Alternatived Products of [ 14852-31-4 ]
Product Details of [ 14852-31-4 ]
CAS No. : | 14852-31-4 |
MDL No. : | MFCD00004553 |
Formula : |
C16H34O
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
242.44
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 14852-31-4 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 14852-31-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 14852-31-4 ]
- Downstream synthetic route of [ 14852-31-4 ]
- 1
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[ 18787-63-8 ]
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[ 14852-31-4 ]
Yield | Reaction Conditions | Operation in experiment |
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With cyclohexane; cobalt catalyst at 200℃; Hydrogenation; |
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With sodium tetrahydroborate |
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With lithium tri-t-butoxyaluminum hydride In tetrahydrofuran no long-chain inhibition compared with 2-hexanone; |
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Reference:
[1]Asinger; Eckoldt
[Chemische Berichte, 1943, vol. 76, p. 591]
[2]Jones,D.F.; Howe,R.
[Journal of the Chemical Society C: Organic, 1968, p. 2801 - 2808]
[3]Menger; Nelson Jr., Kingsley H.
[Tetrahedron Letters, 1994, vol. 35, # 9, p. 1347 - 1348]
- 2
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[ 307-30-2 ]
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[ 14852-31-4 ]
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2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-octyloxy)-hexadecane
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
93% |
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 65℃; for 6h; |
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- 3
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[ 18787-63-8 ]
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[ 14852-31-4 ]
Yield | Reaction Conditions | Operation in experiment |
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at 200℃; Hydrogenation; |
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- 4
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[ 544-76-3 ]
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[ 593-03-3 ]
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[ 591-72-0 ]
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[ 21078-87-5 ]
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[ 19781-43-2 ]
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[ 14852-31-4 ]
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[ 45206-91-5 ]
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[ 57661-23-1 ]
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[ 18787-64-9 ]
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[ 18787-63-8 ]
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[ 18787-65-0 ]
Yield | Reaction Conditions | Operation in experiment |
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With 2percent Au/2percent TESPTS in mesoporous silica at 150℃; for 6h; Air; |
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- 5
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[ 14852-31-4 ]
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[ 18787-63-8 ]
Yield | Reaction Conditions | Operation in experiment |
70% |
With pyridine; tert.-butylhydroperoxide; [Fe[(S)-N-benzyl-2-phenyl-2-(pyridin-2-ylmethoxy)-N-(pyridin-2-ylmethyl)ethanamine](OTf)2] In acetone at 20℃; for 8h; Inert atmosphere; Green chemistry; |
7.4.2. Determination of isolated yields in acetone, typical procedure for 9H-fluoren-9-one
General procedure: The substrate 9H-fluorene (0.100 g, 0.601 mmol) and the catalyst [Fe(12)(OTf)2] (0.013 g, 0.018 mmol) were dissolved in acetone (2.0 mL). The oxidant tBuOOH (0.344 mL, 70 wt.% in H2O, 2.4 mmol) was added dropwise and the dark solution was shaken for 8 h at room temperature. The solvent was removed under vacuum. The product 9H-fluoren-9-one was isolated by column chromatography as an colorless oil (0.071 g, 0.394 mmol, 65%) using silica gel and CHCl3 as eluent. Analytical data for all oxidation products in Table 1 are given in the Supporting information |
98 %Chromat. |
With 5H3N*5H(1+)*IMo6O24(5-); oxygen; sodium acetate In water; acetonitrile at 70℃; for 20h; Green chemistry; |
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Reference:
[1]Lenze, Matthew; Sedinkin, Sergey L.; Bauer, Eike B.
[Journal of Molecular Catalysis A: Chemical, 2013, vol. 373, p. 161 - 171]
[2]Zhang, Mengqi; Zhai, Yongyan; Ru, Shi; Zang, Dejin; Han, Sheng; Yu, Han; Wei, Yongge
[Chemical Communications, 2018, vol. 54, # 72, p. 10164 - 10167]
- 6
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[ 112-39-0 ]
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[ 629-62-9 ]
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[ 34557-54-5 ]
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[ 544-76-3 ]
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[ 14852-31-4 ]
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[ 36653-82-4 ]
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[ 629-80-1 ]
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[ 540-10-3 ]
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[ 124-38-9 ]
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[ 201230-82-2 ]
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[ 57-10-3 ]
- 7
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[ 112-39-0 ]
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[ 629-62-9 ]
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[ 34557-54-5 ]
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[ 544-76-3 ]
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[ 14852-31-4 ]
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[ 36653-82-4 ]
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[ 629-80-1 ]
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[ 540-10-3 ]
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[ 201230-82-2 ]
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[ 57-10-3 ]
- 8
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[ 14852-31-4 ]
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[ 629-62-9 ]
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[ 629-59-4 ]
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[ 544-76-3 ]
Yield | Reaction Conditions | Operation in experiment |
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With hydrogen In n-heptane at 199.84℃; Autoclave; |
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Reference:
[1]Di, Lu; Yao, Sikai; Li, Mengru; Wu, Guangjun; Dai, Weili; Wang, Guichang; Li, Landong; Guan, Naijia
[ACS Catalysis, 2015, vol. 5, # 12, p. 7199 - 7207]
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