[ CAS No. 1477527-27-7 ] {[proInfo.proName]}

Name: 1477527-27-7|1,1,2,2-Tetrakis(4-(1H-imidazol-1-yl)phenyl)ethene|97%
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Quality Control of [ 1477527-27-7 ]

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Product Details of [ 1477527-27-7 ]

CAS No. :	1477527-27-7	MDL No. :	N/A
Formula :	C₃₈H₂₈N₈	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	NAWGRFXRBZACML-UHFFFAOYSA-N
M.W :	596.68	Pubchem ID :	102109009
Synonyms :

Safety of [ 1477527-27-7 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1477527-27-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1477527-27-7 ]

[ 1477527-27-7 ] Synthesis Path-Downstream 1~30

1
[ 288-32-4 ]
[ 299914-63-9 ]
1,1,2,2-tetrakis(4-(1H-imidazol-1-yl)phenyl)ethene [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydride In tetrahydrofuran-d8

Reference： [1]Zhang, Hong-Ling; Zhao, Bo; Yuan, Wei-Guan; Tang, Wei; Xiong, Fang; Jing, Lin-Hai; Qin, Da-Bin [Inorganic Chemistry Communications, 2013, vol. 35, p. 208 - 212]

2
[ CAS Unavailable ]
[ 554-95-0 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 75-05-8 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
51%	at 170℃; for 96h; High pressure;	A mixture of TIPE (0.0595 g, 0.1 mmol), CoCl2·6H2O (0.0237 g, 0.2 mmol), H3btc (0.0420 g, 0.2 mmol), CH3CN (5 mL) and H2O (4 mL) was placed in a Teflon reactor (25 mL) and heated at 170 °C for 4 days. Then the mixture had been cooled to room temperature for 3 days. Large quantities of red block crystals of 1 were obtained in a 51% yield based on TIPE. Anal. Calcd. for C49H45CoN9O11 (Mr = 994.85): C, 59.16; H, 4.56; N, 12.67. Found: C, 59.36; H, 4.35; N, 12.61. IR (KBr, cm-1): 3350(s), 3130(m), 1610(s), 1570(m), 1520(m), 1430(m),1380(m), 1310(s), 1070(m), 964(w), 835(w), 748(s), 652(w).

Reference： [1]Zhang, Hong-Ling; Zhao, Bo; Yuan, Wei-Guan; Tang, Wei; Xiong, Fang; Jing, Lin-Hai; Qin, Da-Bin [Inorganic Chemistry Communications, 2013, vol. 35, p. 208 - 212]

3
[ 288-32-4 ]
[ 61326-44-1 ]
1,1,2,2-tetrakis(4-(1H-imidazol-1-yl)phenyl)ethene [ No CAS ]

Reference： [1]Chemistry - A European Journal,2017,vol. 23,p. 12565 - 12574
[2]Angewandte Chemie - International Edition,2017,vol. 56,p. 2785 - 2789
Angew. Chem.,2017,vol. 129,p. 2829 - 2833,5
[3]Chemical Communications,2014,vol. 50,p. 15243 - 15246
[4]Journal of Materials Chemistry B,2015,vol. 3,p. 7222 - 7226

4
[ CAS Unavailable ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
70%	With <i>L</i>-proline at 160℃; for 96h;	4 Example 4 (Synthesis of catalyst Cd-TIPE) Weigh TIPE (1.7mg, 0.028mmol), Cd(NO3)2•4H2O (30.8mg, 0.1mmol) and L-Pro (16.6mg, 0.138mmol) dissolved in 1mL water and 4mL N,N- dimethylformamide mixed solution, stirred for 3h until homogeneity, placed in an oven, heated at 160 deg. C for 96 hours, the oven was turned off, cooled to room temperature, colorless bulk crystal was produced, filtered and dried, yield 70%.

