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[ CAS No. 194861-72-8 ] {[proInfo.proName]}

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Chemical Structure| 194861-72-8

Chemical Structure| 194861-72-8

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Quality Control of [ 194861-72-8 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 194861-72-8 ]

Product Details of [ 194861-72-8 ]

CAS No. :	194861-72-8	MDL No. :	MFCD30534199
Formula :	C₂₄H₁₆N₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	SAAQRUMAXVBWDL-UHFFFAOYSA-N
M.W :	332.40	Pubchem ID :	15320285
Synonyms :

Safety of [ 194861-72-8 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 194861-72-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 194861-72-8 ]

[ 194861-72-8 ] Synthesis Path-Downstream 1~47

1
[ 523-27-3 ]
[ 181219-01-2 ]
[ 194861-72-8 ]

Yield	Reaction Conditions	Operation in experiment
51%	With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂ In 1,4-dioxane at 100℃; for 20h;

Reference： [1]Coudret, Christophe; Mazenc, Valerie [Tetrahedron Letters, 1997, vol. 38, # 30, p. 5293 - 5296]

2
[ 67-56-1 ]
copper(II) nitrate trihydrate [ No CAS ]
[ 194861-72-8 ]
[ 71-43-2 ]
Cu(C₂₄H₁₆N₂)⁽²⁺⁾*2NO₃^(1-)=CuC₂₄H₁₆N₂(NO₃)2 [ No CAS ]
Cu(C₂₄H₁₆N₂)CH₃OH⁽²⁺⁾*2NO₃^(1-)*CH₃OH*C₆H₆=CuC₂₄H₁₆N₂(CH₃OH)(NO₃)2*CH₃OH*C₆H₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
1: 20% 2: 50%	layering of MeOH soln. of salt on benzene soln. of ligand, allowed to stand for 2 days;

Reference： [1]Biradha, Kumar; Fujita, Makoto [Journal of the Chemical Society, Dalton Transactions, 2000, # 21, p. 3805 - 3810]

3
copper(II) nitrate trihydrate [ No CAS ]
[ 100-47-0 ]
[ 194861-72-8 ]
Cu(C₂₄H₁₆N₂)2⁽²⁺⁾*2C₆H₅CN*2NO₃^(1-)=CuC₄₈H₃₂N₄(NO₃)2*2C₆H₅CN [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	In methanol layering of MeOH soln. of salt on benzene soln. of ligand, allowed to stand for 2 days; filtration;

Reference： [1]Biradha, Kumar; Fujita, Makoto [Journal of the Chemical Society, Dalton Transactions, 2000, # 21, p. 3805 - 3810]

4
copper(II) nitrate trihydrate [ No CAS ]
[ 98-95-3 ]
[ 194861-72-8 ]
Cu(C₂₄H₁₆N₂)2⁽²⁺⁾*2C₆H₅NO₂*2NO₃^(1-)=CuC₄₈H₃₂N₄(NO₃)2*2C₆H₅NO₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	In methanol layering of MeOH soln. of salt on nitrobenzene soln. of ligand, allowed to stand for 2 days; filtration;

Reference： [1]Biradha, Kumar; Fujita, Makoto [Journal of the Chemical Society, Dalton Transactions, 2000, # 21, p. 3805 - 3810]

5
nickel(II) nitrate hexahydrate [ No CAS ]
[ 194861-72-8 ]
Ni(C₂₄H₁₆N₂)2(H₂O)2⁽²⁺⁾*2NO₃^(1-)=NiC₄₈H₃₂N₄(H₂O)2(NO₃)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In methanol; benzene layering of MeOH soln. of salt on benzene soln. of ligand, allowed to stand for 2 days; filtration;

Reference： [1]Biradha, Kumar; Fujita, Makoto [Journal of the Chemical Society, Dalton Transactions, 2000, # 21, p. 3805 - 3810]

6
nickel(II) nitrate hexahydrate [ No CAS ]
[ 100-47-0 ]
[ 194861-72-8 ]
Ni(C₂₄H₁₆N₂)2⁽²⁺⁾*2C₆H₅CN*2NO₃^(1-)=NiC₄₈H₃₂N₄(NO₃)2*2C₆H₅CN [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	In methanol layering of MeOH soln. of salt on cyanobenzene soln. of ligand, allowed to stand for 2 days; filtration;

Reference： [1]Biradha, Kumar; Fujita, Makoto [Journal of the Chemical Society, Dalton Transactions, 2000, # 21, p. 3805 - 3810]

7
nickel(II) nitrate hexahydrate [ No CAS ]
[ 98-95-3 ]
[ 194861-72-8 ]
Ni(C₂₄H₁₆N₂)2⁽²⁺⁾*2C₆H₅NO₂*2NO₃^(1-)=NiC₄₈H₃₂N₄(NO₃)2*2C₆H₅NO₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In methanol layering of MeOH soln. of salt on nitrobenzene soln. of ligand, allowed to stand for 2 days; filtration;

