[ CAS No. 14172-91-9 ] {[proInfo.proName]}

Name: 14172-91-9|5,10,15,20-Tetraphenyl-21H,23H-porphine copper(II)|98%
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Product Details of [ 14172-91-9 ]

CAS No. :	14172-91-9	MDL No. :	MFCD00148862
Formula :	C₄₄H₂₈CuN₄	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	676.27	Pubchem ID :	-
Synonyms :

Safety of [ 14172-91-9 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P261-P305+P351+P338	UN#:	N/A
Hazard Statements:	H302-H315-H319-H335	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 14172-91-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 14172-91-9 ]

[ 14172-91-9 ] Synthesis Path-Downstream 1~88

1
[ 917-23-7 ]
copper(II) perchlorate hexahydrate [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[2]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[3]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[4]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[5]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[6]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[7]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[8]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[9]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[10]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[11]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[12]Inorganic Chemistry,1982,vol. 21,p. 2323 - 2327
[13]Journal of Physical Chemistry,1992,vol. 96,p. 1204 - 1215

2
[ 917-23-7 ]
copper(II) choride dihydrate [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565

3
[ 917-23-7 ]
copper dichloride [ No CAS ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; In water; at 350.0℃; for 0.0666667h;Inert atmosphere; Sealed tube;	Using a 50 mL volumetric flask, 1.208 g of copper sulfate as a metal salt was dissolved in 50 mL of distilled water to prepare a 0.1 mol / L CuSO 4 aqueous solution. Next, 0.02 g (3.3 × 10 -5 mol) of tetraphenylporphyrin (TPP) as a compound having a porphyrin-type skeleton, 0.02 g (3.3 × 10 -5 mol) of copper sulfate Aqueous solution of sodium carbonate and 0.032 g of sodium carbonate equivalent to copper sulfate to prevent corrosion of the reaction vessel, and the interior of the reaction vessel was purged with argon and sealed. Next, the reaction vessel was charged into the sand bath set at 350 C. The reaction temperature in the reaction vessel reached the reaction temperature in about 4 minutes.

Reference： [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652
[2]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 276 - 281
[3]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680
[4]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680
[5]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680
[6]Kinetics and Catalysis,1989,vol. 29,p. 674 - 680
[7]Patent: JP5823988,2015,B2 .Location in patent: Paragraph 0068

4
[ 917-23-7 ]
[ 142-71-2 ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
400 mg	With acetic acid; In chloroform; for 2h;Reflux;	Copper tetraphenyl porphyrin was synthesised by taking tetra phenyl porphyrin[H2(TPP)]16(500mg) in chloroform(100ml).Copper(II) acetate(200mg) in glacial aceticacid(50ml) was added to the above solution andthe mixture was refluxed for 2hrs. The contents wereconcentrated to a volume of about 50-60ml andcooled to room temperature which resulted in crudecopper-tetraphenyl porphyrin Cu(TPP) (about450mg). The crude product was purified by columnchromatography using neutral alumina andchloroform as eluent. On elution the unreactedtetraphenyl porphyrin was eluted out first, followedby pure Cu(TPP). The chloroform fraction containingCu(TPP) was concentrated to obtain pure crystalsof Cu(TPP)[2]. The formation of Cu(TPP) wasmonitored by UV-visible spectroscopy which givepeaks-around 580, 541 and 417nm respectivelyconfirming the formation of Cu(TPP) (yield=400mg).

Reference： [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652
[2]Thesis Clark Univ., Worcester, Mass., 1957, S. 34,
[3]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760
[4]Journal of the American Chemical Society,1948,vol. 70,p. 1808 - 1812
[5]Journal of Thermal Analysis and Calorimetry,1998,vol. 54,p. 243 - 248
[6]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442
[7]Journal of the American Chemical Society,1948,vol. 70,p. 1808 - 1812
[8]Journal of Thermal Analysis and Calorimetry,1998,vol. 54,p. 243 - 248
[9]Journal of Physics and Chemistry of Solids,1988,vol. 49,p. 315 - 322
[10]Journal of the American Chemical Society,1951,vol. 73,p. 4315 - 4320
[11]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760
[12]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760
[13]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760
[14]Oriental Journal of Chemistry,2015,vol. 31,p. 1195 - 1200

