-benzenetriyl)tris(methylene)]tris[1H -imidazole]|98%
Brand: Ambeed
SKU: A1154747
Rating: 93 (40 reviews)

1
[ 288-32-4 ]
[ 21988-87-4 ]
[ 220593-43-1 ]

Yield	Reaction Conditions	Operation in experiment
92%	Stage #1: 1H-imidazole With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.5h; Stage #2: 1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene In N,N-dimethyl-formamide at 20℃; for 20h;
64%	Stage #1: 1H-imidazole With sodium hydroxide In acetonitrile at 20℃; for 2h; Stage #2: 1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene In acetonitrile at 50 - 60℃; for 24h;	4.3.2. Synthesis of 1,3,5-Tris(imidazole-1-yl-methyl)-2,4,6-trimethylbenzene (A) To a mixture of imidazole (874 mg, 12.8 mmol) in acetonitrile (50 mL), in a 100 mL round-bottomedflask, NaOH (1.029 g, 25.72 mmol) was added and stirred at room temperature for two hours.1,3,5-Tris(bromomethyl)-2,4,6-trimethylbenzene (1.416 g, 4.000 mmol) in acetonitrile (20 mL) wasadded to the reaction mixture and refluxed for 24 h at 50-60 °C. The reaction mixture was monitoredwith TLC and after completion, the solvent was removed by rotary evaporation, the residue wasdissolved in water (100 mL) and extracted with methylene chloride (30 mL 5). The organic layerswere combined, dried over anhydrous MgSO4, filtered and purified by flash column chromatography(CH2Cl2/MeOH = 5/1) to give the desired product as a white solid. Recrystallization in ethyl acetateproduced clear block like crystals 64% yield. mp 214-215 °C (Lit value 226-227 °C) [31]; 1H-NMR(δH; CDCl3, 400 MHz) δ 7.31 (s, 3H), 7.07 (s, 3H), 6.75 (s, 3H), 5.24 (s, 6H) 2.32 (s, 9H).
	In N,N-dimethyl-formamide

Reference： [1]Yuan; Jiang; Yan; Gao; Chan; Xie [Synthetic Communications, 2000, vol. 30, # 24, p. 4555 - 4561]
[2]Andree, Stefan N. L.; Sinha, Abhijeet S.; Aaker y, Christer B. [Molecules, 2018, vol. 23, # 1]
[3]Baker, Murray V.; Bosnich, Mark J.; Williams, Charlotte C.; Skelton, Brian W.; White, Allan H. [Australian Journal of Chemistry, 1999, vol. 52, # 9, p. 823 - 825]

2
[ 21988-87-4 ]
[ 220593-43-1 ]
2,11,13,21,29,31-hexamethyl-5,16,24-triaza-8,19,27-triazaniumheptacyclo[10.10.6.1^1,3.1^5,8.1^10,14.1^16,19.1^24,27]tritriaconta-1,3⁽²⁹⁾,6,8⁽³⁰⁾,10,12,14⁽³¹⁾,17,19⁽³²⁾,21,25,27⁽³³⁾-dodecene tribromide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
91%	In acetonitrile at 68℃; for 96h;
87%	In acetone at 25℃; for 168000h;

Reference： [1]Yuan; Jiang; Yan; Gao; Chan; Xie [Synthetic Communications, 2000, vol. 30, # 24, p. 4555 - 4561]
[2]Baker, Murray V.; Bosnich, Mark J.; Williams, Charlotte C.; Skelton, Brian W.; White, Allan H. [Australian Journal of Chemistry, 1999, vol. 52, # 9, p. 823 - 825]

3
[ 220593-43-1 ]
[ 74-88-4 ]
1,3,5-tris(N-(N'-methyl)imidazolimmethyl)-2,4,6-trimethylbenzene iodide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%

Reference： [1]Gao, Ge; Xiao, Rong; Yuan, Yi; Zhou, Cheng-He; You, Jingsong; Xie, Ru-Gang [Journal of Chemical Research - Part S, 2002, # 6, p. 262 - 263]

4
[ 220593-43-1 ]
[ 626-15-3 ]
C₂₉H₃₂N₆⁽²⁺⁾*2Br^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile for 35h; Heating;

Reference： [1]Yuan, Yi; Gao, Ge; Jiang, Zong-Lin; You, Jin-Song; Zhou, Zhong-Yuan; Yuan, De-Qi; Xie, Ru-Gang [Tetrahedron, 2002, vol. 58, # 44, p. 8993 - 8999]