Reference： [1]Biradha, Kumar; Fujita, Makoto [Journal of the Chemical Society, Dalton Transactions, 2000, # 21, p. 3805 - 3810]

8
[ 194861-72-8 ]
[ 3840-30-0 ]
4,4′-(anthracene-9,10-diyl)bis[1-(3,4,5-trimethoxybenzyl)pyridin-1-ium] chloride [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
71%	In toluene for 48h; Reflux;

Reference： [1]Kohmoto, Shigeo; Chuko, Tomotaka; Hisamatsu, Shugo; Okuda, Yasuhiro; Masu, Hyuma; Takahashi, Masahiro; Kishikawa, Keiki [Crystal Growth and Design, 2015, vol. 15, # 6, p. 2723 - 2731]

9
[ 956761-45-8 ]
[ 194861-72-8 ]
4,4′-(anthracene-9,10-diyl)bis{1-[3,4,5-tris(octyloxy)benzyl]-pyridin-1-ium} bromide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In toluene for 48h; Reflux;

Reference： [1]Kohmoto, Shigeo; Chuko, Tomotaka; Hisamatsu, Shugo; Okuda, Yasuhiro; Masu, Hyuma; Takahashi, Masahiro; Kishikawa, Keiki [Crystal Growth and Design, 2015, vol. 15, # 6, p. 2723 - 2731]

10
[ 478083-71-5 ]
[ 194861-72-8 ]
4,4′-(anthracene-9,10-diyl)bis{1-[3,4,5-tris(dodecyloxy)benzyl]-pyridin-1-ium} bromide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
90%	In toluene for 48h; Reflux;

Reference： [1]Kohmoto, Shigeo; Chuko, Tomotaka; Hisamatsu, Shugo; Okuda, Yasuhiro; Masu, Hyuma; Takahashi, Masahiro; Kishikawa, Keiki [Crystal Growth and Design, 2015, vol. 15, # 6, p. 2723 - 2731]

11
cadmium(II) nitrate tetrhydrate [ No CAS ]
[ 1141-38-4 ]
[ 194861-72-8 ]
2Cd⁽²⁺⁾*3C₂₄H₁₆N₂*2C₁₂H₆O₄^(2-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
50.5%	In N,N-dimethyl-formamide at 95℃; for 72h; Sealed tube; High pressure;	2.3.3. Preparation of [Cd2(L)3(2,6-ndc)2] (3) The preparation of complex 3was similar to that of 1, except thatCd(NO3)24H2O (31 mg, 0.1 mmol) was used instead ofZn(NO3)26H2O (30 mg, 0.1 mmol), and heated at 95 C for 3 days.Resulting in the formation of yellow particles and crystals of 3 wereobtained. Yield: 50.5% based on L. Anal Calcd (%) for C48H30N3O4Cd(%): C, 69.87; H, 3.66; N, 5.09. Found: C, 69.85; H, 3.68; N, 5.07. IR(KBrpellets, cm1): 3320(m), 3057(s), 2933(s), 1956(m), 1834(m),1654(s), 1603(s), 1564(s), 1491(s), 1400(s), 1359(s), 1219(s), 1192(s),1143(s), 1097(s), 1013(s), 931(s), 797(s).

Reference： [1]Dong, Jun-Liang; Wang, Duo-Zhi; Jia, Yan-Yuan; Wang, Dan-Hong [Journal of Molecular Structure, 2017, vol. 1142, p. 304 - 310]

12
zinc(II) nitrate hexahydrate [ No CAS ]
[ 100-21-0 ]
[ 194861-72-8 ]
C₂₄H₁₆N₂*3C₈H₄O₄^(2-)*3Zn⁽²⁺⁾*2C₃H₇NO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
51.2%	In N,N-dimethyl-formamide at 70℃; for 120h; Sealed tube; High pressure;	2.3.1. Preparation of [Zn3(L)(1,4-bdc)3]·2DMF (1) A mixture of Zn(NO3)26H2O (30 mg, 0.1 mmol), L (16.6 mg,0.05 mmol), 1,4-H2bdc (16.6 mg, 0.1 mmol) was put in a reactionvessel (10 ml) and DMF (3 ml) was added to it, then sealed, withultrasonic processing for 30 min the solid completely dissolved inDMF giving a clear solution. The reaction solution was heated at70 C for five days then cooled to room temperature and filtered,after the solid was washed with DMF and dried to obtain manyyellow petals crystals (ca. 51.2% yield based on L). Anal. Calcd (%) forC48H28N2O12Zn3 (%): C, 54.73; H, 3.53; N, 4.91. Found: C, 54.71; H,3.58; N, 4.89. IR (KBr pellets, cm1): 3062(m), 2926(s), 2856(s),1954(m), 1829(m), 1671(s), 1607(s), 1506(s), 1390(s), 1262(m),1134(s), 1096(s), 1023(m), 951(s), 885(s), 825(s), 750(s), 644(m).

Reference： [1]Dong, Jun-Liang; Wang, Duo-Zhi; Jia, Yan-Yuan; Wang, Dan-Hong [Journal of Molecular Structure, 2017, vol. 1142, p. 304 - 310]

13
zinc(II) nitrate hexahydrate [ No CAS ]
[ 1141-38-4 ]
[ 194861-72-8 ]
C₂₄H₁₆N₂*2Zn⁽²⁺⁾*3C₃H₇NO*2C₁₂H₆O₄^(2-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62.1%	In N,N-dimethyl-formamide at 95℃; for 96h; Sealed tube; High pressure;	2.3.2. Preparation of [Zn2(L)(2,6-ndc)2]·3DMF (2) The preparation of complex 2was similar to that of 1, except that2,6-H2ndc (21.6 mg, 0.1 mmol) was used instead of 1,4-H2bdc(16.6 mg, 0.1 mmol), and heated at 95 C for four days. Resulting inthe formation of orange square crystals of 2 that were obtained.Yield: 62.1% based on L. Anal Calcd (%) for C117H105N11O23Zn4 (%): C,61.69; H, 4.36; N, 5.05. Found: C, 61.63; H, 4.37; N, 5.02. IR(KBrpellets, cm1): 3300(m), 3055(m), 2933(s), 1949(m), 1662(s),1608(s), 1514(m), 1457(m), 1418(s), 1358(s), 1259(s), 1217(s),1158(s),1091(s), 1068(s), 1030(s), 859(m), 824(s).

Reference： [1]Dong, Jun-Liang; Wang, Duo-Zhi; Jia, Yan-Yuan; Wang, Dan-Hong [Journal of Molecular Structure, 2017, vol. 1142, p. 304 - 310]

14
[ 523-27-3 ]
[ 1692-15-5 ]
[ 194861-72-8 ]

Yield	Reaction Conditions	Operation in experiment
82%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; N,N-dimethyl-formamide for 12h; Inert atmosphere;
82%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 24h; Inert atmosphere;
72%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In 1,4-dioxane; water at 100℃; for 18h; Inert atmosphere;

70%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In N,N-dimethyl-formamide; toluene at 130℃; for 48h; Inert atmosphere;	2.2. Preparation of ligand L 9,10-dibromoanthracene (2.0 g, 5.95 mmol), Pyridine-4-boronicacid (2.4 g,17.8 mmol), K2CO3 (11.6 g, 35.5 mmol), Pd(PPh3)4 (0.68 g,0.59 mmol) and PhMe:DMF (6:1, 300 ml) were successively add to a500ml flask. Under N2 conditions, the reaction mixturewas heatedto 130 C in the dark for 48 h. After the reaction mixturewas cooledto room temperature and filtered to remove the catalyst by diatomaceousearth. The removal of solvent under reduced pressureyielded crude solid. The crude solid was dissolved in dichloromethaneand washed with distilled water, then dried over anhydrousmagnesium sulfate and concentrate dichloromethane underreduced pressure. A HCl solutionwas added and adjusted the pH to2e3. Solid precipitation was produced and then filtered, the solidwas dissolved in water and adjusted the pH to 8e9 by the additionof NaOH (10 M) solution. The pale yellow solid thus obtained byfiltration andwaswashed with distilledwater. Yield (1.4 g, 70%). MS(333.1387). 1H NMR (CDCl3-d6, dppm): 8.879 (m, 4H, pyridine-2),7.609 (m, 4H, anthracene-1), 7.456 (m, 4H, pyridine-3), 7.405 (t,4H, anthracene-2).
70%	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In N,N-dimethyl-formamide; toluene at 130℃; for 48h; Inert atmosphere;
	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In 1,4-dioxane; water at 90℃; for 72h; Inert atmosphere;
	With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 18h; Inert atmosphere;

Reference： [1]Fudickar, Werner; Linker, Torsten [Journal of Organic Chemistry, 2017, vol. 82, # 17, p. 9258 - 9262]
[2]Dong, Wei; Huang, Wei; Liu, Xing-Gui; Lu, Zhen-Zhong; Meng, Mei-Mei; Wang, Li-Fei; Xi, Ji-Ming; Xu, Yong-Kai; Zhang, Rui; Zheng, He-Gen; Zhu, Rui [Dalton Transactions, 2021, vol. 50, # 23, p. 7944 - 7948]
[3]Meneses-Sánchez, Manuel; Piñeiro-López, Lucía; Delgado, Teresa; Bartual-Murgui, Carlos; Muñoz, M. Carmen; Chakraborty, Pradip; Real, José Antonio [Journal of Materials Chemistry C, 2020, vol. 8, # 5, p. 1623 - 1633]
[4]Dong, Jun-Liang; Wang, Duo-Zhi; Jia, Yan-Yuan; Wang, Dan-Hong [Journal of Molecular Structure, 2017, vol. 1142, p. 304 - 310]
[5]Yao, Zhao-Quan; Li, Guang-Yu; Xu, Jian; Hu, Tong-Liang; Bu, Xian-He [Chemistry - A European Journal, 2018, vol. 24, # 13, p. 3192 - 3198]
[6]Vasylevskyi, Serhii I.; Bassani, Dario M.; Fromm, Katharina M. [Inorganic Chemistry, 2019, vol. 58, # 9, p. 5646 - 5653]
[7]Huang, Zehuan; Scherman, Oren A.; Wu, Guanglu [Angewandte Chemie - International Edition, 2020, vol. 59, # 37, p. 15963 - 15967][Angew. Chem., 2020, vol. 132, # 37, p. 16097 - 16101,5]
[8]Liu, Lu; Qu, Wei-Dong; Dong, Kai-Xun; Qi, Ye; Gong, Wei-Tao; Ning, Gui-Ling; Cui, Jing-Nan [Chemical Communications, 2021, vol. 57, # 27, p. 3339 - 3342]

15
[ 1120-87-2 ]
[ 194861-72-8 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: Triisopropyl borate; n-butyllithium / tetrahydrofuran / 3 h / -78 °C 2: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / N,N-dimethyl-formamide; water / 12 h / Inert atmosphere

Reference： [1]Fudickar, Werner; Linker, Torsten [Journal of Organic Chemistry, 2017, vol. 82, # 17, p. 9258 - 9262]

16
[ 194861-72-8 ]
9,10-bis(4-pyridyl)-9,10-dihydro-9,10-epidioxidoanthracene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
96%	With oxygen; 5,15,10,20-tetraphenylporphyrin In dichloromethane at -20℃; for 12h; Irradiation;
	With oxygen In N,N-dimethyl-formamide UV-irradiation;

Reference： [1]Fudickar, Werner; Linker, Torsten [Journal of Organic Chemistry, 2017, vol. 82, # 17, p. 9258 - 9262]
[2]Fujimura, Masashi; Kusaka, Shinpei; Masuda, Ayaka; Hori, Akihiro; Hijikata, Yuh; Pirillo, Jenny; Ma, Yunsheng; Matsuda, Ryotaro [Small, 2021, vol. 17, # 22]

17
9,10-bis(4-pyridyl)-9,10-dihydro-9,10-epidioxidoanthracene [ No CAS ]
[ 80937-33-3 ]
[ 194861-72-8 ]

Yield	Reaction Conditions	Operation in experiment
1: 92% 2: 39%	In toluene for 24h;

Reference： [1]Fudickar, Werner; Linker, Torsten [Journal of Organic Chemistry, 2017, vol. 82, # 17, p. 9258 - 9262]

18
cadmium(II) nitrate hexahydrate [ No CAS ]
[ 100-21-0 ]
[ 194861-72-8 ]
(x)C₃H₇NO*C₈H₄O₄^(2-)*C₂₄H₁₆N₂*Cd⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
59%	at 85℃; for 72h; Sealed tube;	Synthesis of 1 (CCDC:1,534,561) A mixture of Cd(NO3)2·4H2O (31mg, 0.1mmol), dpa (16.6mg, 0.05mmol), and pta (16.6mg, 0.1mmol) in 3mL DMF was stirred in air for 30min and sealed in a 10mL Teflon lined stainless steel container. Then the reaction system was heated at 85°C for 3d. After cooling down to room temperature, yellow block crystals were obtained (yield: ca. 59% based on dpa). EA (%) Calcd for C32H20CdN2O4: C 63.11, H 3.32, N 4.60; found C 63.09, H 3.35, N, 4.57. FT-IR (cm-1, KBr): 3064s, 2922s, 2855s, 1953m, 1825m, 1676vs, 1604s, 1565vs, 1380s, 1294m, 1220vs, 951s, 885m, 828vs, 749vs, 677s, 642s, 613vs.

Reference： [1]Wang, Jian-Hong; Li, Guang-Yu; Liu, Xiao-Jing; Feng, Rui; Zhang, Huan-Jun; Zhang, Shi-Yu; Zhang, Ying-Hui [Inorganica Chimica Acta, 2018, vol. 473, p. 70 - 74]

19
zinc(II) nitrate hexahydrate [ No CAS ]
[ 2215-89-6 ]
[ 33513-42-7 ]
[ 194861-72-8 ]
[Zn₃(9,10-bis(4-pyridyl)anthracene)(4,4’-oxybis(benzoate))₃]*2DMF [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
53.8%	at 100℃; for 72h; Sealed tube;

Reference： [1]Yao, Zhao-Quan; Li, Guang-Yu; Xu, Jian; Hu, Tong-Liang; Bu, Xian-He [Chemistry - A European Journal, 2018, vol. 24, # 13, p. 3192 - 3198]

20
[ 333-27-7 ]
[ 194861-72-8 ]
9,10-bis(1-methylpyridinium-4-yl)anthracene ditrifluoromethanesulfonate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
600 mg	In dichloromethane at 5℃; for 0.666667h;

Reference： [1]Fudickar, Werner; Linker, Torsten [Angewandte Chemie - International Edition, 2018, vol. 57, # 39, p. 12971 - 12975][Angew. Chem., 2018, vol. 130, p. 13153 - 13157,5]

21
[ 67-56-1 ]
lead(II) nitrate [ No CAS ]
[ 194861-72-8 ]
[ 7681-82-5 ]
[Me₂(9,10-bis(4-pyridyl)anthracene)][Pb₄I₁₀] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
55%	With hydrogen iodide In water at 145℃; for 168h; Autoclave; High pressure;

Reference： [1]Ge, Bang-Di; Wei, Qi; Sun, Ai-Huan; Lin, Chong-Yang; Duan, Xiao-Fang; Li, Jin-Hua; Wang, Guo-Ming [Chemistry - An Asian Journal, 2019, vol. 14, # 12, p. 2086 - 2090]

22
[ 67-56-1 ]
zinc(II) trifluoroacetate hydrate [ No CAS ]
[ 194861-72-8 ]
[Zn(μ₂-BA)(MeOH)₂(CF₃CO₂)₂]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
41%	In dichloromethane at 20℃; for 0.5h;

Reference： [1]Vasylevskyi, Serhii I.; Bassani, Dario M.; Fromm, Katharina M. [Inorganic Chemistry, 2019, vol. 58, # 9, p. 5646 - 5653]

23
[ 67-56-1 ]
zinc(II) trifluoromethanesulfonate hexahydrate [ No CAS ]
[ 194861-72-8 ]
Zn⁽²⁺⁾*2C₂₄H₁₆N₂*2CH₄O*2H₂O*2CF₃O₃S^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
38%	In dichloromethane at 20℃; for 0.5h;

Reference： [1]Vasylevskyi, Serhii I.; Bassani, Dario M.; Fromm, Katharina M. [Inorganic Chemistry, 2019, vol. 58, # 9, p. 5646 - 5653]

24
[ 67-56-1 ]
cadmium(II) perchlorate hexahydrate [ No CAS ]
[ 75-09-2 ]
[ 194861-72-8 ]
[Cd(μ₂-BA)₂(ClO₄)₂]*n(DCM)}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
78%	at 20℃; for 0.5h;

Reference： [1]Vasylevskyi, Serhii I.; Bassani, Dario M.; Fromm, Katharina M. [Inorganic Chemistry, 2019, vol. 58, # 9, p. 5646 - 5653]

25
[ 123-91-1 ]
[ 67-56-1 ]
cadmium(II) hexafluorosilicate hexahydrate [ No CAS ]
[ 194861-72-8 ]
[Cd(μ₂-BA)(MeOH)₂(dioxane)(η₂-SiF₆)]*m(dioxane)}_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
37%	In dichloromethane at 20℃; for 0.5h;

Reference： [1]Vasylevskyi, Serhii I.; Bassani, Dario M.; Fromm, Katharina M. [Inorganic Chemistry, 2019, vol. 58, # 9, p. 5646 - 5653]

26
[ 67-56-1 ]
zinc(II) p-toluenesulfonate hydrate [ No CAS ]
[ 194861-72-8 ]
[Zn(μ₂-BA)(MeOH)₂(p-Tos)₂]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
47%	In dichloromethane at 20℃; for 0.5h;

Reference： [1]Vasylevskyi, Serhii I.; Bassani, Dario M.; Fromm, Katharina M. [Inorganic Chemistry, 2019, vol. 58, # 9, p. 5646 - 5653]

27
iron(II) tetrafluoroborate hexahydrate [ No CAS ]
potassium dicyanoargentate(I) [ No CAS ]
[ 194861-72-8 ]
{Fe^II(bis(4-pyridyl)anthracene)[Ag^I(CN)₂]₂} [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; dichloromethane Sealed tube;

Reference： [1]Meneses-Sánchez, Manuel; Piñeiro-López, Lucía; Delgado, Teresa; Bartual-Murgui, Carlos; Muñoz, M. Carmen; Chakraborty, Pradip; Real, José Antonio [Journal of Materials Chemistry C, 2020, vol. 8, # 5, p. 1623 - 1633]

28
potassium dicyanouranate [ No CAS ]
iron(II) tetrafluoroborate hexahydrate [ No CAS ]
[ 194861-72-8 ]
{Fe^II(bis(4-pyridyl)anthracene)[Au^I(CN)₂]₂} [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; dichloromethane Sealed tube;

Reference： [1]Meneses-Sánchez, Manuel; Piñeiro-López, Lucía; Delgado, Teresa; Bartual-Murgui, Carlos; Muñoz, M. Carmen; Chakraborty, Pradip; Real, José Antonio [Journal of Materials Chemistry C, 2020, vol. 8, # 5, p. 1623 - 1633]

29
potassium dicyanouranate [ No CAS ]
zinc(II) tetrafluoroborate hexahydrate [ No CAS ]
[ 194861-72-8 ]
{Zn^II(bis(4-pyridyl)anthracene)[Au^I(CN)₂]₂} [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol; dichloromethane Sealed tube;

