Alternatived Products of [ 1639134-02-3 ]
Product Details of [ 1639134-02-3 ]
CAS No. : | 1639134-02-3 |
MDL No. : | N/A |
Formula : |
C34H20O4S4
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | RLELZGCAYDJDTI-UHFFFAOYSA-N |
M.W : |
620.78
|
Pubchem ID : | 129896763 |
Synonyms : |
|
Safety of [ 1639134-02-3 ]
Application In Synthesis of [ 1639134-02-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1639134-02-3 ]
- 1
-
[ 33228-45-4 ]
-
2,3,6,7-tetra(4-formylphenyl)tetrathiafulvalene
[ No CAS ]
-
C82H88N4S4
[ No CAS ]
- 2
-
[ 31366-25-3 ]
-
[ 1122-91-4 ]
-
2,3,6,7-tetra(4-formylphenyl)tetrathiafulvalene
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
40% |
With palladium diacetate; PtBu<SUB>3</SUB>HBF<SUB>4</SUB>; caesium carbonate In tetrahydrofuran for 48h; Reflux; Inert atmosphere; |
|
38% |
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran for 48h; Inert atmosphere; Reflux; |
|
36% |
With tris(isopropyl)phosphonium tetrafluoroborate; palladium diacetate; caesium carbonate In tetrahydrofuran for 24h; Inert atmosphere; Reflux; |
|
30% |
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 75℃; for 30h; Schlenk technique; Inert atmosphere; |
|
25% |
With tri-tert-butylphosphonium tetrafluoroborate; palladium diacetate; caesium carbonate In tetrahydrofuran for 15h; Reflux; Inert atmosphere; |
|
Reference:
[1]Chang, Jianhong; Fang, Qianrong; Guan, Xinyu; Li, Cuiyan; Li, Daohao; Li, Hui; Li, Shanshan; Qiu, Shilun; Tang, Lingxue; Valtchev, Valentin; Xue, Ming; Yan, Yushan
[Journal of the American Chemical Society, 2019]
[2]Ding, Huimin; Li, Yonghai; Hu, Hui; Sun, Yimeng; Wang, Jianguo; Wang, Caixing; Wang, Cheng; Zhang, Guanxin; Wang, Baoshan; Xu, Wei; Zhang, Deqing
[Chemistry - A European Journal, 2014, vol. 20, # 45, p. 14614 - 14618]
[3]Jin, Shangbin; Sakurai, Tsuneaki; Kowalczyk, Tim; Dalapati, Sasanka; Xu, Fei; Wei, Hao; Chen, Xiong; Gao, Jia; Seki, Shu; Irle, Stephan; Jiang, Donglin
[Chemistry - A European Journal, 2014, vol. 20, # 45, p. 14608 - 14613]
[4]Lu, Meng; Liu, Jiang; Li, Qiang; Zhang, Mi; Liu, Ming; Wang, Jin-Lan; Yuan, Da-Qiang; Lan, Ya-Qian
[Angewandte Chemie - International Edition, 2019, vol. 58, # 36, p. 12392 - 12397][Angew. Chem., 2019, vol. 131, p. 12522 - 12527,6]
[5]Cai, Song-Liang; Zhang, Yue-Biao; Pun, Andrew B.; He, Bo; Yang, Jinhui; Toma, Francesca M.; Sharp, Ian D.; Yaghi, Omar M.; Fan, Jun; Zheng, Sheng-Run; Zhang, Wei-Guang; Liu, Yi
[Chemical Science, 2014, vol. 5, # 12, p. 4693 - 4700]
- 3
-
[ 1639134-02-3 ]
-
[ 62-53-3 ]
-
[ 1807606-81-0 ]
Yield | Reaction Conditions | Operation in experiment |
94% |
In toluene at 130℃; for 5h; Dean-Stark; |
|
Reference:
[1]Cai, Song-Liang; Zhang, Yue-Biao; Pun, Andrew B.; He, Bo; Yang, Jinhui; Toma, Francesca M.; Sharp, Ian D.; Yaghi, Omar M.; Fan, Jun; Zheng, Sheng-Run; Zhang, Wei-Guang; Liu, Yi
[Chemical Science, 2014, vol. 5, # 12, p. 4693 - 4700]
- 4
-
[ CAS Unavailable ]
-
[ 1639134-02-3 ]
-
[ CAS Unavailable ]
Yield | Reaction Conditions | Operation in experiment |
70% |
With acetic acid In water; 1,2-dichloro-benzene at 140℃; for 120h; Sonication; Sealed tube; |
1 Example 1
5 mg (0.01 mmol) of tetrakis tetrahedral configuration of tetrakis(4-anilino)adamantane (TAPA) and 6.2 mg (0.01 mmol)Tetrakis(p-butyryl)tetrathiafulvalene (TTF-Ph-CHO) was added to an ampoule, 1 mL of o-dichlorobenzene was added, ultrasonically mixed uniformly, and then 0.1 mL (6 mol/L) of aqueous acetic acid solution was added. The ampoule was placed in liquid nitrogen for freezing, vacuumed and flame sealed, sealed in an oven, and heated to 140 ° C for 5 days. After the reaction is completed, the obtained solid is transferred to a centrifuge tube.The mixture was washed 5 times with N,N-dimethylformamide and tetrahydrofuran, and dried under vacuum at 80 ° C for 12 h to obtain 7 mg of dark red solid powder COF-TTF-Ad in a yield of 70%. |
- 5
-
2,3,6,7-tetra(4-formylphenyl)tetrathiafulvalene
[ No CAS ]
-
[ 16004-77-6 ]
-
C74H92N16S4
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
75% |
With acetic acid In water; 1,2-dichloro-benzene; butan-1-ol at 120℃; for 72h; Sealed tube; |
|
Reference:
[1]Chang, Jianhong; Fang, Qianrong; Guan, Xinyu; Li, Cuiyan; Li, Daohao; Li, Hui; Li, Shanshan; Qiu, Shilun; Tang, Lingxue; Valtchev, Valentin; Xue, Ming; Yan, Yushan
[Journal of the American Chemical Society, 2019]
- 6
-
[ 60532-63-0 ]
-
[ 1639134-02-3 ]
-
[ CAS Unavailable ]
Yield | Reaction Conditions | Operation in experiment |
78% |
With acetic acid In water; 1,2-dichloro-benzene; butan-1-ol at 120℃; for 72h; Sealed tube; |
|
Reference:
[1]Chang, Jianhong; Fang, Qianrong; Guan, Xinyu; Li, Cuiyan; Li, Daohao; Li, Hui; Li, Shanshan; Qiu, Shilun; Tang, Lingxue; Valtchev, Valentin; Xue, Ming; Yan, Yushan
[Journal of the American Chemical Society, 2019]