5
7,8-dihydro-5,10,15,20-tetraphenylporphyrin [ No CAS ]
[ 142-71-2 ]
[ 14172-91-9 ]

Reference： [1]Journal of Chemical Physics,1988,vol. 89,p. 6567 - 6576

6
[ 10170-99-7 ]
[ 917-23-7 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442
[2]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

7
[ 917-23-7 ]
[ 13014-03-4 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

8
[ 917-23-7 ]
[ 45227-32-5 ]
[ 14172-91-9 ]

Reference： [1]Inorganic Chemistry,2001,vol. 40,p. 5636 - 5644

9
[ 917-23-7 ]
[ 7787-70-4 ]
[ 14172-91-9 ]

Reference： [1]Canadian Journal of Chemistry,1990,vol. 68,p. 2234 - 2238

10
[ 917-23-7 ]
copper(II) oxide [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652

11
[ 917-23-7 ]
[ 12775-96-1 ]
[ 14172-91-9 ]

Reference： [1]Journal of Chemical Research - Part S,
Journal of Chemical Research, Synopses,1981,p. 14 - 14
[2]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652

12
[ 917-23-7 ]
[ 377741-30-5 ]
[ 14172-91-9 ]

Reference： [1]Inorganic Chemistry,2001,vol. 40,p. 5636 - 5644

13
[ 917-23-7 ]
[ 503276-25-3 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

14
[ 917-23-7 ]
copper(II) nitrate [ No CAS ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; In water; at 350.0℃; for 0.0666667h;Inert atmosphere; Sealed tube;	Using a 50 mL volumetric flask, 1.208 g of copper sulfate as a metal salt was dissolved in 50 mL of distilled water to prepare a 0.1 mol / L CuSO 4 aqueous solution. Next, 0.02 g (3.3 × 10 -5 mol) of tetraphenylporphyrin (TPP) as a compound having a porphyrin-type skeleton, 0.02 g (3.3 × 10 -5 mol) of copper sulfate Aqueous solution of sodium carbonate and 0.032 g of sodium carbonate equivalent to copper sulfate to prevent corrosion of the reaction vessel, and the interior of the reaction vessel was purged with argon and sealed. Next, the reaction vessel was charged into the sand bath set at 350 C. The reaction temperature in the reaction vessel reached the reaction temperature in about 4 minutes.

Reference： [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652
[2]Patent: JP5823988,2015,B2 .Location in patent: Paragraph 0068

15
[ 917-23-7 ]
[ 6046-93-1 ]
[ 14172-91-9 ]

Reference： [1]Russian Chemical Bulletin,2007,vol. 56,p. 748 - 753

16
[ 917-23-7 ]
copper(II) perchlorate [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Helvetica Chimica Acta,1956,vol. 39,p. 2130 - 2132
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760

17
[ 917-23-7 ]
copper(II) ethylenediaminetetraacetate [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 529 - 533

18
[ 917-23-7 ]
[ 15416-63-4 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775
[2]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442

19
[ 917-23-7 ]
[ 16561-86-7 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775
[2]Russian Journal of Inorganic Chemistry,2003,vol. 48,p. 439 - 442

20
[ 917-23-7 ]
[ 31106-16-8 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

21
[ 917-23-7 ]
[ 12320-32-0 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

22
[ 917-23-7 ]
copper(II) α-nitroso-β-naphtholate [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

23
[ 917-23-7 ]
[ 34946-82-2 ]
[ 14172-91-9 ]
Cu((C₆H₅)4C₂₀H₁₀N₄)⁽²⁺⁾ [ No CAS ]

Reference： [1]Polyhedron,2000,vol. 19,p. 633 - 639

24
[ 917-23-7 ]
[ 13395-16-9 ]
[ 14172-91-9 ]

Reference： [1]Inorganic Chemistry,1992,vol. 31,p. 2877 - 2880
[2]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

25
copper(ll) sulfate pentahydrate [ No CAS ]
[ 917-23-7 ]
[ 14172-91-9 ]