Reference： [1]Current Patent Assignee: DALIAN UNIVERSITY OF TECHNOLOGY - CN105348071, 2016, A Location in patent: Paragraph 0038; 0039

5
[ CAS Unavailable ]
[ 1477527-27-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
55.8%	With ammonium hydroxide In ethanol; lithium hydroxide monohydrate at 155℃; for 90h; Sealed tube;
	With ammonium hydroxide In lithium hydroxide monohydrate at 155℃; for 72h; Autoclave;

Reference： [1]Chen, He; Liu, Ping-Xiao; Xu, Ning; Meng, Xing; Wang, Hai-Ning; Zhou, Zi-Yan [Dalton Transactions, 2016, vol. 45, # 34, p. 13477 - 13482]
[2]Zhang, Ya; Zhou, Qiang; Qiu, Zhao-Feng; Zhang, Xiao-Yu; Chen, Jia-Qi; Zhao, Yue; Gong, Feng; Sun, Wei-Yin [Advanced Functional Materials, 2022, vol. 32, # 36]

6
[ 109-65-9 ]
[ 1477527-27-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
51%	Stage #1: 1-bromo-butane; 1,1,2,2-tetrakis(4-(1H-imidazol-1-yl)phenyl)ethene In N,N-dimethyl-formamide at 100℃; for 48h; Inert atmosphere; Schlenk technique; Stage #2: With ammonium hexafluorophosphate In methanol at 25℃; for 16h; Inert atmosphere; Schlenk technique;

Reference： [1]Sinha, Narayan; Stegemann, Linda; Tan, Tristan T. Y.; Doltsinis, Nikos L.; Strassert, Cristian A.; Hahn, F. Ekkehardt [Angewandte Chemie - International Edition, 2017, vol. 56, # 10, p. 2785 - 2789][Angew. Chem., 2017, vol. 129, # 10, p. 2829 - 2833,5]

7
[ 74-96-4 ]
[ 1477527-27-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
44%	Stage #1: ethyl bromide; 1,1,2,2-tetrakis(4-(1H-imidazol-1-yl)phenyl)ethene In N,N-dimethyl-formamide at 100℃; for 48h; Inert atmosphere; Schlenk technique; Stage #2: With ammonium hexafluorophosphate In methanol at 25℃; for 16h; Inert atmosphere; Schlenk technique;

8
[ 761442-02-8 ]
[ 1477527-27-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
85%	In water at 50℃; for 6h;

Reference： [1]Das, Paramita; Kumar, Atul; Howlader, Prodip; Mukherjee, Partha Sarathi [Chemistry - A European Journal, 2017, vol. 23, # 51, p. 12565 - 12574]

9
[ CAS Unavailable ]
[ 964-68-1 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 75-05-8 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
55%	at 160℃; for 96h; Autoclave;	2.4. Synthesis of [Co₄(L)₂(BPDC)₄4H₂O]5MeCN5H₂O}_n (2) Co(NO3)26H2O (29.1 mg, 0.01 mmol), 4,4'-benzophenonedicarboxylic acid (H2BPDC, 27.0 mg, 0.10 mmol), and L (15.2 mg, 0.026 mmol) were dissolved in CH3CN-H2O (v/v 6 mL/6 mL) and placed in a Telfon-lined stainless autoclave, which were heated to 160 °C for 96 h. After cooling to ambient temperature, a large number of violet crystals was observed and collected by filtration, washed with CH2Cl2 and dried in air. Yield: 55%. Anal. Calcd. for C146H121Co4N21O29, C, 61.09; H, 4.25; N,10.25. Found: C, 60.05; H, 4.31; N, 10.28. IR (KBr pellets, cm-1): 3409 (w), 3130 (w), 2924 (w), 1656 (w), 1594 (s), 1522 (vs), 1386 (s), 1304(m), 1270 (m), 1122 (w), 1061 (m), 963 (w), 932 (w), 837 (m), 810 (m),733 (s), 657 (w), 540 (w).

Reference： [1]Peng, Mengni; Huang, Kun; Li, Xianglin; Han, Defang; Qiu, Qi; Jing, Linhai; Qin, Dabin [Journal of Solid State Chemistry, 2019, vol. 280]

10
[ CAS Unavailable ]
[ 2215-89-6 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
50%	In acetonitrile at 160℃; for 96h; Autoclave;	2.3. Synthesis of [Cd₄(L)₂(obba)₄]4H₂O}_n (1) To a Telfon-lined stainless autoclave was added Cd(NO3)24H2O (35.9 mg, 0.12 mmol), 4,40-oxybis(benzoic acid) (H2oba, 25.8 mg,0.10 mmol) and L (30 mg, 0.05 mmol) in mixture of MeCN (6 mL) and H2O (6 mL), which were heated to 160 °C for 96 h. The resulting mixturewas cooled to room temperature with the appearance of large amount of yellow crystals. The crystals were collected by filtration, washed with CH2Cl2 and dried in air. Yield: 50%. Anal. Calcd. for C132H88Cd4N16O28,C, 56.66; H, 3.17; N, 8.01. Found: C, 56.73; H, 3.25; N, 7.99. IR (KBr pellets, cm-1): 3428 (w), 3134 (w), 1597 (s), 1519 (vs), 1396 (vs), 1306(m), 1238 (s), 1160 (m), 1118 (w), 1059 (m), 1014 (w), 963 (m), 931(w), 876 (w), 842 (w), 807 (w), 779 (m), 659 (m), 537 (w).

Reference： [1]Peng, Mengni; Huang, Kun; Li, Xianglin; Han, Defang; Qiu, Qi; Jing, Linhai; Qin, Dabin [Journal of Solid State Chemistry, 2019, vol. 280]

11
[ 623-24-5 ]
[ 1477527-27-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile at 85℃; for 72h;

Reference： [1]Nian, Hao; Li, Aisen; Li, Yawen; Cheng, Lin; Wang, Ling; Xu, Weiqing; Cao, Liping [Chemical Communications, 2020, vol. 56, # 21, p. 3195 - 3198]

12
[ 34373-96-1 ]
[ 1477527-27-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	In acetonitrile at 85℃; for 72h;

Reference： [1]Nian, Hao; Li, Aisen; Li, Yawen; Cheng, Lin; Wang, Ling; Xu, Weiqing; Cao, Liping [Chemical Communications, 2020, vol. 56, # 21, p. 3195 - 3198]

13
[ 288-32-4 ]
[ 1089898-31-6 ]
[ 1477527-27-7 ]

Yield	Reaction Conditions	Operation in experiment
66%	With potassium carbonate In N,N-dimethyl-formamide at 30℃; for 10h; Inert atmosphere; Irradiation;

Reference： [1]Mondal, Bijnaneswar; Bhandari, Pallab; Mukherjee, Partha Sarathi [Chemistry - A European Journal, 2020, vol. 26, # 65, p. 15007 - 15015]

14
[ CAS Unavailable ]
[ 127-19-5 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 2601419-98-9 ]

Yield	Reaction Conditions	Operation in experiment
47%	With 1,5-pentanedioic acid at 100℃; for 72h; Autoclave;	2.2. Preparation of [Cd(L)Cl2].3DMF (1) and [Cd(L)(DMA)(H2O](ClO4)2.5DMA (2) For 2, Cd(ClO4)2.6H2O (33.0 mg, 0.08 mmol), L (12.0 mg, 0.02 mmol), glutaric acid(5.3 mg, 0.04 mmol) and DMA (5.0 mL) were sealed in a Teflon-lined stainless steel containerand heated at 100 °C for 72 h. After cooling to room temperature colorless crystalsof 2 were obtained in 47% yield. IR (KBr pellet, cm-1, Figure S1): 3644 (w), 3119(w), 1604 (w), 1520 (s), 1416 (w), 1305 (s), 1258 (m), 1127 (m), 1061 (s), 958 (m), 931(m), 837(m), 809 (s), 733(m), 659 (s), 621(m), 575 (w), 537 (m).

Reference： [1]Xu, Zou-Hong; Zhao, Shu-Man; Zhao, Yue; Sun, Wei-Yin [Journal of Coordination Chemistry, 2021, vol. 74, # 1-3, p. 294 - 305]

15
[ CAS Unavailable ]
[ 1477527-27-7 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
65%	With nitric acid at 100℃; for 72h; Autoclave;	2.2. Preparation of [Cd(L)Cl2].3DMF (1) and [Cd(L)(DMA)(H2O](ClO4)2.5DMA (2) For 1, CdCl22.5H2O (9.2 mg, 0.4 mmol), L (24.0 mg, 0.04 mmol), DMF (5.0 mL) and nitric acid (10 mL) were sealed in a Teflon-lined stainless steel container and heated at 100 °C for 72 h. Colorless crystals of 1 were obtained in 65% yield after cooling toroom temperature. IR (KBr pellet, cm-1, Figure S1): 3503 (w), 3119 (w), 2923 (w), 1669(s), 1604 (w), 1520 (s), 1380 (m), 1305 (m), 1258 (m), 1127 (w), 1061 (s), 958 (m), 931(m), 837(m), 809 (m), 733(w), 659 (s), 575 (w), 537 (m).