Reference： [1]Meneses-Sánchez, Manuel; Piñeiro-López, Lucía; Delgado, Teresa; Bartual-Murgui, Carlos; Muñoz, M. Carmen; Chakraborty, Pradip; Real, José Antonio [Journal of Materials Chemistry C, 2020, vol. 8, # 5, p. 1623 - 1633]

30
[ 194861-72-8 ]
6C₂₄H₁₆N₂O₂*6C₁₀H₄^(2-)*12Pt⁽²⁺⁾*12CF₃O₃S^(1-)*24C₆H₁₅P [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With oxygen; methylene blue In d⁽⁴⁾-methanol Irradiation;

Reference： [1]Fudickar, Werner; Han, Jun; He, Yan-Qin; Li, Xiaopeng; Linker, Torsten; Liu, Min; Stang, Peter J.; Tang, Jian-Hong; Wang, Heng; Wang, Zhengping; Zhong, Yu-Wu [Journal of the American Chemical Society, 2020, vol. 142, # 5, p. 2601 - 2608]

31
C₃₆H₆₄F₆O₆P₄Pt₂S₂ [ No CAS ]
[ 194861-72-8 ]
6C₂₄H₁₆N₂*6C₁₀H₄^(2-)*12Pt⁽²⁺⁾*12CF₃O₃S^(1-)*24C₆H₁₅P [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
99%	In methanol; dichloromethane at 50℃; for 10h;

Reference： [1]Fudickar, Werner; Han, Jun; He, Yan-Qin; Li, Xiaopeng; Linker, Torsten; Liu, Min; Stang, Peter J.; Tang, Jian-Hong; Wang, Heng; Wang, Zhengping; Zhong, Yu-Wu [Journal of the American Chemical Society, 2020, vol. 142, # 5, p. 2601 - 2608]

32
[ 97-00-7 ]
[ 194861-72-8 ]
4,4'-(anthracene-9,10-diyl)bis(1-(2,4-dinitrophenyl)pyridin-1-ium) chloride [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
63%	In acetonitrile at 72℃; for 90h;
	In ethanol at 90℃; for 120h; Inert atmosphere;

Reference： [1]Liu, Lu; Qu, Wei-Dong; Dong, Kai-Xun; Qi, Ye; Gong, Wei-Tao; Ning, Gui-Ling; Cui, Jing-Nan [Chemical Communications, 2021, vol. 57, # 27, p. 3339 - 3342]
[2]Huang, Zehuan; Scherman, Oren A.; Wu, Guanglu [Angewandte Chemie - International Edition, 2020, vol. 59, # 37, p. 15963 - 15967][Angew. Chem., 2020, vol. 132, # 37, p. 16097 - 16101,5]

33
[ 194861-72-8 ]
C₄₂H₃₈N₂⁽²⁺⁾*2Cl^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: ethanol / 120 h / 90 °C / Inert atmosphere 2: ethanol / 12 h / 90 °C / Inert atmosphere

Reference： [1]Huang, Zehuan; Scherman, Oren A.; Wu, Guanglu [Angewandte Chemie - International Edition, 2020, vol. 59, # 37, p. 15963 - 15967][Angew. Chem., 2020, vol. 132, # 37, p. 16097 - 16101,5]

34
[ 194861-72-8 ]
4,4'-(anthracene-9,10-diyl)bis(1-phenylpyridin-1-ium) chloride [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: ethanol / 120 h / 90 °C / Inert atmosphere 2: ethanol / 12 h / 90 °C / Inert atmosphere

Reference： [1]Huang, Zehuan; Scherman, Oren A.; Wu, Guanglu [Angewandte Chemie - International Edition, 2020, vol. 59, # 37, p. 15963 - 15967][Angew. Chem., 2020, vol. 132, # 37, p. 16097 - 16101,5]

35
zinc(II) nitrate hexahydrate [ No CAS ]
[ 1141-38-4 ]
[ 33513-42-7 ]
[ 194861-72-8 ]
[Zn₂(9,10-di(4-pyridyl)anthracene)(2,6-2,6-naphthalenedicarboxylate)₂]*(N,N-dimethylformamide)₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	at 100℃; for 72h; Autoclave;

Reference： [1]Fujimura, Masashi; Kusaka, Shinpei; Masuda, Ayaka; Hori, Akihiro; Hijikata, Yuh; Pirillo, Jenny; Ma, Yunsheng; Matsuda, Ryotaro [Small, 2021, vol. 17, # 22]

36
9,10-bis(4-pyridyl)-9,10-dihydro-9,10-epidioxidoanthracene [ No CAS ]
[ 194861-72-8 ]

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide at 120℃; for 24h;

Reference： [1]Fujimura, Masashi; Kusaka, Shinpei; Masuda, Ayaka; Hori, Akihiro; Hijikata, Yuh; Pirillo, Jenny; Ma, Yunsheng; Matsuda, Ryotaro [Small, 2021, vol. 17, # 22]

37
[cis-Pt(PEt₃)₂(OTf)₂] [ No CAS ]
Pt(II) meso-tetra(4-carboxyphenyl)porphine sodium salt [ No CAS ]
[ 194861-72-8 ]
16C₆H₁₅P*4C₂₄H₁₆N₂*2C₄₈H₂₄N₄O₈^(6-)*8CF₃O₃S^(1-)*10Pt⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
88.4%	In water; acetone at 70℃; for 12h;

Reference： [1]Ge, Fujing; Huang, Feihe; Li, Qi; Liu, Yuezhou; Mao, Zhengwei; Shi, Bingbing; Stang, Peter J.; Wang, Sheng; Yu, Guocan; Zhu, Hong; Zhu, Huangtianzhi [Angewandte Chemie - International Edition, 2020, vol. 59, # 45, p. 20208 - 20214][Angew. Chem., 2020, vol. 132, # 45, p. 20383 - 20389,7]

38
[ 7681-65-4 ]
ammonium tetrathiotungstate [ No CAS ]
[ 33513-42-7 ]
[ 194861-72-8 ]
[ 7681-82-5 ]
1.5C₂₄H₁₆N₂*0.5S₄W^(2-)*2Cu⁽¹⁺⁾*C₃H₇NO*I^(1-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In dichloromethane for 0.333333h;	2.3 Preparation of 2 L2 (0.0332g, 0.1mmol) was added into 3mL dichloromethane (DCM). (NH4)2WS4 (0.0688g, 0.2mmol), CuI (0.0312g, 0.6mmol), NaI (0.090g, 0.6mmol) were added into 6mL DMF. The two solutions were stirred for 20min, and then the resulting DCM solution was filtered into a glass tube. 1.5mL DCM and 6mL DMF filtrate were slowly layered on the surface of the filtrate in turn. Two weeks later, red block crystals were obtained for 2. Anal. (%) Calcd. for C78H64Cu4I2N8O2S4W: C, 47.58; H, 3.19; N, 5.72. Found: C, 47.62; H, 3.28; N, 5.70. IR (KBr pellet, cm-1): 3428(s), 1602(s), 1413(s), 1067(s), 813(s), 770(s), 642(s), 548(s), 435(s).

Reference： [1]Zhang, Jinfang; Xiang, Qian; Qiu, Qingxia; Zhu, Yuan; Zhang, Chi [Journal of Solid State Chemistry, 2021, vol. 298]

39
[ 1336-21-6 ]
[ 64-17-5 ]
[ 723-62-6 ]
[ 194861-72-8 ]
[ 20667-12-3 ]
[Ag₂(μ-aca)₂(μ-9,10-bis(4-pyridyl)anthracene)₂]*EtOH*2H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
15%	at 20℃; for 0.5h;

Reference： [1]Chen, Cong-Cong; Cai, Yue; Wang, Long-Fei; Wu, Yun-Dang; Yin, Hao-Jun; Zhou, Jia-Rong; Ni, Chun-Lin; Liu, Wei [Inorganic Chemistry, 2021, vol. 60, # 8, p. 5463 - 5473]

40
[ 65-85-0 ]
[ 194861-72-8 ]
[ 20667-12-3 ]
[Ag(μ-bza)(μ-9,10-bis(4-pyridyl)anthracene)] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
42%	With ammonium hydroxide In ethanol at 20℃; for 0.5h;

Reference： [1]Chen, Cong-Cong; Cai, Yue; Wang, Long-Fei; Wu, Yun-Dang; Yin, Hao-Jun; Zhou, Jia-Rong; Ni, Chun-Lin; Liu, Wei [Inorganic Chemistry, 2021, vol. 60, # 8, p. 5463 - 5473]

41
zinc(II) nitrate hexahydrate [ No CAS ]
[ 14609-54-2 ]
[ 33513-42-7 ]
[ 194861-72-8 ]
C₂₄H₁₆N₂*C₄₈H₂₆N₄O₈^(4-)*2Zn⁽²⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With nitric acid In ethanol at 80℃; for 72h;

Reference： [1]Chen, Qiang; Xian, Shikai; Dong, Xinglong; Liu, Yanyao; Wang, Hao; Olson, David H.; Williams, Lawrence J.; Han, Yu; Bu, Xian-He; Li, Jing [Angewandte Chemie - International Edition, 2021, vol. 60, # 19, p. 10593 - 10597][Angew. Chem., 2021, vol. 133, # 19, p. 10687 - 10691,5]

42
zinc(II) nitrate hexahydrate [ No CAS ]
[5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]-Pd(II) [ No CAS ]
[ 33513-42-7 ]
[ 194861-72-8 ]
[Zn₂([5,10,15,20-tetrakis-(4-methoxycarbonylphenyl)porphyrinato]-Pd^II)(9,10-bis(4-pyridyl)-anthracene)]*N,N’-dimethylformamide [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	With nitric acid In ethanol at 80℃; for 72h;

Reference： [1]Chen, Qiang; Xian, Shikai; Dong, Xinglong; Liu, Yanyao; Wang, Hao; Olson, David H.; Williams, Lawrence J.; Han, Yu; Bu, Xian-He; Li, Jing [Angewandte Chemie - International Edition, 2021, vol. 60, # 19, p. 10593 - 10597][Angew. Chem., 2021, vol. 133, # 19, p. 10687 - 10691,5]

43
zinc(II) nitrate hexahydrate [ No CAS ]
5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinatozinc(II) [ No CAS ]
[ 33513-42-7 ]
[ 194861-72-8 ]
C₂₄H₁₆N₂*C₃H₇NO*3Zn⁽²⁺⁾*C₄₈H₂₄N₄O₈^(6-) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With nitric acid In ethanol at 80℃; for 72h;

Reference： [1]Chen, Qiang; Xian, Shikai; Dong, Xinglong; Liu, Yanyao; Wang, Hao; Olson, David H.; Williams, Lawrence J.; Han, Yu; Bu, Xian-He; Li, Jing [Angewandte Chemie - International Edition, 2021, vol. 60, # 19, p. 10593 - 10597][Angew. Chem., 2021, vol. 133, # 19, p. 10687 - 10691,5]

44
cadmium nitrate dihydrate [ No CAS ]
cyclohexane-1,4-dicarboxylic acid [ No CAS ]
[ 33513-42-7 ]
[ 194861-72-8 ]
[Cd(9,10-di(4-pyridyl)anthracene)₂(cda)(H₂O)]_n.nDMF [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	In water at 80℃; for 72h; Autoclave;

Reference： [1]Dong, Wei; Huang, Wei; Liu, Xing-Gui; Lu, Zhen-Zhong; Meng, Mei-Mei; Wang, Li-Fei; Xi, Ji-Ming; Xu, Yong-Kai; Zhang, Rui; Zheng, He-Gen; Zhu, Rui [Dalton Transactions, 2021, vol. 50, # 23, p. 7944 - 7948]

45
cadmium nitrate dihydrate [ No CAS ]
cyclohexane-1,4-dicarboxylic acid [ No CAS ]
[ 194861-72-8 ]
[Cd(9,10-di(4-pyridyl)anthracene)₂(cda)]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
81%	In N,N-dimethyl-formamide at 80℃; for 72h; Autoclave;

Reference： [1]Dong, Wei; Huang, Wei; Liu, Xing-Gui; Lu, Zhen-Zhong; Meng, Mei-Mei; Wang, Li-Fei; Xi, Ji-Ming; Xu, Yong-Kai; Zhang, Rui; Zheng, He-Gen; Zhu, Rui [Dalton Transactions, 2021, vol. 50, # 23, p. 7944 - 7948]

46
[ 7647-01-0 ]
cadmium nitrate dihydrate [ No CAS ]
cyclohexane-1,4-dicarboxylic acid [ No CAS ]
[ 194861-72-8 ]
[Cd₂(9,10-di(4-pyridyl)anthracene)₂(cda)Cl₂]_n [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In water; N,N-dimethyl-formamide at 80℃; for 72h; Autoclave;

Reference： [1]Dong, Wei; Huang, Wei; Liu, Xing-Gui; Lu, Zhen-Zhong; Meng, Mei-Mei; Wang, Li-Fei; Xi, Ji-Ming; Xu, Yong-Kai; Zhang, Rui; Zheng, He-Gen; Zhu, Rui [Dalton Transactions, 2021, vol. 50, # 23, p. 7944 - 7948]

47
[ 165336-82-3 ]
disodium isophthalate [ No CAS ]
[ 194861-72-8 ]
C₁₁₂H₁₃₆F₂₄N₄O₃₂P₈Pt₄S₈ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In water; acetone at 60℃; for 12h;	Results and Discussion Here, ANTHR-based metallacycle was synthesized using ANTHRbasedligands (9,10-di(pyridin-4-yl)anthracene [DPA]), dicarboxylatemoieties (isophthalic acid [IPA2-]), and cis-(PEt3)2Pt(OTf)2. Themetallacycle was readily prepared using a heteroligation-directedthree-component CDSA strategy. As shown in Scheme 1 A and B,metallacycle 1 was formed by the reaction of pyridyl-functionalizedANTHR ligand (2), dicarboxylate ligand (3), and phosphine-capped90° Pt(II) acceptor (4) at a molar ratio of 1:1:2. Compounds 2 and 3were dissolved in acetone and water, respectively. The two solutionswere then mixed, and 4 in acetone was added. After heating at60 °C for 12 h, the solvent was evaporated via N2 flow. The resultantproduct 1 was obtained after drying under vacuum (SI Appendix).

Reference： [1]Chen, Chongyi; Li, Dan; Sepehrpour, Hajar; Stang, Peter J.; Sun, Yan; Tuo, Wei; VanderLinden, Ryan T.; Wang, Jin; Yan, Chaoguo; Zhang, Fengmin; Zhang, Shuwei; Zhao, Yue [Proceedings of the National Academy of Sciences of the United States of America, 2021, vol. 118, # 27]

Same Skeleton Products

Related Products

Historical Records

Ghs Precautionary Statements

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Ghs Hazard Statements

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere