Alternatived Products of [ 150405-69-9 ]
Product Details of [ 150405-69-9 ]
CAS No. : | 150405-69-9 |
MDL No. : | MFCD00799419 |
Formula : |
C30H27N3
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | ZVFQEOPUXVPSLB-UHFFFAOYSA-N |
M.W : |
429.56
|
Pubchem ID : | 11441792 |
Synonyms : |
|
UV : | 290 nm (in THF) |
FL : | 370 nm (in THF) |
Materials Type : | Other OLED Materials |
Safety of [ 150405-69-9 ]
Signal Word: | Warning |
Class: | N/A |
Precautionary Statements: | P280-P305+P351+P338 |
UN#: | N/A |
Hazard Statements: | H302 |
Packing Group: | N/A |
GHS Pictogram: |
|
Application In Synthesis of [ 150405-69-9 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 150405-69-9 ]
- 1
-
[ 150405-69-9 ]
-
[ 22445-41-6 ]
-
C46H43N3
[ No CAS ]
-
C38H35N3
[ No CAS ]
-
C38H35N3
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
42% |
With C17H24N5Ru(1+)*F6P(1-); potassium acetate; potassium carbonate In 1-methyl-pyrrolidin-2-one at 50℃; for 72h; Inert atmosphere; |
|
42% |
With C17H24N5Ru(1+)*F6P(1-); potassium acetate; potassium carbonate In 1-methyl-pyrrolidin-2-one at 50℃; for 72h; Inert atmosphere; Glovebox; |
General Procedure C: arylation of DG-containing (hetero)arenes with (hetero)aryl (pseudo)halides using cyclometalated ruthenium(ll) catalysts
General procedure: Unless otherwise stated, in an Argon filled glove-box a crimp-cap microwave vial equipped with a magnetic stirring bar was charged with the appropriate cyclometalated Ru(ll)-catalyst (like Ru1-Ru46, from 3 mol % to 10 mol %), KOAc (5.9 mg, 0.06 mmol, 30 mol %), K2CO3 (2.0 - 4.0 equiv.), the appropriate DG-containing arene (like N1-N12, 0.20 mmol, 1.0 equiv.), the appropriate (hetero)aryl (pseudo)halide (like X1-X42, 0.2 mmol, 1.0 equiv) and /V-methyl-2- pyrrolidone (NMP) (200 pL, 1 M). The vial was capped and stirred at 35 °C for 24 hours. Upon completion, the crude mixture was loaded on a silica gel column and purified by flash chromatography |
Reference:
[1]Simonetti, Marco; Cannas, Diego M.; Just-Baringo, Xavier; Vitorica-Yrezabal, Iñigo J.; Larrosa, Igor
[Nature Chemistry, 2018, vol. 10, # 7, p. 724 - 731]
[2]Current Patent Assignee: UNIVERSITY OF MANCHESTER - WO2019/215426, 2019, A1
Location in patent: Page/Page column 38; 58-59