5
copper(II) perchlorate hexahydrate [ No CAS ]
[ 111-40-0 ]
[ 220593-43-1 ]
[(Cu₃(diethylenetriamine)3(1,3,5-tris(imidazol-1-yl)methyl-2,4,6-trimethylbenzene))(ClO₄)6(CH₃CN)0.5(H₂O)0.25]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
54%	In water; acetonitrile addn. of ligand (in MeCN/water=9:1) to mixt. of Cu-salt and triamine (inMeCN) with stirring, stirring for 5 min at room temp.; filtration, crystn. on Et2O diffusion;

Reference： [1]Liu, Hong-Ke; Sun, Wei-Yin; Zhu, Hai-Liang; Yu, Kai-Bei; Tang, Wen-Xia [Inorganica Chimica Acta, 1999, vol. 295, # 2, p. 129 - 135]

6
[Cu(diethylenetriamine)(imidazole)](ClO₄)2 [ No CAS ]
[ 220593-43-1 ]
[(Cu₃(diethylenetriamine)3(1,3,5-tris(imidazol-1-yl)methyl-2,4,6-trimethylbenzene))(ClO₄)6(CH₃CN)0.5(H₂O)0.25]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61%	In water; acetonitrile addn. of ligand (in MeCN/water=9:1) to Cu-complex (in MeCN) with stirring, stirring for 5 min at room temp.; filtration, crystn. on Et2O diffusion; elem. anal.;

Reference： [1]Liu, Hong-Ke; Sun, Wei-Yin; Zhu, Hai-Liang; Yu, Kai-Bei; Tang, Wen-Xia [Inorganica Chimica Acta, 1999, vol. 295, # 2, p. 129 - 135]

7
bis(acetonitrile)palladium(II) dichloride [ No CAS ]
[ 7732-18-5 ]
[ 220593-43-1 ]
Pd₆(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)8Cl₁₂*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
41%	In water; acetonitrile soln of ligand in 1:1 CH3CN-H2O mixt. added to soln. of Pd-complex in CH3CN at room temp., stirred for 1 h; mixt. filtered, filtrate stand at ambient temp. for a month; elem. anal.;

Reference： [1]Liu, Hong-Ke; Tong, Xiaojun [Chemical Communications, 2002, # 12, p. 1316 - 1317]

8
[ 142-71-2 ]
[ 220593-43-1 ]
[Cu₃(1,3,5-tris(imidazol-1-ylmethyl)2,4,6-trimethylbenzene)2(OCOCH₃)6] * H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol 2 equiv. of ligand; elem. anal.;

Reference： [1]Liu, Hong-Ke; Sun, Wei-Yin; Tang, Wen-Xia; Yamamoto, Tetsuo; Ueyama, Norikazu [Inorganic Chemistry, 1999, vol. 38, # 26, p. 6313 - 6316]

9
Ag⁽¹⁺⁾*2NH₃*N₃^(1-)=Ag(NH₃)2N₃ [ No CAS ]
[ 7732-18-5 ]
[ 220593-43-1 ]
[ 493000-48-9 ]

Yield	Reaction Conditions	Operation in experiment
47%	In water; acetonitrile soln. ligand in MeCN was layered over aq. soln. Ag(NH3)2N3; crystals were filtered; elem. anal.;

Reference： [1]Fan, Jian; Zhu, Hui-Fang; Okamura, Taka-Aki; Sun, Wei-Yin; Tang, Wen-Xia; Ueyama, Norikazu [Inorganic Chemistry, 2003, vol. 42, # 1, p. 158 - 162]

10
[ 7732-18-5 ]
[ 142-71-2 ]
[ 220593-43-1 ]
[Cu₃(1,3,5-tris(imidazol-1-ylmethyl)2,4,6-trimethylbenzene)2(OCOCH₃)6] * H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol by spontaneous assembly from (C(CH3)C(CH2(NCHN(CH)2)))3 ligand and copper(II) acetate in methanol soln.; according to H.-K. Liu, W.-Y. Sun, W.-X. Tang, T. Yamamoto, Ueyama, Inorg. Chem. 38(1999) 6313;

Reference： [1]Honda, Zentaro; Katsumata, Koichi; Yamada, Koji [Physica B: Condensed Matter, 2003, vol. 329-333, # II, p. 1032 - 1033]

11
[ 5970-45-6 ]
[ 220593-43-1 ]
[Zn(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(acetate)](OH)*8.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
30%	In ethanol EtOH soln. Zn(OAc)2*2H2O was added slowly to soln. ligand in EtOH and stirred for 5 h at room temp.; elem. anal.;

Reference： [1]Fan, Jian; Zhu, Hui-Fang; Okamura, Taka-Aki; Sun, Wei-Yin; Tang, Wen-Xia; Ueyama, Norikazu [Inorganic Chemistry, 2003, vol. 42, # 1, p. 158 - 162]

12
manganese (II) sulfate monohydrate [ No CAS ]
[ 220593-43-1 ]
[Mn(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2]SO₄*16H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	In methanol; water MeOH soln. of ligand and water soln. of MnSO4*H2O mixed, allowed to stand in air at room temp. for several days; elem. anal.;

Reference： [1]Fan, Jian; Sui, Bin; Okamura, Taka-Aki; Sun, Wei-Yin; Tang, Wen-Xia; Ueyama, Norikazu [Journal of the Chemical Society, Dalton Transactions, 2002, # 20, p. 3868 - 3873]

13
2[Ag(NH₃)2]⁽¹⁺⁾*C₆H₄(CO₂)2^(2-)=[Ag(NH₃)2]2(C₆H₄(CO₂)2) [ No CAS ]
[ 220593-43-1 ]
[Ag₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2]2[terephthalate]3 * 23 H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	In methanol; water exclusion of light; soln. of the benzene derivative in CH3OH carefully layered over aq. soln. of Ag complex; crystn. within several weeks; elem. anal.;

Reference： [1]Fan, Jian; Sun, Wei-Yin; Okamura, Taka-Aki; Xie, Jin; Tang, Wen-Xia; Ueyama, Norikazu [New Journal of Chemistry, 2002, vol. 26, # 2, p. 199 - 201]

14
[Ag(NH₃)2]⁽¹⁺⁾*NO₃^(1-)*5H₂O=[Ag(NH₃)2]NO₃*5H₂O [ No CAS ]
[ 220593-43-1 ]
[Ag₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2][nitrate]3 * 5 H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	In methanol; water exclusion of light; soln. of the benzene derivative in CH3OH carefully layered over aq. soln. of Ag complex; crystn. within several weeks; elem. anal.;

Reference： [1]Fan, Jian; Sun, Wei-Yin; Okamura, Taka-Aki; Xie, Jin; Tang, Wen-Xia; Ueyama, Norikazu [New Journal of Chemistry, 2002, vol. 26, # 2, p. 199 - 201]

15
zinc perchlorate [ No CAS ]
[ 220593-43-1 ]
[Zn(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2](ClO₄)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
87%	In ethanol; water soln. of ligand in EtOH was layered on soln. of Zn(ClO4)2*6H2O in water,crystn. after several weeks; elem. anal.;

Reference： [1]Fan, Jian; Sui, Bin; Okamura, Taka-Aki; Sun, Wei-Yin; Tang, Wen-Xia; Ueyama, Norikazu [Journal of the Chemical Society, Dalton Transactions, 2002, # 20, p. 3868 - 3873]

16
Cd⁽²⁺⁾*SO₄^(2-)*2.7H₂O=CdSO₄*2.7H₂O [ No CAS ]
[ 64-17-5 ]
[ 220593-43-1 ]
[Cd₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2(SO₄)4(H₂O)2(EtOH)2][Cd(H₂O)6]*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	In ethanol; water soln. of ligand in EtOH was layered over soln. of CdSO4*2.7H2O in water; crystn. after several weeks; elem. anal.;

Reference： [1]Fan, Jian; Sui, Bin; Okamura, Taka-Aki; Sun, Wei-Yin; Tang, Wen-Xia; Ueyama, Norikazu [Journal of the Chemical Society, Dalton Transactions, 2002, # 20, p. 3868 - 3873]

17
[ 14242-05-8 ]
[ 54-21-7 ]
[ 220593-43-1 ]
[Ag₂(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2][salicylate]2*3H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
74%	In methanol; water (in the dark); a MeOH soln. of ligand added to an aq. soln. of Ag complex (prepd. from AgClO4*H2O and sodium salicylate), stirred for 30 min; filtered, crystd. for days at room temp.; elem. anal.;

Reference： [1]Fan, Jian; Sun, Wei-Yin; Okamura, Taka-Aki; Tang, Wen-Xia; Ueyama, Norikazu [Inorganica Chimica Acta, 2004, vol. 357, # 8, p. 2385 - 2389]

18
sodium azide [ No CAS ]
[ 6156-78-1 ]
[ 220593-43-1 ]
[Mn(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(N₃)2]*1.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	In water; acetonitrile aq. soln. Mn(OAc)2*4H2O and NaN3 was refluxed and stirred for 8 h, filtered and cooled to room temp., soln. ligand in MeCN was layered carefullyover aq. soln. at room temp., 2 weeks; elem. anal.;

Reference： [1]Zhao, Wei; Song, You; Okamura, Taka-Aki; Fan, Jian; Sun, Wei-Yin; Ueyama, Norikazu [Inorganic Chemistry, 2005, vol. 44, # 9, p. 3330 - 3336]

19
[ 583-52-8 ]
[ 6156-78-1 ]
[ 220593-43-1 ]
[Mn₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2(C₂O₄)3(H₂O)]*10H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
40%	In methanol; water aq. soln. Mn(OAc)2*4H2O and K2C2O4 was refluxed and stirred for 8 h, filtered and cooled to room temp., soln. ligand in MeOH was layered carefully over aq. soln. at room temp., 3 weeks; elem. anal.;

Reference： [1]Zhao, Wei; Song, You; Okamura, Taka-Aki; Fan, Jian; Sun, Wei-Yin; Ueyama, Norikazu [Inorganic Chemistry, 2005, vol. 44, # 9, p. 3330 - 3336]

20
[ 141-82-2 ]
zinc(II) oxide [ No CAS ]
[ 220593-43-1 ]
[Zn₂(1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene)2(malonate)][malonate]*12H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50%	In methanol; water aq. soln. ZnO and H2mal was refluxed and stirred for 8 h, soln. was filtered and cooled to room temp., soln. titmb in MeOH was layered over aq. soln. at room temp., 3 weeks; elem. anal.;

Reference： [1]Zhao, Wei; Fan, Jian; Okamura, Taka-Aki; Sun, Wei-Yin; Ueyama, Norikazu [Journal of Solid State Chemistry, 2004, vol. 177, # 7, p. 2358 - 2365]

21
copper(II) perchlorate hexahydrate [ No CAS ]
[ 220593-43-1 ]
[Cu₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2](ClO₄)3 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
35%	In water High Pressure; Cu-salt:N-compd. molar ratio was 3:2, teflon-lined autoclave, 150 °C for 72 h; cooling to room temp., crystals were collected, elem. anal.;

Reference： [1]Meng, Wen-Li; Fan, Jian; Okamura, Taka-Aki; Kawaguchi, Hiroyuki; Lv, Yang; Sun, Wei-Yin; Ueyama, Norikazu [Zeitschrift fur Anorganische und Allgemeine Chemie, 2006, vol. 632, # 10-11, p. 1890 - 1896]

22
sodium azide [ No CAS ]
[ 6046-93-1 ]
[ 220593-43-1 ]
[Cu(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)](N₃)2*0.5H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
67%	In water High Pressure; Cu-salt:N-compd.:NaN3 molar ratio was 1:1:2, teflon-lined autoclave, 100°C for 72 h; cooling to room temp., crystals were collected, elem. anal.;

Reference： [1]Meng, Wen-Li; Fan, Jian; Okamura, Taka-Aki; Kawaguchi, Hiroyuki; Lv, Yang; Sun, Wei-Yin; Ueyama, Norikazu [Zeitschrift fur Anorganische und Allgemeine Chemie, 2006, vol. 632, # 10-11, p. 1890 - 1896]

23
copper(ll) sulfate pentahydrate [ No CAS ]
[ 220593-43-1 ]
[Cu(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)]SO₄*2.2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
52%	In water High Pressure; Cu-salt:N-compd. molar ratio was 2:1, teflon-lined autoclave, 100 °C for 72 h; cooling to room temp., crystals were collected, elem. anal.;

Reference： [1]Meng, Wen-Li; Fan, Jian; Okamura, Taka-Aki; Kawaguchi, Hiroyuki; Lv, Yang; Sun, Wei-Yin; Ueyama, Norikazu [Zeitschrift fur Anorganische und Allgemeine Chemie, 2006, vol. 632, # 10-11, p. 1890 - 1896]

24
[ 26042-63-7 ]
[ 220593-43-1 ]
Ag₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2(PF₆)3 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
66%	In methanol; acetonitrile soln. of ligand in MeOH added to MeCN soln. of AgPF6 at room temp., stirred for 1 h; filtered, allowed to stand for 1 wk; elem. anal.;

Reference： [1]Liu, Hong-Ke; Huang, Xiaohua; Lu, Tianhong; Wang, Xiujian; Sun, Wei-Yin; Kang, Bei-Sheng [Dalton Transactions, 2008, # 24, p. 3178 - 3188]

25
[ 67-56-1 ]
silver hexafluoroantimonate [ No CAS ]
[ 220593-43-1 ]
Ag₃(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2(SbF₆)3*1.5MeOH [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
54%	In methanol soln. of ligand in MeOH added to MeOH soln. of AgSbF6 at room temp., stirred for 1 h; filtered, allowed to stand for 1 wk; elem. anal.;

Reference： [1]Liu, Hong-Ke; Huang, Xiaohua; Lu, Tianhong; Wang, Xiujian; Sun, Wei-Yin; Kang, Bei-Sheng [Dalton Transactions, 2008, # 24, p. 3178 - 3188]

26
[Et₄N]4[WS₄Cu₄I₆] [ No CAS ]
[ 7732-18-5 ]
[ 220593-43-1 ]
([W(μ2-S)4Cu2(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)]*0.5water)n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
60%	In N,N-dimethyl-formamide High Pressure; heating mixt. of tungsten compd., imidazole deriv. and DMF at 120°C for 24 h; cooling to room temp. at rate 0.05°C/min, isolation of crystals, washing with CH3CN and diethyl ether, drying in air, elem. anal.;

Reference： [1]Huang, Yu-Jian; Song, Ying-Lin; Chen, Yang; Li, Hong-Xi; Zhang, Yong; Lang, Jian-Ping [Dalton Transactions, 2009, # 8, p. 1411 - 1421]

27
[ 554-95-0 ]
[ 10108-64-2 ]
[ 220593-43-1 ]
[Cd₂(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(1,3,5-benzenetricarboxylate)Cl]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	In ethanol; water High Pressure; CdCl2, 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, 1,3,5-benzenetricarboxylic acid placed in autoclave with H2O and EtOH 3:1, heatedto 160°C in 4 h, kept for 3 d, cooled to room temp. at 2.5.degre e.C/h; elem. anal.;

Reference： [1]Zhou, Hui; Lin, Jian-Di; Du, Shao-Wu [Journal of Molecular Structure, 2009, vol. 930, # 1-3, p. 49 - 54]

28
[ 10196-18-6 ]
[ 554-95-0 ]
[ 220593-43-1 ]
[Zn₂(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(1,3,5-benzenetricarboxylate)NO₃]n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
52%	In ethanol; water High Pressure; Zn(NO3)2, 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, 1,3,5-benzenetricarboxylic acid placed in autoclave with H2O and EtOH 3:1, heated to 160°C in 4 h, kept for 3 d, cooled to room temp. at 2.5°C/h; elem. anal.;

Reference： [1]Zhou, Hui; Lin, Jian-Di; Du, Shao-Wu [Journal of Molecular Structure, 2009, vol. 930, # 1-3, p. 49 - 54]

29
[ 554-95-0 ]
[ 7646-85-7 ]
[ 220593-43-1 ]
Zn2(1,3,5-tris(1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)(1,3,5-benzenetricarboxylate)Cl [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
71%	With sodium hydroxide In water at 180℃; for 72h; Sealed tube;	2.2. Synthesis of Zn₂(titmb)(BTC)Cl (1) A mixture containing ZnCl2 (27.2 mg, 0.2 mmol), H3BTC(21.0 mg, 0.1 mmol), titmb (36.0 mg, 0.1 mmol) and NaOH(12.0 mg, 0.3 mmol) in 15 ml deionized water was sealed in a25 ml Teflon lined stainless steel container and heated at 180 °C for 3 days. Colorless cubic crystals of 1 were collected by filtrationand washed with water and ethanol several times with a yield of71%. Anal. Calc. for C30H27ClN6O6Zn2 (733.77): C, 49.10; H, 3.71;N, 11.45. Found: C, 49.01; H, 3.74; N, 11.42%. IR (KBr/pellet)/cm-1: 3415 (br), 3132 (w), 2819 (w), 1611 (s), 1577 (s), 1521 (s),1443 (m), 1385 (m), 1295 (m), 1251 (m), 1109 (m), 1093 (m),1075 (s), 1012 (m), 946 (m), 865 (w), 817 (w), 772 (m), 759 (m),675 (w), 641 (m).
39%	In ethanol; water High Pressure; ZnCl2, 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, 1,3,5-benzenetricarboxylic acid placed in autoclave with H2O and EtOH 3:1, heatedto 160°C in 4 h, kept for 3 d, cooled to room temp. at 2.5.degre e.C/h; elem. anal.;

Reference： [1]Wang, Xiao-Feng; Liu, Guang-Xiang; Zhou, Hong [Inorganica Chimica Acta, 2013, vol. 406, p. 223 - 229]
[2]Zhou, Hui; Lin, Jian-Di; Du, Shao-Wu [Journal of Molecular Structure, 2009, vol. 930, # 1-3, p. 49 - 54]

30
[ 7647-01-0 ]
cadmium(II) sulfate*8/3H₂O [ No CAS ]
[ 7732-18-5 ]
[ 220593-43-1 ]
[Cd5Cl2(μ-Cl)4(μ3-Cl)2(η,η,η-μ3-SO4)2(H2O)2(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene+1H)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
55%	In hydrogenchloride; water High Pressure; into Pyrex glass tube added CdSO4*2.67H2O, aq. HCl, ligand and water andtube sealed; tube heated to 150°C for 2 d and then cooled down a t rate 5°C/h; crystals washed with ethanol and dried in air; elem. anal.;

Reference： [1]Chang, Yu-Jie; Liu, Dong; Ren, Zhi-Gang; Lang, Jian-Ping [Inorganic Chemistry Communications, 2011, vol. 14, # 2, p. 403 - 406]

31
[ 7647-01-0 ]
[ 67-56-1 ]
cadmium(II) sulfate*8/3H₂O [ No CAS ]
[ 220593-43-1 ]
[Cd4Cl2(μ-Cl)2(η,η,η-μ3-SO4)2(CH3OH)2(1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
45%	In hydrogenchloride; methanol High Pressure; into Pyrex glass tube added CdSO4*2.67H2O, aq. HCl, ligand and methanol and tube sealed; tube heated to 150°C for 2 d and then cooled down at rate 5°C/h; crystals washed with ethanol and dried in air; elem. anal.;

Reference： [1]Chang, Yu-Jie; Liu, Dong; Ren, Zhi-Gang; Lang, Jian-Ping [Inorganic Chemistry Communications, 2011, vol. 14, # 2, p. 403 - 406]

32
[ 7647-01-0 ]
cadmium(II) sulfate*8/3H₂O [ No CAS ]
[ 220593-43-1 ]
[ 1272671-94-9 ]

Yield	Reaction Conditions	Operation in experiment
69%	In hydrogenchloride; ethanol High Pressure; into Pyrex glass tube added CdSO4*2.67H2O, aq. HCl, ligand and ethanol and tube sealed; tube heated to 150°C for 2 d and then cooled downat rate 5°C/h; crystals washed with ethanol and dried in air; elem. anal.;

Reference： [1]Chang, Yu-Jie; Liu, Dong; Ren, Zhi-Gang; Lang, Jian-Ping [Inorganic Chemistry Communications, 2011, vol. 14, # 2, p. 403 - 406]

33
[ 200138-14-3 ]
[ 220593-43-1 ]
3Br^(1-)*C₇₂H₁₃₅N₆O₉Si₃⁽³⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
99%	In acetonitrile at 80℃; for 48h;

Reference： [1]Location in patent: experimental part Trilla, Montserrat; Cattoen, Xavier; Blanc, Christophe; Wong Chi Man, Michel; Pleixats, Roser [Journal of Materials Chemistry, 2011, vol. 21, # 4, p. 1058 - 1063]

34
[ 67-56-1 ]
erbium(III) nitrate hexahydrate [ No CAS ]
[ 122-51-0 ]
[ 220593-43-1 ]
[Er₂(1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene)(H-1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene)(NO₃)6(HCOO)]*3CH₃OH [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In methanol mixt. Ln(NO3)3*6H2O, ligand, MeOH , and HC(OEt)3 was refluxed for 2 h; soln. was filtered, filtrate was allowed to stand in desiccator at room temp. for several days; elem. anal.;