Reference： [1]Xu, Zou-Hong; Zhao, Shu-Man; Zhao, Yue; Sun, Wei-Yin [Journal of Coordination Chemistry, 2021, vol. 74, # 1-3, p. 294 - 305]

16
[ CAS Unavailable ]
[ 482-05-3 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	With N,N-dimethyl-formamide; sodium hydroxide at 122℃; for 84h; Autoclave;	2.3. Synthesis of [Zn(tipe)1/2(bpdc)]H2O}n (MOF 2 or 2H2O) A mixture of tipe (0.010 mmol), H2bpdc (0.020 mmol), ZnSO4-H2O (0.030 mmol), NaOH (0.032 mmol), H2O (7.2 mL) and DMF(2.8 mL) were added to a Teflon-lined stainless autoclave(25 mL), and heated to 122 °C for 3.5 days, and then cooled to roomtemperature. The colourless crystals of MOF 2 were synthesized.Anal. Calc. for C33H24N4O5Zn (MOF 2): C, 63.73%; H, 3.89%; N,9.01%. Found: C, 63.86%; H, 3.78%; N, 8.84%. IR data (cm-1):3114w, 1667m, 1580m, 1517s, 1486s, 1373m, 1304m, 1242m,1107m, 1058s, 962s, 833s, 803s, 746s, 656s, 618m.

Reference： [1]Tian, Hai-Xin; Zha, Miao; Ma, Li-Xiao; Zhou, Wen-Jing; Li, Bao-Long; Wu, Bing [Polyhedron, 2021, vol. 197]

17
[ CAS Unavailable ]
[ 554-95-0 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	at 122℃; for 84h; Autoclave;	2.2. Synthesis of [Zn4(OH)(tipe)2(btc)2](OH)9H2ODMF}n (MOF 1 or1(OH)9H2ODMF) A mixture of tipe (0.020 mmol), H3btc (0.030 mmol), ZnSO4-7H2O (0.080 mmol), NaOH (0.075 mmol), H2O (7.2 mL) and DMF(2.8 mL) was added to a Teflon-lined stainless autoclave (25 mL).The reaction mixture was heated to 122 °C for 3.5 days, and cooledto room temperature. The colourless crystals of MOF 1 were synthesized.Anal. Calc. for C97H89N17O24Zn4 (MOF 1): C, 54.48%; H,4.20%; N, 11.14%. Found: C, 54.22%; H, 4.23%; N, 11.17%. IR data(cm-1): 3449w, 3107w, 1613s, 1585m, 1525s, 1431m, 1408m,1338s, 1311s, 1266m, 1125m, 1096m, 1068s, 966m, 834m,806m, 767s, 748s, 726s, 655s

Reference： [1]Tian, Hai-Xin; Zha, Miao; Ma, Li-Xiao; Zhou, Wen-Jing; Li, Bao-Long; Wu, Bing [Polyhedron, 2021, vol. 197]

18
[ 67-56-1 ]
[ CAS Unavailable ]
[ 677010-20-7 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
41%	at 100℃; for 72h; Autoclave;

Reference： [1]Qiu, Zhao-Feng; Zhao, Shu-Man; Xu, Zou-Hong; Zhao, Yue; Wang, Zheng-Liang; Sun, Wei-Yin [Crystal Growth and Design, 2021, vol. 21, # 9, p. 5306 - 5316]

19
[ 67-56-1 ]
[ CAS Unavailable ]
[ 1351279-73-6 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
35%	at 100℃; for 72h; Autoclave;

Reference： [1]Qiu, Zhao-Feng; Zhao, Shu-Man; Xu, Zou-Hong; Zhao, Yue; Wang, Zheng-Liang; Sun, Wei-Yin [Crystal Growth and Design, 2021, vol. 21, # 9, p. 5306 - 5316]

20
[ CAS Unavailable ]
[ 127-19-5 ]
[ 1477527-27-7 ]
[ 99-31-0 ]
[ 7732-18-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
27%	at 100℃; for 72h; Autoclave;

Reference： [1]Qiu, Zhao-Feng; Zhao, Shu-Man; Xu, Zou-Hong; Zhao, Yue; Wang, Zheng-Liang; Sun, Wei-Yin [Crystal Growth and Design, 2021, vol. 21, # 9, p. 5306 - 5316]