Reference： [1]Inorganic Chemistry,1985,vol. 24,p. 3538 - 3541

26
[ 917-23-7 ]
[ 7758-99-8 ]
[ 14172-91-9 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate; In water; at 350.0℃; for 0.0666667h;Inert atmosphere; Sealed tube;	Using a 50 mL volumetric flask, 1.208 g of copper sulfate as a metal salt was dissolved in 50 mL of distilled water to prepare a 0.1 mol / L CuSO 4 aqueous solution. Next, 0.02 g (3.3 × 10 -5 mol) of tetraphenylporphyrin (TPP) as a compound having a porphyrin-type skeleton, 0.02 g (3.3 × 10 -5 mol) of copper sulfate Aqueous solution of sodium carbonate and 0.032 g of sodium carbonate equivalent to copper sulfate to prevent corrosion of the reaction vessel, and the interior of the reaction vessel was purged with argon and sealed. Next, the reaction vessel was charged into the sand bath set at 350 C. The reaction temperature in the reaction vessel reached the reaction temperature in about 4 minutes.

27
copper(I) oxide [ No CAS ]
[ 917-23-7 ]
[ 14172-91-9 ]

Reference： [1]Doklady Physical Chemistry,1983,vol. 271,p. 510 - 512
Dokl. Phys. Chem. (Transl. of Dokl. Akad. Nauk.),1983,vol. 271,p. 650 - 652

28
[ 917-23-7 ]
[ 91199-75-6 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2002,vol. 28,p. 771 - 775

29
[ 14172-91-9 ]
[ 68-12-2 ]
[ 71763-49-0 ]

Yield	Reaction Conditions	Operation in experiment
87%		General procedure: Under the protection of nitrogen, 0.14 mmol of the corresponding 5,10,15,20-tetrakis(4-R-phenyl)porphyrin copper(II)complex was dissolved in 16 ml of CHCl3, to which 0.75 ml of DMFwas added with magnetic stirring. The solution was cooled to 0 Cin an ice bath, and then 0.56 ml of phosphoryl chloride (POCl3) wasslowly added within 20 min. The ice bath was removed and stirringwas continued at room temperature for 1 h, and the solution wascontinuously stirred and heated at 70 C for 24 h. Then 3.606 g ofNaAc and 14.4 ml of distilled water were added in an ice bath andstirring for another 1 h. After separation of the aqueous layer, theorganic layer was washed with 10 ml of distilled water for 3 times,then dried over anhydrous magnesium sulfate and filtered. Thesolvent was removed by rotary evaporation at low temperature toafford a crude product. The crude product was dissolved indichloromethane and subjected to column chromatography overneutral alumina with dichloromethane/petroleum ether (v/v 3:1)as the eluent. The third coloured bandwas collected and the solventwas removed by rotary evaporation to afford a purple powder.

Reference： [1]Inorganica Chimica Acta,1980,vol. 45,p. L161 - L164
[2]Journal of the American Chemical Society,2002,vol. 124,p. 6168 - 6179
[3]Journal of Molecular Structure,2019,vol. 1188,p. 244 - 254
[4]Russian Chemical Bulletin,2007,vol. 56,p. 160 - 167

30
[ 14172-91-9 ]
[ 10544-72-6 ]
C₄₄H₂₈CuN₆O₄ [ No CAS ]

Reference： [1]Journal of Physics and Chemistry of Solids,1988,vol. 49,p. 315 - 322

31
[ 71147-55-2 ]
[ 124-41-4 ]
[ 14172-91-9 ]
[ 95386-81-5 ]
[ 95386-84-8 ]

Reference： [1]Journal of the Chemical Society. Perkin Transactions 2 (2001),1996,vol. 1996,p. 1251 - 1260

32
[ 71147-55-2 ]
[ 124-41-4 ]
[ 14172-91-9 ]

Reference： [1]Journal of the Chemical Society. Perkin Transactions 2 (2001),1996,vol. 1996,p. 1251 - 1260

33
[ 52064-15-0 ]
[ 14172-91-9 ]

Reference： [1]Journal of the American Chemical Society,1946,vol. 68,p. 2278
[2]Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760

34
[ 10380-28-6 ]
N-methyl-5,10,15,20-tetraphenylporphyrin [ No CAS ]
[ 14172-91-9 ]
C₄₅H₃₁N₄CuC₉H₆NO [ No CAS ]

Reference： [1]Russian Journal of General Chemistry,2000,vol. 70,p. 1299 - 1303

35
[ 14172-91-9 ]
(5,10,15,20-tetraphenylporphyrinato)copper(II) cation radical [ No CAS ]

Reference： [1]Dalton Transactions,2004,p. 1703 - 1707

36
[ 14172-91-9 ]
copper(II) oxide [ No CAS ]

Reference： [1]Thermochimica Acta,1989,vol. 143,p. 67 - 74

37
[ 14977-07-2 ]
copper(II) nitrate [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2005,vol. 31,p. 95 - 100
[2]Russian Journal of Coordination Chemistry,2005,vol. 31,p. 95 - 100
[3]Russian Journal of General Chemistry,2010,vol. 80,p. 518 - 526

38
[ 14977-07-2 ]
[ 142-71-2 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2005,vol. 31,p. 95 - 100
[2]Russian Journal of General Chemistry,2010,vol. 80,p. 518 - 526
[3]Russian Journal of Inorganic Chemistry,2012,vol. 57,p. 744 - 750
[4]Russian Journal of Inorganic Chemistry,2012,vol. 57,p. 744 - 750
[5]Russian Journal of Inorganic Chemistry,2012,vol. 57,p. 744 - 750
[6]Russian Journal of Inorganic Chemistry,2012,vol. 57,p. 744 - 750
[7]Russian Journal of Inorganic Chemistry,2012,vol. 57,p. 744 - 750
[8]Russian Journal of Inorganic Chemistry,2013,vol. 58,p. 486 - 490
Zh. Neorg. Khim.,2013,vol. 58,p. 553 - 557,5
[9]Russian Journal of General Chemistry,2016,vol. 86,p. 102 - 109
Zh. Obshch. Khim.,2016,vol. 86,p. 110 - 117,8

39
[ 14977-07-2 ]
copper dichloride [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2005,vol. 31,p. 95 - 100
[2]Russian Journal of General Chemistry,2010,vol. 80,p. 518 - 526

40
[ 14172-91-9 ]
[ 293-42-5 ]
disulphidothionitrato(meso-tetraphenylporphyrinato)copper(III) [ No CAS ]

Reference： [1]Polyhedron,1989,vol. 8,p. 1447 - 1452

41
[ 14172-91-9 ]
{Cu(II)-tetraphenylporphyrin}-radical cation [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1993,vol. 115,p. 12029 - 12034
[2]Journal of Physical Chemistry B,2008,vol. 112,p. 2842 - 2847

42
[ 14172-91-9 ]
[ 123582-29-6 ]

Reference： [1]Polyhedron,1989,vol. 8,p. 1447 - 1452

43
[ 14172-91-9 ]
copper(II) nitrate [ No CAS ]
[ 71147-55-2 ]

Reference： [1]Polyhedron,1994,vol. 13,p. 1863 - 1874

44
[ 14172-91-9 ]
[ 131214-87-4 ]

Yield	Reaction Conditions	Operation in experiment
72%		0.0157 g (0.088 mmol) of N-bromosuccinimide was added to a solution of 0.04 g (0.059 mmol) of Cuin 20 mL of l3, and the mixture was refluxed during 30 min. The operation was repeated three times,total amount of the added N-bromosuccinimide being0.047 g (0.26 mmol). After addition of the last portion of the reactant, the mixture was refluxed during 2 hand cooled to ambient; a solution of 0.07 g (0.44 mmol)of bromine in 5 mL of CHCl3 was then added atstirring. The resulting mixture was kept at 20 during about 24 h. Excess of bromine was removed by washing the reaction mixture with 15 mL of 20%aqueous solution of Na2S2O3. The organic layer was washed with water and dried over Na2SO4. The solvent was removed, and the residue was purified by chromatographyon alumina eluting with chloroform,followed by recrystallization from ethanol. Yield 0.055 g(72%, 0.0421 mmol).
68%	With N-Bromosuccinimide; In chloroform; N,N-dimethyl-formamide; at 20.0℃; for 8h;	(a) N-Bromosuccinimide (0.105 g, 0.592 mmol) was added with stirring to a solution of 0.02 g (0.0296 mmol) of complex 5 in a mixture of 10 mL of chloroform and 1 mL of DMF, the mixture was stirred at ambient temperature for 8 h. The reaction mixture was concentrated to minimal volume, 10 mL of DMF, water, and solid NaCl were added, the precipitate was separated by filtration, washed with water, acetonitrile, dried, chromatographed on aluminum oxide using chloroform as an eluent, and reprecipitated from ethanol. Yield 0.026 g (0.0199 mmol), 68%. MS (m/z (Irel, %)): 1306.6 (98) [M]+; for C44H20N4Br8Cu calcd.: 1307.5. IR (nu, cm-1): 2925 s, 2853 m nu(C-H, Ph), 1680 w, 1488 m nu(C=C, Ph), 1467 w, 1444 w nu(C=N), 1366 w, 1351 w nu(C-N), 1175 m, 1145 w, 1108 w delta(C-H, Ph), 1024 s nu(C-C), 924 m, 858 m gamma(C-H, pyrrole ring), 756 m, 734 m, 695 m gamma(C-H, Ph). For C44H20N4Br8Cu anal. calcd. (%): C, 40.42; N, 4.29; H, 1.54; Br, 48.89. Found (%): C, 40.15; N, 4.16; H, 1.59; Br, 48.71.

Reference： [1]Inorganic Chemistry,1991,vol. 30,p. 239 - 245
[2]Russian Journal of General Chemistry,2016,vol. 86,p. 102 - 109
Zh. Obshch. Khim.,2016,vol. 86,p. 110 - 117,8
[3]Russian Journal of Inorganic Chemistry,2018,vol. 63,p. 732 - 735
Zh. Neorg. Khim.,2018,vol. 63,p. 695 - 699,5

45
(N-methyl-5,10,15,20-tetraphenylporphinato)copper(II)⁽¹⁺⁾ [ No CAS ]
[ 111-92-2 ]
[ 1017265-92-7 ]
[ 14172-91-9 ]

Reference： [1]Inorganic Chemistry,1983,vol. 22,p. 1095 - 1099

46
[ 14172-91-9 ]
[ 683-60-3 ]
copper(tetraphenylporphyrine) ^(1-) [ No CAS ]

Reference： [1]Journal of Physical Chemistry,1994,vol. 98,p. 4617 - 4621

47
(N-methyl-5,10,15,20-tetraphenylporphinato)copper(II)⁽¹⁺⁾ [ No CAS ]
[ 109-89-7 ]
[ 14172-91-9 ]
[ 85649-95-2 ]

Reference： [1]Inorganic Chemistry,1983,vol. 22,p. 1095 - 1099

48
[ 14172-91-9 ]
tris-(4-bromophenyl)aminium hexachloroantimonate [ No CAS ]
Cu(C₆H₅)4C₂₀H₈N₄⁽¹⁺⁾*SbCl₆^(1-) = {Cu(C₆H₅)4C₂₀H₈N₄}SbCl₆ [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1982,vol. 104,p. 6791 - 6793

49
copper(tetraphenylporphyrine) ^(1-) [ No CAS ]
[ 99685-96-8 ]
[ 14172-91-9 ]
fullerene [ No CAS ]

Reference： [1]Journal of Physical Chemistry,1994,vol. 98,p. 4617 - 4621

50
[ 3524-08-1 ]
[ 14172-91-9 ]
5,10,15,20-tetraphenylporphyrinatocopper(II)*4,6-dinitrobenzofuroxan [ No CAS ]

Reference： [1]Canadian Journal of Chemistry,1984,vol. 62,p. 475 - 480

51
[ 14172-91-9 ]
phenyloxathiinylium hexachloroantimonate [ No CAS ]
Cu(C₂₀H₈N₄(C₆H₅)4)⁽¹⁺⁾*SbCl₆^(1-)*0.5CH₂Cl₂={Cu(C₂₀H₈N₄(C₆H₅)4)}{SbCl₆}*0.5CH₂Cl₂ [ No CAS ]

Reference： [1]Journal of the American Chemical Society,1987,vol. 109,p. 2644 - 2652

52
[ 553-26-4 ]
[ 14172-91-9 ]
[Cu(II)(tetraphenylporphyrin)(4,4'-bipyridine)2] [ No CAS ]

Reference： [1]Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry,2001,vol. 31,p. 1041 - 1051

53
[ 128-09-6 ]
[ 14172-91-9 ]
[ 873796-70-4 ]

Reference： [1]European Journal of Inorganic Chemistry,2005,p. 1609 - 1615

54
[ 917-23-7 ]
[ 31794-94-2 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2004,vol. 49,p. 1670 - 1673

55
[ 917-23-7 ]
Cu(AlaGly)Cl*H₂O [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2004,vol. 49,p. 1670 - 1673

56
[ 917-23-7 ]
Cu(AlaGly)*2H₂O [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2004,vol. 49,p. 1670 - 1673

57
[ 917-23-7 ]
[ 872605-81-7 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2004,vol. 49,p. 1670 - 1673

58
copper tetraphenylporphyrin o-xylene [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Thermochimica Acta,1998,vol. 311,p. 163 - 171

59
[ 205876-11-5 ]
[ 14172-91-9 ]

Reference： [1]Thermochimica Acta,1998,vol. 311,p. 163 - 171

60
[ 14172-91-9 ]
5-(4-fluoresceinpropyloxy)phenyl-10,15,20-triphenylporphyrin [ No CAS ]
[Cu((5,10,15,20-tetraphenylporphyrin))]*(C₄H₂NHCPh)(C₄H₂NCPh)C₄H₂NHCPh)(C₄H₂NCC₆H₄O(CH₂)3OC₁₃H₆O(O)(C₆H₄COOH)) [ No CAS ]

Reference： [1]Inorganic Chemistry Communications,2004,vol. 7,p. 1030 - 1033

61
[ 917-23-7 ]
[ 790170-59-1 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565
[2]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 276 - 281

62
[ 917-23-7 ]
[ 63904-13-2 ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 276 - 281
[2]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565

63
[ 917-23-7 ]
[CuCl₂((-)-adenosine)2] [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565
[2]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 276 - 281

64
[ 917-23-7 ]
[CuCl₂((-)-adenosine)]2 [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565
[2]Russian Journal of Coordination Chemistry,2006,vol. 32,p. 276 - 281

65
[ 917-23-7 ]
[CuCl₂(adenine(+1H))2] [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of Inorganic Chemistry,2005,vol. 50,p. 1561 - 1565

66
[ 14172-91-9 ]
[ 71-43-2 ]
[ 179032-09-8 ]

Reference： [1]Thermochimica Acta,1996,vol. 279,p. 121 - 136

67
[ 179032-09-8 ]
[ 14172-91-9 ]

Reference： [1]Thermochimica Acta,1996,vol. 279,p. 121 - 136

68
[ 14172-91-9 ]
[ 28132-68-5 ]

Reference： [1]Journal of Physical Chemistry B,2008,vol. 112,p. 2842 - 2847

69
[ 917-23-7 ]
[ 14172-91-9 ]

Reference： [1]Chemical Communications,2010,vol. 46,p. 7536 - 7538
[2]Advanced Synthesis and Catalysis,2009,vol. 351,p. 2391 - 2410
[3]Inorganic Chemistry Communications,2011,vol. 14,p. 1561 - 1568
[4]Russian Journal of General Chemistry,2016,vol. 86,p. 102 - 109
Zh. Obshch. Khim.,2016,vol. 86,p. 110 - 117,8

70
[ 14977-07-2 ]
bis(acetylacetonate)copper(II) [ No CAS ]
[ 14172-91-9 ]

Reference： [1]Russian Journal of General Chemistry,2010,vol. 80,p. 518 - 526

71
[ 14172-91-9 ]
2-Nitro-5,10,15,20-tetraphenylporphyrin [ No CAS ]