630-580-1088 sales@ambeed.com
Structure Search

List Search MOL Search Structure Search

0
Chemistry
Asymmetric Synthesis >>Chiral Building BlocksChiral Catalysts, Chiral Ligands and Chiral ReagentsChiral Resolution ReagentsBoronic acids/esters >>Aliphatic BoronsAromatic BoronsOther BoronsOxaborolesCatalysis Chemistry >>Achiral Crown LigandsC-H ActivationCarbon-Donor LigandsChiral Carbon LigandsChiral Crown LigandsChiral Olefin LigandsCross-CouplingCross-Coupling Using Transition Metal CatalystsDACH or Trost LigandsChemical Biology >>Conjugation Chemistry
GlycoscienceLinkers and CrosslinkersNucleic Acid ChemistryPEGylationPeptide ChemistryPhotolabile Protecting GroupHeterocyclic Building Blocks >>AcridinesAliphatic HeterocyclesAromatic HeterocyclesAzetidinesBenzimidazolesBenzisoxazolesBenzodioxansBenzofuransBenzothiazolesInorganic reagents >>Inorganic ReagentOrganic Building Blocks >>Acid AnhydridesAcyl Chlorides
AlcoholsAldehydesAliphatic Chain HydrocarbonsAliphatic Cyclic HydrocarbonsAlkenesAlkylsAlkynesOrganometallic Reagents >>Grignard ReagentsOrganoarsenicOrganobismuthOrganoboronOrganogermaniumOrganolithiumOrganomercuryOrganosiliconOrganotinSpecialty Synthesis >>Enzyme-Mediated SynthesisFluorous SynthesisIonic Liquids
Solid Supported SynthesisStains and Dyes >>Acid DyesAzoic DyesBasic DyesDirect DyesDisperse DyesDye IntermediatesMordant DyesOil DyesOther Stains and DyesSynthetic Reagents >>Acids and BasesC-C Bond FormationC-X Bond Formation (Halogen)C-X Bond Formation (Non-Halogen)Chelation and Complexation CompoundsCondensation AgentsCouplingDehydrating ReagentsFluorination Reagent
Pharmaceutical Intermediates
Analgesics >>BenzhydrocodoneBicifadineCapsaicinCelecoxibDebio-0827DexamethasoneElagolix SodiumEsketamine HydrochlorideIbuprofen SodiumAnesthetics >>CiprofolEsketamine HydrochlorideFospropofol Fospropofol DisodiumLevobupivacaine RemimazolamRemimazolam BesilateRemimazolam BesylateRopivacaineAnti-Addiction Agents >>Kakonein
Lofexidine HydrochlorideVarenicline Anti-inflammatory Agents >>ApremilastAsunaprevirATB-346 RelatedBalsalazide BaricitinibBencycloquidium BromideBudesonideCefiderocol Sulfate TosylateCeftaroline Fosamil AcetateAntibacterials >>AFN-1252 RelatedAlatrofloxacin Bedaquiline FumarateBesifloxacin BrilacidinCaspofungin AcetateCefiderocol Sulfate TosylateCefilavancinCeftaroline Fosamil
Anticonvulsants >>BrivaracetamCannabidiolEscitalopram OxalateEslicarbazepine Acetate RelatedFosphenytoinGabapentin EnacarbilJNJ-10234094LacosamideLevetiracetam RelatedAntidementia Agents >>Azeliragon RelatedDavunetideDonepezil HydrochlorideDonepezil RelatedEnsaculinFlorbetaben Flortaucipir F 18Flutemetamol IdalopirdineAntidepressants >>4-Chlorokynurenine
AgomelatineAgomelatine RelatedAllopregnanolone RelatedAmibegronAmitifadineAripiprazole RelatedBasimglurantBefloxatoneAntiemetics >>AprepitantAprepitant RelatedDolasetron RelatedDolasetron Mesylate HydrateFosaprepitant DimeglumineFosaprepitant RelatedOlanzapinePalonosetron RelatedPalonosetron HydrochlorideAntifungals >>Anidulafungin RelatedCabotegravirMore >>
