Alternatived Products of [ 1581771-50-7 ]
Product Details of [ 1581771-50-7 ]
CAS No. : | 1581771-50-7 |
MDL No. : | |
Formula : |
C26H16N4S4
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | ABNARIHKWRBIIL-UHFFFAOYSA-N |
M.W : |
512.69
|
Pubchem ID : | 13295747 |
Synonyms : |
|
Safety of [ 1581771-50-7 ]
Application In Synthesis of [ 1581771-50-7 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1581771-50-7 ]
- 1
-
[ 31366-25-3 ]
-
[ 15854-87-2 ]
-
[ 1581771-50-7 ]
Yield | Reaction Conditions | Operation in experiment |
71% |
With palladium diacetate; caesium carbonate; tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane for 24h; Inert atmosphere; Reflux; |
|
Reference:
[1]Vajpayee, Vaishali; Bivaud, Sebastien; Goeb, Sebastien; Croue, Vincent; Allain, Magali; Popp, Brian V.; Garci, Amine; Therrien, Bruno; Salle, Marc
[Organometallics, 2014, vol. 33, # 7, p. 1651 - 1658]
- 2
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[ 1263416-32-5 ]
-
[ 1581771-50-7 ]
-
C140H144N8O16Ru8S8(8+)*8CF3O3S(1-)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
81% |
In methanol at 20℃; for 12h; |
|
Reference:
[1]Vajpayee, Vaishali; Bivaud, Sebastien; Goeb, Sebastien; Croue, Vincent; Allain, Magali; Popp, Brian V.; Garci, Amine; Therrien, Bruno; Salle, Marc
[Organometallics, 2014, vol. 33, # 7, p. 1651 - 1658]
- 3
-
[ 1263416-33-6 ]
-
[ 1581771-50-7 ]
-
C78H76N4O8Ru4S4(4+)*4CF3O3S(1-)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
85% |
In methanol at 20℃; for 12h; |
|
Reference:
[1]Vajpayee, Vaishali; Bivaud, Sebastien; Goeb, Sebastien; Croue, Vincent; Allain, Magali; Popp, Brian V.; Garci, Amine; Therrien, Bruno; Salle, Marc
[Organometallics, 2014, vol. 33, # 7, p. 1651 - 1658]
- 4
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manganese bis(1,1,1,5,5,5-hexafluoroacetylacetonato) dihydrate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 1581771-50-7 ]
-
[Mn(hfac)2][tetra(4-pyridyl)tetrathiafulvalene]0.5
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
62% |
In acetonitrile at 20℃; for 168h; |
|
- 5
-
manganese(II) chloride dihydrate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 1581771-50-7 ]
-
[ 333-20-0 ]
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[Mn(SCN)2][tetra(4-pyridyl)tetrathiafulvalene]*6(CH2Cl2)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
68% |
Stage #1: manganese(II) chloride dihydrate; potassium thioacyanate In methanol for 0.166667h;
Stage #2: dichloromethane; tetra(4-pyridyl)-tetrathiafulvalene In methanol at 20℃; for 120h; |
|
- 6
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tetrakis(acetonitrile)copper(I) perchlorate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 1581771-50-7 ]
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Cu2[tetra(4-pyridyl)tetrathiafulvalene]2*(ClO4)2*2.5(CH2Cl2)*1.5(CH3CN)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
73% |
In acetonitrile at 20℃; for 168h; |
|
- 7
-
copper(II) bis(hexafluoroacetylacetonate) dihydrate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 1581771-50-7 ]
-
[Cu-(hfac)2][tetra(4-pyridyl)tetrathiafulvalene]*2(CH2Cl2)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
