There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
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CAS No. : | 21324-40-3 | MDL No. : | MFCD00011096 |
Formula : | F6LiP | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | AXPLOJNSKRXQPA-UHFFFAOYSA-N |
M.W : | 151.91 | Pubchem ID : | 23688915 |
Synonyms : |
|
Num. heavy atoms : | 8 |
Num. arom. heavy atoms : | 0 |
Fraction Csp3 : | None |
Num. rotatable bonds : | 0 |
Num. H-bond acceptors : | None |
Num. H-bond donors : | None |
Molar Refractivity : | 13.57 |
TPSA : | 13.59 Ų |
GI absorption : | None |
BBB permeant : | None |
P-gp substrate : | None |
CYP1A2 inhibitor : | None |
CYP2C19 inhibitor : | None |
CYP2C9 inhibitor : | None |
CYP2D6 inhibitor : | None |
CYP3A4 inhibitor : | None |
Log Kp (skin permeation) : | None cm/s |
Log Po/w (iLOGP) : | None |
Log Po/w (XLOGP3) : | None |
Log Po/w (WLOGP) : | None |
Log Po/w (MLOGP) : | None |
Log Po/w (SILICOS-IT) : | None |
Consensus Log Po/w : | None |
Lipinski : | None |
Ghose : | None |
Veber : | None |
Egan : | None |
Muegge : | None |
Bioavailability Score : | None |
Log S (ESOL) : | None |
Solubility : | None mg/ml ; None mol/l |
Class : | None |
Log S (Ali) : | None |
Solubility : | None mg/ml ; None mol/l |
Class : | None |
Log S (SILICOS-IT) : | None |
Solubility : | None mg/ml ; None mol/l |
Class : | None |
PAINS : | None alert |
Brenk : | None alert |
Leadlikeness : | None |
Synthetic accessibility : | None |
Signal Word: | Danger | Class: | 8,6.1 |
Precautionary Statements: | P234-P260-P264-P270-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501 | UN#: | 2923 |
Hazard Statements: | H290-H302-H311-H314 | Packing Group: | Ⅱ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
93% | In water; at 20℃; for 20h; | To 1.00 g (0.00217 mol) of tris(N-methyl-ethylamino) di-n-butylaminophosphonium iodide obtained in B(ac), an aqueous solution dissolving 0.40 g (0.0026 mol) of LiPF6 in 5 ml of ultrapure water was added, and the resulting solution was stirred at room temperature for 20 hours. The resulting salt was extracted with 10 ml of CH2Cl2 and washed with ultrapure water three times. The extracted solution was concentrated with a rotary evaporator, and vacuum-dried at 80C so as to obtain 0.97 g of tris(N-methyl-ethylamino)di-n-butylaminophosphonium hexafluorophosphate; the yield was 93%. The resulting compound was identified with a nuclear magnetic resonance analyzer (BRUKER Ultra Shield 300 NMR Spectrometer, manufactured by BRUKER Limited.). The resulting spectral data are shown below. 1H-NMR (300 MHz, solvent: CDCl3, standard substance: tetramethylsilane) delta 3.05 (m, 6H) 2.97 (m, 4H) 2.75 (d, 9H) 1.55 (m, 4H) 1.33 (m, 4H) 1.22 (t, 9H) 0.96 (t, 6H) 19F-NMR (282 MHz, solvent: CDCl3, standard substance: CF3Cl) delta -73.27 (d, 6F) 31P-NMR (121 MHz, solvent: CDCl3, standard substance: triphenylphosphine) delta 43.26 (m, 1P) -144.30 (heat, 1P) The structural formula is shown below (in the formula, the dashed lines shows a conjugated structure). [Show Image] [Show Image] The melting point was measured with a differential scanning calorimeter (DSC8230, manufactured by Shimadzu Corp.). The glass transition temperature was -61.7C. The thermal decomposition temperature was measured with a thermal gravimetry analyzer (TG8120, manufactured by Rigaku Corp.). The 5% weight-loss temperature measured at a temperature rise rate of 10C/min was 296.5C. |