Inhibitors/Agonists
ADC >>ADC AntibodyADC LinkerADC Linker with PayloadADC ToxinAntibody-Drug Conjugates (ADCs)Drug-Linker Conjugates for ADCAngiogenesis >>ALKBcr-AblBTKEGFRFAKFGFRFLT3HER2HIFAnti-infection >>3CLproAntibacterialAntibioticAntifungal
AntiparasiticAntiprotozoalAntiviralArenavirusBVDVApoptosis >>Apoptosis InducerBcl-2Bcl-6BRKc-Mycc-RETC/EBPCARDCaspaseAutophagy >>Atg4ATG4BATTECsAUTACsAutophagyBeclin1
FKBPLC3LRRK2Biochemical Reagent >>Cell Cycle >>AntifolateAPCAurora KinaseBUBCasein KinaseCdc25CDKChkCRISPR/Cas9Cytoskeleton >>ActinArp2/3 ComplexCYTHCytoplasmic DyneinDynaminFAKMore >>
Material Science
Aggregation-Induced Emission >>Other AIE BlocksTetraphenylethylene SeriesCOFs Linkers >>Aldehyde COFs LinkersAlkynyl COFs LinkersAmine COFs LinkersBoric COFs LinkersCyano COFs LinkersMultifunctional COFs linkersOther COFs linkersTriptycene SeriesElectronic Materials >>Battery MaterialsDye-Sensitized Solar Cell (DSSC) MaterialsElectronic MaterialLiquid Crystal (LC) MaterialsMolecular ConductorsOrganic Light-Emitting Diode (OLED) MaterialsOrganic Solar Cell (OPV) MaterialsOrganic Transistor (OFET) MaterialsPerovskite Solar Cell (PSC) MaterialsMagnetic Materials >>Magnetic Ionic LiquidsMagnetic MaterialMagnetic Metal Complexes
Organic Radicals Material Chemical Compounds >>Ligands for Functional Metal ComplexesLiquid Crystal (LC) Building BlocksPhthalocyanine Building BlocksPolymer and Macromolecule Semiconductor Building BlocksSmall Molecule Semiconductor Building BlocksSolubility Enhancing Reagents Supramolecular Host Materials MOF Ligands >>Carboxylic Acid MOF LigandsCarboxylic Acid Nitrogen-Containing Mixed MOF LigandsNitrogen-Containing MOF LigandsOther MOF LigandsNanomaterials >>Carbon NanomaterialsCeramic MembranesDendrimersGold NanoparticlesIron Oxide NanoparticlesMaterials by ApplicationMesoporous MaterialsMetals and Metal AlloysNano Minerals: NanoclaysOLED Materials >>Dopant
HostHTMOLED IntermediatesOther OLED related materialsOptical Materials >>Coumarin DyesCyanine and Squarylium DyesDCM DyesDipyrromethene DyesFluorescence MaterialsFluorescent ProbesHeat and Pressure Sensitive DyesNear-Infrared (NIR) DyesOrganic Non-Linear Optical (NLO) MaterialsOrganic Pigments >>Organic PigmentOther Materials >>Mateial OtherPolymer Science >>MonomersPolymer AdditivesPolymerization ReagentsPolymersResins
Contact Us
Home Cart 0 Sign in  
Chemistry
Organic Building Blocks
Carboxylic Acids
dibenzoic
4,4'-((1H-1,2,4-Triazol-1-yl)methylene)dibenzoic acid
Chemistry
Material Science
Organic Building Blocks
MOF Ligands Heterocyclic Building Blocks
Carboxylic Acids
Benzene Compounds Carboxylic Acid Nitrogen-Containing Mixed MOF Ligands Aromatic Heterocycles
dibenzoic
Ternary Carboxylic Acid Nitrogen-Containing Mixed Ligands

[ CAS No. 1644566-39-1 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 1644566-39-1
Chemical Structure| 1644566-39-1
Structure of 1644566-39-1 * Storage: {[proInfo.prStorage]}
Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

For Research Only 110K+ Compounds Competitive Price 1-2 Day Shipping

Quality Control of [ 1644566-39-1 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 1644566-39-1 ]

SDS Specification
Alternatived Products of [ 1644566-39-1 ]

Product Details of [ 1644566-39-1 ]

CAS No. :1644566-39-1 MDL No. :
Formula : C17H13N3O4 Boiling Point : -
Linear Structure Formula :- InChI Key :OMYQMDBEDMTHOJ-UHFFFAOYSA-N
M.W : 323.30 Pubchem ID :145710611
Synonyms :

Safety of [ 1644566-39-1 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1644566-39-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1644566-39-1 ]

[ 1644566-39-1 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 112809-51-5 ]
  • 4,4′-(1H-1,2,4-triazol-1-yl)methylene-bis(benzoic acid) [ No CAS ]
YieldReaction ConditionsOperation in experiment
94.9% Stage #1: letrozol With sodium hydroxide In water for 6h; Reflux; Stage #2: With hydrogenchloride In water
86.1% Stage #1: letrozol With potassium hydroxide In ethanol; water for 36h; Reflux; Stage #2: With hydrogenchloride In water
77% Stage #1: letrozol With sodium hydroxide In N,N-dimethyl-formamide at 120℃; for 12h; Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide Synthesis of H2ltzdc. A mixture of 1-[bis(4-cyanophenyl)methyl]-1,2,4-triazole (5.7 g, 20 mmol) with 3 M NaOH (2.4 g, 60 mmol in 20 mL H2O) in DMF (20 mL)was heated at 120°C for 12 h. Then the reaction mixturewas poured onto ice, acidifi ed with conc. HCl to pH 1,saturated with solid NaCl, and extracted with TBME. Theorganic layer was dried over MgSO4. After fi ltration, thesolvent was removed in vacuum to afford the product asoff-white solid, yield 77%. It was used further withoutadditional purifi cation. IR spectrum, ν, cm-1: 3389-2700(CO-OH), 1696(C=O), 1605 (C=C), 1503 (C=C), 1435(C=C), 1300 (C-O), 835 (C-H). 1H NMR spectrum, δ,ppm: 8.52 (1H, triazole), 8.08 (1H, triazole), 8.04-8.03(4H, C6H4), 7.36-7.34 (4H, C6H4), 7.15 (1H, CH). 13CNMR spectrum, δ, ppm: 169.07, 152.87, 145.70, 144.16,132.23, 131.25, 129.53, 67.60.
97.43 %Spectr. With [Rh(6,7-dihydrotribenzo-[e,i,m][1,4,7,12]-ioxadiazacyclotetradecine)]Cl; water; sodium hydroxide at 70℃; for 0.25h; Hydrolysis of Letrozole In a 100 ml round bottom (RB) flask, 3 ml of LTZ solution (200 lg/ml), 3 ml of NaOH and [Rh(HBACHD)]Cl (Comp.1, 0.02 mmol) were taken and refluxed for 15 min. The contents of RB flask were cooled for 10 min and transferred to 20 ml calibrated tubes. Now, 5 ml of ferric chloride was added to each tube and the total volumes were made up to 20 ml with double distilled water and kept aside for 5 min. The absorbance of the yellow colored solutions was measured at 380 nm against a similar reagent blank (Fig. S1). The amount of HLTZ was assayed from the calibration curve (Fig. S1). The procedure was repeated by changing the rhodium catalysts.
Alkaline conditions;

Reference： [1]Zhang, Da-Shuai; Zhang, Yong-Zheng; Gao, Jun; Liu, Hui-Ling; Hu, Hui; Geng, Long-Long; Zhang, Xiuling; Li, Yun-Wu [Dalton Transactions, 2018, vol. 47, # 39, p. 14025 - 14032]
[2]Si, Jin-Ping; Wang, Wen-Jing; Chang, Jun; Huang, Kun-Lin; Zhang, Zhi-Hui; Chen, Sheng-Chun; He, Ming-Yang; Chen, Qun [Zeitschrift fur Anorganische und Allgemeine Chemie, 2020, vol. 646, # 21, p. 1739 - 1747]
[3]Kang; Fu; Xin; Jiu; Wang; Liu [Russian Journal of General Chemistry, 2020, vol. 90, # 12, p. 2365 - 2370]
[4]Reddy, P. Muralidhar; Shanker; Srinivas; Krishna, E. Ravi; Rohini; Srikanth; Hu, Anren; Ravinder [Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, vol. 139, # 1, p. 43 - 48]
[5]An, Jun Dan; Ding, Bin; Huo, Jian Zhong; Liu, Yuan Yuan; Shi, Yang Fan; Wang, Tian Tian; Wu, Xiang Xia [Journal of Molecular Structure, 2020, vol. 1216]
  • 2
  • [ CAS Unavailable ]
  • [ 127-19-5 ]
  • [ 1644566-39-1 ]
  • [ 7732-18-5 ]
  • [ 25372-07-0 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
58% With sodium hydroxide In ethanol at 100℃; for 50h; Autoclave; High pressure; 2.2.2 [Mn2(TZMB)2(1,4-bib)0.5(H2O)2]·(H2O)2(DMA)}n (2) The synthetic procedure of complex 2 is similar to 1 except that H2TZMB (0.024mmol, 7.8mg), 1,4-bib (0.024mmol, 5.0mg) and MnCl2·4H2O (0.024mmol, 4.73mg) were dissolved in mixed DMA/EtOH/H2O (3mL, v:v:v=1:1:1), added a bit of NaOH aqueous solution (0.05mL, 0.25mol·L-1) and heated at 100°C. The colorless block crystals of 2 were obtained with a yield of 58% (based on H2TZMB). Anal. Calc. (%) for C44H44N9O13Mn2: C, 51.92; H, 4.32; N, 12.39. Found (%): C, 51.34; H, 4.51; N, 12.89. IR (KBr pellet, cm-1): 3460 (w), 3145 (w), 1652 (m), 1614 (s), 1558 (vs), 1417 (vs), 1272 (w), 1124 (w), 995 (w), 838 (w), 779 (w), 649 (w).
Reference： [1]Hu, Tuo-Ping; Li, Miao-Miao; Huang, Ya-Ru; Gao, Ling-Ling; Wang, Xiao-Qing; Gao, Jian-Feng; Niu, Xiao-Yan [Polyhedron, 2018, vol. 151, p. 306 - 312]
  • 3
  • cadmium(II) nitrate hexahydrate [ No CAS ]
  • [ 56643-83-5 ]
  • 4,4′-(1H-1,2,4-triazol-1-yl)methylene-bis(benzoic acid) [ No CAS ]
  • Cd(2+)*2.5H2O*0.5C14H14N4*C17H11N3O4(2-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
49% With sodium hydroxide In water at 150℃; for 48h; High pressure; Autoclave; [Cd(TZMB)(1,4-bimb)0.5]*2.5H2O} (1) A mixture of H2TZMB (0.024mmol, 7.8 mg), 1,4-bimb (0.024mmol, 7.3 mg) Cd(NO3)2*6H2O(0.036mmol, 11.1mg), NaOH (0.10 ml, 0.25mol/L) aqueous solution and 3mL H2O was sealed in a 25mL Teflon-lined stainless steel vessel and heated at 150 °C for 2880 min, then cooled to 25 C. Colorless block crystals of 1 were obtained with the yield of 49% (based on H2TZMB). Anal. Calcd (%) for C24H23N5O6Cd: C, 48.86; H, 3.93; N, 11.87. Found (%):C, 49.02; H, 3.64; N, 11.91. IR (KBr pellet, cm-1): 3447 (m), 3130 (m),1606 (w), 1590 (s), 1554 (s), 1388 (s), 1075 (s), 844 (s), 744 (s) (Fig. S1).
Reference： [1]Zhang, Jie; Gao, Lingling; Wang, Yang; Zhai, Lijun; Wang, Xiaoqing; Niu, Xiaoyan; Hu, Tuoping [Journal of Solid State Chemistry, 2019, vol. 277, p. 356 - 362]
  • 4
  • [ 51-17-2 ]
  • [ CAS Unavailable ]
  • [ CAS Unavailable ]
  • [ 127-19-5 ]
  • [ 1644566-39-1 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
88.35% With sodium hydroxide In water at 110℃; for 50h; Sealed tube; 2.2.1. Synthesis of [Zn2((TZMB)2(bim)]*2DMA*EtOH}n (1) NaOH (0.01 mol/L, 0.8 mL) was added into the mixture of the H2TZMB ligand (0.004 mmol, 1.3 mg) and a mixed solvent of DMA/EtOH/H2O (1 mL, v/v/v 2:1:1), and then the mixture was transferred into a glass tube containing bim (0.008 mmol, 0.9 mg) and Zn(NO3)2*6H2O (0.008 mmoL, 2.4 mg). The glass tube was sealed and heated at 110 °C for 3000 min and then naturally cooled to ambient temperature to obtain colorless block crystals. Yield: 88.35% (based on Zn). Anal. calcd (%) for C51H51Zn2N10O11: C, 55.14; H, 4.63; N, 12.61. Found (%): C, 55.02; H, 4.49; N, 12.89. IR (KBr pellet, cm-1): 3448 (vs), 2370 (w), 1616 (s), 1558 (s), 1419 (s), 1282 (s), 1122 (s), 995 (m), 842 (m), 756 (m), 649 (m).
Reference： [1]Liang, Jinfang; Liang, Jinxia; Zhai, Lijun; Wu, Haonan; Niu, Xiaoyan; Zhang, Jie; Hu, Tuoping [Journal of Solid State Chemistry, 2019, vol. 280]

Tags: 1644566-39-1 synthesis path| 1644566-39-1 SDS| 1644566-39-1 COA| 1644566-39-1 purity| 1644566-39-1 application| 1644566-39-1 NMR| 1644566-39-1 COA| 1644566-39-1 structure

Same Skeleton Products
Related Products
Categories
Chemistry
Organic Building Blocks
Carboxylic Acids
dibenzoic
Chemistry
Organic Building Blocks
Benzene Compounds
dibenzoic
Material Science
MOF Ligands
Carboxylic Acid Nitrogen-Containing Mixed MOF Ligands
Ternary Carboxylic Acid Nitrogen-Containing Mixed Ligands
Chemistry
Heterocyclic Building Blocks
Aromatic Heterocycles
Historical Records

Related Parent Nucleus of
[ 1644566-39-1 ]

Aromatic Heterocycles

Chemical Structure| 31250-99-4

[ 31250-99-4 ]

1-Trityl-1H-1,2,4-triazole

Similarity: 0.80

Chemical Structure| 31250-99-4

[ 31250-99-4 ]

1-Trityl-1H-1,2,4-triazole

Similarity: 0.80