73% |
In acetonitrile at 20℃; for 168h; |
|
- 8
-
[ 67-66-3 ]
-
[ 1581771-50-7 ]
-
cobalt(II) aceylacetonate
[ No CAS ]
-
[Co(acac)2][tetra(4-pyridyl)tetrathiafulvalene]0.5*(CHCl3)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
57% |
In acetonitrile at 20℃; for 96h; |
|
- 9
-
[ 1581771-50-7 ]
-
[ 142-71-2 ]
-
[ 75-05-8 ]
-
[Cu2(OAc)4][tetra(4-pyridyl)tetrathiafulvalene]0 .5*1.5(CHCl3)*0.5(H2O)*(CH3CN)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
68% |
at 20℃; for 96h; |
|
- 10
-
manganese(II) chloride dihydrate
[ No CAS ]
-
[ 1581771-50-7 ]
-
[ 3425-46-5 ]
-
[Mn(SeCN)Cl][tetra(4-pyridyl)tetrathiafulvalene]
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
71% |
Stage #1: manganese(II) chloride dihydrate; potassium selenocyanate In methanol for 0.166667h;
Stage #2: tetra(4-pyridyl)-tetrathiafulvalene In methanol; dichloromethane at 20℃; for 120h; |
|
- 11
-
[ 67-56-1 ]
-
ferrous perchlorate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 1581771-50-7 ]
-
[ 1934-75-4 ]
-
[Fe(dicyanamide)][tetra(4-pyridyl)tetrathiafulvalene]*ClO4*CH2Cl2*2CH3OH}n
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
68% |
Stage #1: methanol; ferrous perchlorate; sodium dicyanamide at 20℃; for 1h;
Stage #2: dichloromethane; tetra(4-pyridyl)-tetrathiafulvalene at 20℃; for 168h; |
|
Reference:
[1]Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol; Jiao, Cheng-Qi; Wu, Yue; Leong, Chanel F.; D'Alessandro, Deanna M.; Liu, Tao; Zuo, Jing-Lin
[Angewandte Chemie - International Edition, 2017, vol. 56, # 20, p. 5465 - 5470][Angew. Chem., 2017, vol. 129, # 20, p. 5557 - 5562]
- 12
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ferrous perchlorate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 1581771-50-7 ]
-
[ 1934-75-4 ]
-
[Fe(dicyanamide)2][tetra(4-pyridyl)tetrathiafulvalene]0.5*0.5CH2Cl2}n
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
73% |
Stage #1: ferrous perchlorate; sodium dicyanamide In methanol at 20℃; for 1h;
Stage #2: dichloromethane; tetra(4-pyridyl)-tetrathiafulvalene In methanol at 20℃; for 168h; |
|
Reference:
[1]Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol; Jiao, Cheng-Qi; Wu, Yue; Leong, Chanel F.; D'Alessandro, Deanna M.; Liu, Tao; Zuo, Jing-Lin
[Angewandte Chemie - International Edition, 2017, vol. 56, # 20, p. 5465 - 5470][Angew. Chem., 2017, vol. 129, # 20, p. 5557 - 5562]
- 13
-
[ 1581771-50-7 ]
-
(Re(CO)<SUB>4</SUB>)<SUB>3</SUB>(cyanurate trianion)
[ No CAS ]
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[ 33513-42-7 ]
-
[ 75-05-8 ]
-
[(Re(CO)3)12(TTF(py)4)3(C3N3S3)4]*8CH3CN*12DMF
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
13.4% |
Stage #1: tetra(4-pyridyl)-tetrathiafulvalene; (Re(CO)<SUB>4</SUB>)<SUB>3</SUB>(cyanurate trianion); N,N-dimethyl-formamide; acetonitrile for 0.166667h;
Stage #2: at 100℃; for 48h; Sealed tube; |
|
Reference:
[1]Tzeng, Biing-Chiau; Hsiao, Yu-Jen; Lee, Gene-Hsiang; Wang, Hai-Ying; Leong, Chanel F.; D'Alessandro, Deanna M.; Zuo, Jing-Lin
[Dalton Transactions, 2019, vol. 48, # 22, p. 7946 - 7952]
- 14
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cadmium(II) nitrate tetrhydrate
[ No CAS ]
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[ 75-09-2 ]
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[ 1581771-50-7 ]
-
[ 1283-90-5 ]
-
[Cd(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)•-)1/2]((7,7,8,8-tetracyanoquinodimethane)•-)1/2(NO3)*CH2Cl2
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
40% |
In methanol at 20℃; for 168h; Inert atmosphere; |
|
Reference:
[1]Wang, Hai-Ying; Su, Jian; Ma, Jian-Ping; Yu, Fei; Leong, Chanel F.; D'Alessandro, Deanna M.; Kurmoo, Mohamedally; Zuo, Jing-Lin
[Inorganic Chemistry, 2019, vol. 58, # 13, p. 8657 - 8664]
- 15
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[ 67-56-1 ]
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zinc(II) nitrate hexahydrate
[ No CAS ]
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[ 1581771-50-7 ]
-
[ 1283-90-5 ]
-
[Zn(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)•-)1/2]((7,7,8,8-tetracyanoquinodimethane)•-)1/2(NO3)*2CH3OH
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
42% |
In dichloromethane at 20℃; for 168h; Inert atmosphere; |
|
Reference:
[1]Wang, Hai-Ying; Su, Jian; Ma, Jian-Ping; Yu, Fei; Leong, Chanel F.; D'Alessandro, Deanna M.; Kurmoo, Mohamedally; Zuo, Jing-Lin
[Inorganic Chemistry, 2019, vol. 58, # 13, p. 8657 - 8664]
- 16
-
[ 67-56-1 ]
-
cadmium(II) nitrate tetrhydrate
[ No CAS ]
-
[ 75-09-2 ]
-
[ 18643-56-6 ]
-
[ 1581771-50-7 ]
-
[Cd(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)2-)1/2]((7,7,8,8-tetracyanoquinodimethane)•-)1/2(NO3)1/2*CH2Cl2*1/2CH3OH
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
31% |
With lithium acetate In N,N-dimethyl-formamide at 20℃; for 168h; Inert atmosphere; |
|
Reference:
[1]Wang, Hai-Ying; Su, Jian; Ma, Jian-Ping; Yu, Fei; Leong, Chanel F.; D'Alessandro, Deanna M.; Kurmoo, Mohamedally; Zuo, Jing-Lin
[Inorganic Chemistry, 2019, vol. 58, # 13, p. 8657 - 8664]
- 17
-
[ 67-56-1 ]
-
cadmium(II) nitrate tetrhydrate
[ No CAS ]
-
[ 18643-56-6 ]
-
[ 1581771-50-7 ]
-
[Cd(tetra(4-pyridyl)tetrathiafulvalene)((7,7,8,8-tetracyanoquinodimethane)2-)1/2](NO3)*CH3OH
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
31% |
With lithium acetate In dichloromethane; N,N-dimethyl-formamide at 20℃; for 168h; Inert atmosphere; |
|
Reference:
[1]Wang, Hai-Ying; Su, Jian; Ma, Jian-Ping; Yu, Fei; Leong, Chanel F.; D'Alessandro, Deanna M.; Kurmoo, Mohamedally; Zuo, Jing-Lin
[Inorganic Chemistry, 2019, vol. 58, # 13, p. 8657 - 8664]
- 18
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[ 1581771-50-7 ]
-
[ 939-26-4 ]
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C70H52N4S4(4+)*4Br(1-)
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
65% |
In acetonitrile for 72h; Reflux; |
Synthesis of TTFB
Firstly, tetra(4-pyridyl)-tetrathiafulvalene (0.3 g, 0.59 mmol) was dissolved in acetonitrile (50 mL). Then, 2-(bromomethyl) naphthalene (1.29 g, 5.90 mmol) was added into the above solution. The mixture solution was refluxed for 72 h. When cooling to room temperature, diethyl ether (300 mL) was added dropwise into the solution to produce precipitate. The precipitate was filtered as a brown solid with the yield of 65% (0.54 g, 0.38 mmol). |
Reference:
[1]Li, Xing-Long; Qin, Jie; Jiang, Man; Chen, Meng-Ning; Wang, Rong-Zhou; Yu, Shengsheng; Wang, Hai-Ying; Xing, Ling-Bao
[Tetrahedron Letters, 2021, vol. 66]
- 19
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[ CAS Unavailable ]
-
[ 2215-89-6 ]
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[ 1581771-50-7 ]
-
[ 7732-18-5 ]
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[ 2864346-10-9 ]
Yield | Reaction Conditions | Operation in experiment |
24.3% |
In methanol; N,N-dimethyl-formamide at 100℃; for 72h; |
[Zn(TTF(py)4)2(OBA)2]·H2O}n (3):
To the solution of TTF(py)4 (0.01mmol, 5.1mg) and OBA (0.01mmol, 2.6mg) in DMF (2mL), a solution of Zn(NO3)2·6H2O (0.01mmol, 3.8mg) in H2O (0.5mL) was added, followed by the addition of methanol (0.5mL). The mixed solution was placed in an oven at 100°C and heated for 3 days at a constant temperature, the power switch of the oven was turned off, and then it was naturally cooled to room temperature. Black bulky crystal of complex 3 was obtained by filtration and washed with DMF and methanol, and then dried in air. The yield is about 24.3% (calculated from Zn). Anal. Calcd (%) for C40H28N4O7S4Zn (MW 870.31): C, 55.20; H, 3.24; N, 6.44. Found (%):C, 55.21; H, 3.25; N, 6.45. |
- 20
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[ CAS Unavailable ]
-
[ 100-21-0 ]
-
[ 1581771-50-7 ]
-
[ 2864346-07-4 ]
Yield | Reaction Conditions | Operation in experiment |
43% |
In methanol; lithium hydroxide monohydrate; N,N-dimethyl-formamide at 85℃; for 72h; |
[Cd(TTF(py)4)2(TPA)2]n (1):
To the solution of TTF(py)4 (0.01mmol, 5.1mg) and TPA (0.01mmol, 1.7mg) in DMF (2mL), a solution of Cd(ClO4)2·6H2O (0.1mmol, 3.1mg) in H2O (0.5mL) was added, followed by the addition of methanol (0.5mL). The mixed solution was placed in an oven at 85°C and heated for 3 days at a constant temperature, the power switch of the oven was turned off, and it was naturally cooled to room temperature. Dlack bulky crystal of complex 1 was obtained by filtration and washed with DMF and methanol, and then dried in air. The yield is about 43.0% (calculated from Cd). Anal. Calcd (%) for C34H20N4O4S4Cd (MW: 789.18): C, 51.74; H, 2.55; N, 7.10. Found (%): C, 51.73; H, 2.56; N, 7.11. |
- 21
-
[ CAS Unavailable ]
-
[ 1581771-50-7 ]
-
[ 787-70-2 ]
-
[ 2864346-08-5 ]
Yield | Reaction Conditions | Operation in experiment |
37.1% |
In methanol; lithium hydroxide monohydrate; N,N-dimethyl-formamide at 100℃; for 72h; |
[Zn(TTF(py)4)2(BDA)2]n (2):
To the solution of TTF(py)4 (0.01mmol, 5.1mg) and BDA (0.01mmol, 2.4mg) in DMF (2mL), a solution of Zn(NO3)2·6H2O (0.01mmol, 3.8mg) in H2O (0.5mL) was added, followed by the addition of methanol (0.5mL). The mixed solution was placed in an oven at 100°C and heated for 3 days at a constant temperature, then the power switch of the oven was turned off, and it was naturally cooled to room temperature. Brown bulky crystal of complex 2 was obtained by filtration and washed with DMF and methanol, and then dried in air. The yield is about 37.1% (calculated from Zn). Anal. Calcd (%) for C20H12N2O2S2Zn (MW 441.81): C, 54.37; H, 2.74; N, 6.34. Found (%): C, 54.38; H, 2.73; N, 6.35. |