21
[ CAS Unavailable ]
[ 482-05-3 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide for 1h; Sonication;	2.3. Preparation nano-sized [Cu(tipe)(H2O)](2,20-bpdc)11H2ODMF}n(111H2ODMF or Cu-tipe) Tipe (0.100 mmol), 2,20-H2bpdc (0.100 mmol), CuSO4 H2O(0.100 mmol) and NaOH (0.080 mmol) in H2O (35.0 mL) and 15.0 mLDMF was stirred. This solution was sonicated for 60 min at 100 W and100KHZ. The blue nano particles 111H2ODMF or Cu-tipe were driedin air after filtering and washing with H2O. Anal. Calc. forC55H67CuN9O17: C, 55.53%; H,5.68%; N, 10.60%. Found: C, 55.75%; H,5.70%; N, 10.69%

Reference： [1]Tian, Hai-Xin; Zha, Miao; Ding, Jian-Gang; Zhu, Li-Ming; Li, Bao-Long; Wu, Bing [Journal of Solid State Chemistry, 2021, vol. 304]

22
[ CAS Unavailable ]
[ 482-05-3 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ 68-12-2 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide at 100℃; for 96h;	2.2. Preparation [Cu(tipe)(H2O)](2,20-bpdc)11H2ODMF}n(111H2ODMF or Cu-tipe) as single crystal Tipe (0.040 mmol), 2,20-H2bpdc (0.040 mmol), CuSO4 H2O(0.040 mmol) and NaOH (0.060 mmol) were dissolved in a 20 mLstainless autoclave containing H2O (7.0 mL) and 3.0 mL DMF (3.0 mL).This mixture was heated to 100 C for 4 days. The blue crystals111H2ODMF or Cu-tipe were obtained when this solution was graduallycooled to room temperature. Anal. Calc. for C55H67CuN9O17(111H2ODMF or Cu-tipe): C, 55.53%; H,5.68%; N, 10.60%. Found: C,55.68%; H, 5.63%; N, 10.68%. IR data (cm1): 3139 m, 1660s, 1600 m,1582 m, 1561 m, 1522 m, 1431w, 1377 m, 1309 m, 1252 m, 1128 m, 1095w, 1062 m, 964 m, 832 m, 806 m, 747s, 655 m

Reference： [1]Tian, Hai-Xin; Zha, Miao; Ding, Jian-Gang; Zhu, Li-Ming; Li, Bao-Long; Wu, Bing [Journal of Solid State Chemistry, 2021, vol. 304]

23
[ 67-56-1 ]
[ CAS Unavailable ]
[ 1351279-73-6 ]
[ 1477527-27-7 ]
[ 7732-18-5 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
57%	at 120℃; for 48h;	2.2. Preparation of MOFs [Cd2(tib)(tpe)]5DMAH2O (1) and[Cd4(tipe)2(tpe)2]15CH3OH11H2O (2) For preparation of 2, Cd(NO3)24H2O (24.7 mg, 0.08 mmol), tipe(12.0 mg, 0.02 mmol), H4tpe (20.0 mg, 0.04 mmol) and 5 mL of mixedCH3OH and H2O (2 : 1) solvent were put into in a 10 mL glass vial. Then,the vial was heated in a programmable oven at 120 C for 2 days andcooled naturally. Light-yellow crystalline solid was obtained with 57%yield (based on tipe). Anal. Calcd for C151H170Cd4N16O42: C 54.45%, H5.14%, N 6.73%. Found: C 54.20%, H 4.96%, N 6.65%. IR (Fig. S1, ATR,cm1): 3337(s), 2942(w), 2828(w), 1520(s), 1386(m), 1115(w),1019(s), 835(w).

Reference： [1]Huang, Zi-Qing; Qiu, Zhao-Feng; Sun, Wei-Yin; Sun, Xiang-Yu; Wang, Zheng-Liang; Zhang, Xiao-Yu; Zhao, Shu-Man; Zhao, Yue [Journal of Solid State Chemistry, 2022, vol. 312]

24
[ CAS Unavailable ]
[ 1477527-27-7 ]
[ CAS Unavailable ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	With ammonium hydroxide In lithium hydroxide monohydrate at 155℃; for 72h; Autoclave;

Reference： [1]Zhang, Ya; Zhou, Qiang; Qiu, Zhao-Feng; Zhang, Xiao-Yu; Chen, Jia-Qi; Zhao, Yue; Gong, Feng; Sun, Wei-Yin [Advanced Functional Materials, 2022, vol. 32, # 36]

25
[ 1477527-27-7 ]
[ CAS Unavailable ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	With ammonium hydroxide In ethanol; lithium hydroxide monohydrate at 155℃; for 72h; Autoclave;

Reference： [1]Zhang, Ya; Zhou, Qiang; Qiu, Zhao-Feng; Zhang, Xiao-Yu; Chen, Jia-Qi; Zhao, Yue; Gong, Feng; Sun, Wei-Yin [Advanced Functional Materials, 2022, vol. 32, # 36]

26
[ 1477527-27-7 ]
[ 1765-40-8 ]
[ 2925423-80-7 ]

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide at 100℃;	1 The prepared TPE-im (1 g, 3 mmol) and pentafluorobenzyl bromide (0.78 g, 3 mmol) were dissolved in DMF (20 mL), heated in a round-bottomed flask with a magnetic stir bar, and heated at 100 °C. The reaction is stirred for another 12 h. After cooling, DMF is removed with rotary steaming, then water is added and filtered. The filtrate is evaporated to obtain the target product in the form of a yellowish solid.

Reference： [1]Current Patent Assignee: ZHEJIANG UNIV HANGZHOU INTERNATIONAL KOCH CENTER - CN116041262, 2023, A Location in patent: Paragraph 0068; 0071-0076

27
[ 1477527-27-7 ]
[ 100-39-0 ]
[ 2925423-82-9 ]

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide at 100℃;	2 The TPE-im (1g, 3mmol) and benzyl bromide (0.78g, 3mmol) prepared in Example 1 were dissolved in DMF (20mL), and the solution was heated at 100 °C. The reaction is stirred for another 12 h. After cooling, DMF is removed by rotary steaming, then EA is added to filter the precipitate to obtain a white solid.

Reference： [1]Current Patent Assignee: ZHEJIANG UNIV HANGZHOU INTERNATIONAL KOCH CENTER - CN116041262, 2023, A Location in patent: Paragraph 0077-0083

28
[ 74-96-4 ]
[ 1477527-27-7 ]
[ 2231325-01-0 ]

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide at 100℃;	3 The TPE-im (0.05g, 1 equivalent) and bromoethane (0.07g, 6 equivalent) prepared in Example 1 are dissolved in DMF (10mL) and heated the reaction solution at 100 °C. The reaction is stirred for another 24 h. After cooling, remove DMF with an evaporator, then add EA to filter the precipitate to obtain a white solid.

Reference： [1]Current Patent Assignee: ZHEJIANG UNIV HANGZHOU INTERNATIONAL KOCH CENTER - CN116041262, 2023, A Location in patent: Paragraph 0084-0090

29
[ 119-61-9 ]
[ 1477527-27-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: zinc; titanium tetrachloride / tetrahydrofuran / 12 h / Reflux; Inert atmosphere 2: bromine / dichloromethane / 12 h / 20 °C 3: copper(ll) sulfate pentahydrate; potassium carbonate / 24 h / 160 °C / Schlenk technique; Inert atmosphere

Reference： [1]Current Patent Assignee: ZHEJIANG UNIV HANGZHOU INTERNATIONAL KOCH CENTER - CN116041262, 2023, A

30
[ 632-51-9 ]
[ 1477527-27-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: bromine / dichloromethane / 12 h / 20 °C 2: copper(ll) sulfate pentahydrate; potassium carbonate / 24 h / 160 °C / Schlenk technique; Inert atmosphere

Reference： [1]Current Patent Assignee: ZHEJIANG UNIV HANGZHOU INTERNATIONAL KOCH CENTER - CN116041262, 2023, A

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Ghs Precautionary Statements

Precautionary Statements-General
Code	Phrase
P101	If medical advice is needed,have product container or label at hand.
P102	Keep out of reach of children.
P103	Read label before use
Prevention
Code	Phrase
P201	Obtain special instructions before use.
P202	Do not handle until all safety precautions have been read and understood.
P210	Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P211	Do not spray on an open flame or other ignition source.
P220	Keep/Store away from clothing/combustible materials.
P221	Take any precaution to avoid mixing with combustibles
P222	Do not allow contact with air.
P223	Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230	Keep wetted
P231	Handle under inert gas.
P232	Protect from moisture.
P233	Keep container tightly closed.
P234	Keep only in original container.
P235	Keep cool
P240	Ground/bond container and receiving equipment.
P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 1477527-27-7 ] {[proInfo.proName]}

Quality Control of [ 1477527-27-7 ]

Related Doc. of [ 1477527-27-7 ]

Product Details of [ 1477527-27-7 ]

Safety of [ 1477527-27-7 ]

Application In Synthesis of [ 1477527-27-7 ]

[ 1477527-27-7 ] Synthesis Path-Downstream 1~30

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry