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[ CAS No. 1581771-50-7 ] {[proInfo.proName]}

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Chemical Structure| 1581771-50-7
Chemical Structure| 1581771-50-7
Structure of 1581771-50-7 * Storage: {[proInfo.prStorage]}
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Product Details of [ 1581771-50-7 ]

CAS No. :1581771-50-7 MDL No. :
Formula : C26H16N4S4 Boiling Point : -
Linear Structure Formula :- InChI Key :ABNARIHKWRBIIL-UHFFFAOYSA-N
M.W : 512.69 Pubchem ID :13295747
Synonyms :

Safety of [ 1581771-50-7 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P280-P301+P312-P302+P352-P305+P351+P338 UN#:
Hazard Statements:H302-H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1581771-50-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1581771-50-7 ]

[ 1581771-50-7 ] Synthesis Path-Downstream   1~21

  • 1
  • [ 31366-25-3 ]
  • [ 15854-87-2 ]
  • [ 1581771-50-7 ]
YieldReaction ConditionsOperation in experiment
71% With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane for 24h; Inert atmosphere; Reflux;
  • 2
  • [ 1263416-32-5 ]
  • [ 1581771-50-7 ]
  • C140H144N8O16Ru8S8(8+)*8CF3O3S(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
81% In methanol at 20℃; for 12h;
  • 3
  • [ 1263416-33-6 ]
  • [ 1581771-50-7 ]
  • C78H76N4O8Ru4S4(4+)*4CF3O3S(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% In methanol at 20℃; for 12h;
  • 4
  • manganese bis(1,1,1,5,5,5-hexafluoroacetylacetonato) dihydrate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • [Mn(hfac)2][tetra(4-pyridyl)tetrathiafulvalene]0.5 [ No CAS ]
YieldReaction ConditionsOperation in experiment
62% In acetonitrile at 20℃; for 168h;
  • 5
  • manganese(II) chloride dihydrate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • [ 333-20-0 ]
  • [Mn(SCN)2][tetra(4-pyridyl)tetrathiafulvalene]*6(CH2Cl2) [ No CAS ]
YieldReaction ConditionsOperation in experiment
68% Stage #1: manganese(II) chloride dihydrate; potassium thioacyanate In methanol for 0.166667h; Stage #2: dichloromethane; tetra(4-pyridyl)-tetrathiafulvalene In methanol at 20℃; for 120h;
  • 6
  • tetrakis(acetonitrile)copper(I) perchlorate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • Cu2[tetra(4-pyridyl)tetrathiafulvalene]2*(ClO4)2*2.5(CH2Cl2)*1.5(CH3CN) [ No CAS ]
YieldReaction ConditionsOperation in experiment
73% In acetonitrile at 20℃; for 168h;
  • 7
  • copper(II) bis(hexafluoroacetylacetonate) dihydrate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • [Cu-(hfac)2][tetra(4-pyridyl)tetrathiafulvalene]*2(CH2Cl2) [ No CAS ]
YieldReaction ConditionsOperation in experiment
73% In acetonitrile at 20℃; for 168h;
  • 8
  • [ 67-66-3 ]
  • [ 1581771-50-7 ]
  • cobalt(II) aceylacetonate [ No CAS ]
  • [Co(acac)2][tetra(4-pyridyl)tetrathiafulvalene]0.5*(CHCl3) [ No CAS ]
YieldReaction ConditionsOperation in experiment
57% In acetonitrile at 20℃; for 96h;
  • 9
  • [ 1581771-50-7 ]
  • [ 142-71-2 ]
  • [ 75-05-8 ]
  • [Cu2(OAc)4][tetra(4-pyridyl)tetrathiafulvalene]0 .5*1.5(CHCl3)*0.5(H2O)*(CH3CN) [ No CAS ]
YieldReaction ConditionsOperation in experiment
68% at 20℃; for 96h;
  • 10
  • manganese(II) chloride dihydrate [ No CAS ]
  • [ 1581771-50-7 ]
  • [ 3425-46-5 ]
  • [Mn(SeCN)Cl][tetra(4-pyridyl)tetrathiafulvalene] [ No CAS ]
YieldReaction ConditionsOperation in experiment
71% Stage #1: manganese(II) chloride dihydrate; potassium selenocyanate In methanol for 0.166667h; Stage #2: tetra(4-pyridyl)-tetrathiafulvalene In methanol; dichloromethane at 20℃; for 120h;
  • 11
  • [ 67-56-1 ]
  • ferrous perchlorate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • [ 1934-75-4 ]
  • [Fe(dicyanamide)][tetra(4-pyridyl)tetrathiafulvalene]*ClO4*CH2Cl2*2CH3OH}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
68% Stage #1: methanol; ferrous perchlorate; sodium dicyanamide at 20℃; for 1h; Stage #2: dichloromethane; tetra(4-pyridyl)-tetrathiafulvalene at 20℃; for 168h;
  • 12
  • ferrous perchlorate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • [ 1934-75-4 ]
  • [Fe(dicyanamide)2][tetra(4-pyridyl)tetrathiafulvalene]0.5*0.5CH2Cl2}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
73% Stage #1: ferrous perchlorate; sodium dicyanamide In methanol at 20℃; for 1h; Stage #2: dichloromethane; tetra(4-pyridyl)-tetrathiafulvalene In methanol at 20℃; for 168h;
  • 13
  • [ 1581771-50-7 ]
  • (Re(CO)<SUB>4</SUB>)<SUB>3</SUB>(cyanurate trianion) [ No CAS ]
  • [ 33513-42-7 ]
  • [ 75-05-8 ]
  • [(Re(CO)3)12(TTF(py)4)3(C3N3S3)4]*8CH3CN*12DMF [ No CAS ]
YieldReaction ConditionsOperation in experiment
13.4% Stage #1: tetra(4-pyridyl)-tetrathiafulvalene; (Re(CO)<SUB>4</SUB>)<SUB>3</SUB>(cyanurate trianion); N,N-dimethyl-formamide; acetonitrile for 0.166667h; Stage #2: at 100℃; for 48h; Sealed tube;
  • 14
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 75-09-2 ]
  • [ 1581771-50-7 ]
  • [ 1283-90-5 ]
  • [Cd(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)•-)1/2]((7,7,8,8-tetracyanoquinodimethane)•-)1/2(NO3)*CH2Cl2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% In methanol at 20℃; for 168h; Inert atmosphere;
  • 15
  • [ 67-56-1 ]
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 1581771-50-7 ]
  • [ 1283-90-5 ]
  • [Zn(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)•-)1/2]((7,7,8,8-tetracyanoquinodimethane)•-)1/2(NO3)*2CH3OH [ No CAS ]
YieldReaction ConditionsOperation in experiment
42% In dichloromethane at 20℃; for 168h; Inert atmosphere;
  • 16
  • [ 67-56-1 ]
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 75-09-2 ]
  • [ 18643-56-6 ]
  • [ 1581771-50-7 ]
  • [Cd(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)2-)1/2]((7,7,8,8-tetracyanoquinodimethane)•-)1/2(NO3)1/2*CH2Cl2*1/2CH3OH [ No CAS ]
YieldReaction ConditionsOperation in experiment
31% With lithium acetate In N,N-dimethyl-formamide at 20℃; for 168h; Inert atmosphere;
  • 17
  • [ 67-56-1 ]
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 18643-56-6 ]
  • [ 1581771-50-7 ]
  • [Cd(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)2-)1/2](NO3)*CH3OH [ No CAS ]
YieldReaction ConditionsOperation in experiment
31% With lithium acetate In dichloromethane; N,N-dimethyl-formamide at 20℃; for 168h; Inert atmosphere;
  • 18
  • [ 1581771-50-7 ]
  • [ 939-26-4 ]
  • C70H52N4S4(4+)*4Br(1-) [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% In acetonitrile for 72h; Reflux; Synthesis of TTFB Firstly, tetra(4-pyridyl)-tetrathiafulvalene (0.3 g, 0.59 mmol) was dissolved in acetonitrile (50 mL). Then, 2-(bromomethyl) naphthalene (1.29 g, 5.90 mmol) was added into the above solution. The mixture solution was refluxed for 72 h. When cooling to room temperature, diethyl ether (300 mL) was added dropwise into the solution to produce precipitate. The precipitate was filtered as a brown solid with the yield of 65% (0.54 g, 0.38 mmol).
  • 19
  • [ CAS Unavailable ]
  • [ 2215-89-6 ]
  • [ 1581771-50-7 ]
  • [ 7732-18-5 ]
  • [ 2864346-10-9 ]
YieldReaction ConditionsOperation in experiment
24.3% In methanol; N,N-dimethyl-formamide at 100℃; for 72h; [Zn(TTF(py)4)2(OBA)2]·H2O}n (3): To the solution of TTF(py)4 (0.01mmol, 5.1mg) and OBA (0.01mmol, 2.6mg) in DMF (2mL), a solution of Zn(NO3)2·6H2O (0.01mmol, 3.8mg) in H2O (0.5mL) was added, followed by the addition of methanol (0.5mL). The mixed solution was placed in an oven at 100°C and heated for 3 days at a constant temperature, the power switch of the oven was turned off, and then it was naturally cooled to room temperature. Black bulky crystal of complex 3 was obtained by filtration and washed with DMF and methanol, and then dried in air. The yield is about 24.3% (calculated from Zn). Anal. Calcd (%) for C40H28N4O7S4Zn (MW 870.31): C, 55.20; H, 3.24; N, 6.44. Found (%):C, 55.21; H, 3.25; N, 6.45.
  • 20
  • [ CAS Unavailable ]
  • [ 100-21-0 ]
  • [ 1581771-50-7 ]
  • [ 2864346-07-4 ]
YieldReaction ConditionsOperation in experiment
43% In methanol; lithium hydroxide monohydrate; N,N-dimethyl-formamide at 85℃; for 72h; [Cd(TTF(py)4)2(TPA)2]n (1): To the solution of TTF(py)4 (0.01mmol, 5.1mg) and TPA (0.01mmol, 1.7mg) in DMF (2mL), a solution of Cd(ClO4)2·6H2O (0.1mmol, 3.1mg) in H2O (0.5mL) was added, followed by the addition of methanol (0.5mL). The mixed solution was placed in an oven at 85°C and heated for 3 days at a constant temperature, the power switch of the oven was turned off, and it was naturally cooled to room temperature. Dlack bulky crystal of complex 1 was obtained by filtration and washed with DMF and methanol, and then dried in air. The yield is about 43.0% (calculated from Cd). Anal. Calcd (%) for C34H20N4O4S4Cd (MW: 789.18): C, 51.74; H, 2.55; N, 7.10. Found (%): C, 51.73; H, 2.56; N, 7.11.
  • 21
  • [ CAS Unavailable ]
  • [ 1581771-50-7 ]
  • [ 787-70-2 ]
  • [ 2864346-08-5 ]
YieldReaction ConditionsOperation in experiment
37.1% In methanol; lithium hydroxide monohydrate; N,N-dimethyl-formamide at 100℃; for 72h; [Zn(TTF(py)4)2(BDA)2]n (2): To the solution of TTF(py)4 (0.01mmol, 5.1mg) and BDA (0.01mmol, 2.4mg) in DMF (2mL), a solution of Zn(NO3)2·6H2O (0.01mmol, 3.8mg) in H2O (0.5mL) was added, followed by the addition of methanol (0.5mL). The mixed solution was placed in an oven at 100°C and heated for 3 days at a constant temperature, then the power switch of the oven was turned off, and it was naturally cooled to room temperature. Brown bulky crystal of complex 2 was obtained by filtration and washed with DMF and methanol, and then dried in air. The yield is about 37.1% (calculated from Zn). Anal. Calcd (%) for C20H12N2O2S2Zn (MW 441.81): C, 54.37; H, 2.74; N, 6.34. Found (%): C, 54.38; H, 2.73; N, 6.35.
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