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Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
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Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
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* Storage: {[proInfo.prStorage]}
CAS No. : | 138219-98-4 | MDL No. : | MFCD20265579 |
Formula : | C12H10Cl2N2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | VZKSOWFFOHQARA-UHFFFAOYSA-N |
M.W : | 253.13 | Pubchem ID : | 10562811 |
Synonyms : |
|
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501 | UN#: | 3261 |
Hazard Statements: | H290-H314 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
94% | With hexachloroethane; tetrabutyl ammonium fluoride; silica gel In tetrahydrofuran | |
91% | With potassium fluoride; hexachloroethane In N,N-dimethyl-formamide at 20℃; Inert atmosphere; | |
91% | With potassium fluoride; hexachloroethane In N,N-dimethyl-formamide at 20℃; Inert atmosphere; | I.5 5) 4,4'-bis(chloromethyl)-2,2'-bipyridine, Intermediate Compound 5A solution composed of compound 4 (2 g, 6.1 mmol), hexachloroethane (5.8 g, 24.3 mmol) and KF (1.42 g, 24.3 mmol) in anhydrous DMF (30 ml) was stirred overnight at room temperature under N2. EtOAc (150 ml) was added. The organic layer was washed with water (5×100 ml), dried over MgSO4 and evaporated to dryness. The resulting solid was dissolved in the minimum volume of hexane and let stand in the freezer for few hours. The resulting white crystalline solid was filtered and washed with small cold portions of hexane to afford 1.4 g (91%) of compound 5 as white crystalline solid.1H-NMR (CDCl3, 298K, 200 MHz, δ ppm) 4.65 (s, 4H), 7.40 (d, J=5 Hz, 2H), 8.45 (s, 2H), 8.70 (d, J=5 Hz, 2H). |
91% | With hexachloroethane; cesium fluoride In acetonitrile at 60℃; for 3.5h; Inert atmosphere; | |
91% | With hexachloroethane; cesium fluoride In acetonitrile at 60℃; for 3.5h; Inert atmosphere; | |
84% | With hexachloroethane; cesium fluoride In acetonitrile at 65℃; for 4h; Inert atmosphere; | |
46% | With hexachloroethane; cesium fluoride In N,N-dimethyl-formamide at 20℃; | |
With hexachloroethane; tetrabutyl ammonium fluoride; silica gel In tetrahydrofuran at -78℃; | ||
With hexachloroethane; cesium fluoride In acetonitrile Inert atmosphere; Schlenk technique; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With chloro-trimethyl-silane; CFC-112a; caesium carbonate; cesium fluoride; lithium diisopropyl amide 1.) THF, -78 deg C, 2.) DMF, 25 deg C; Yield given; Multistep reaction; | ||
Multi-step reaction with 2 steps 1: 1.) LDA / 1.) THF, -78 deg C, 20 min; -78 deg C to -10 deg C, 25 min, 2.) -78 deg C, 10 s 2: 94 percent / Cl3CCCl3, TBAF/SiO2 / tetrahydrofuran | ||
Stage #1: 4,4'-dimethyl-2,2'-bipyridines With chloro-trimethyl-silane; lithium diisopropyl amide In tetrahydrofuran; ethanol at -70℃; for 0.00416667h; Inert atmosphere; Stage #2: With hexachloroethane; cesium fluoride In acetonitrile at 75℃; for 4h; Inert atmosphere; |
Multi-step reaction with 2 steps 1: lithium diisopropyl amide / tetrahydrofuran 2: potassium fluoride; hexachloroethane / N,N-dimethyl-formamide / 20 °C / Inert atmosphere | ||
Stage #1: 4,4'-dimethyl-2,2'-bipyridines With lithium diisopropyl amide In tetrahydrofuran at -78℃; Stage #2: With chloro-trimethyl-silane In ethanol for 0.00416667h; Stage #3: With hexachloroethane; cesium fluoride In N,N-dimethyl-formamide at 20℃; for 0.5h; | ||
Multi-step reaction with 2 steps 1.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 0.75 h / -78 - -10 °C 1.2: -78 °C 2.1: hexachloroethane; cesium fluoride / acetonitrile / 3.5 h / 60 °C / Inert atmosphere | ||
Multi-step reaction with 2 steps 1.1: lithium diisopropyl amide / tetrahydrofuran / Inert atmosphere; Schlenk technique 1.2: Inert atmosphere; Schlenk technique 2.1: hexachloroethane; cesium fluoride / acetonitrile / Inert atmosphere; Schlenk technique | ||
Multi-step reaction with 2 steps 1.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: hexachloroethane; cesium fluoride / acetonitrile / 3.5 h / 60 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 3h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 4h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 1h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 2h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 3h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 4h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 5h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(l) chloride at 60℃; for 6h; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,1,4,7,10,10-hexamethyltriethylenetetramine; copper(I) bromide In methoxybenzene |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,1,4,7,10,10-hexamethyltriethylenetetramine; copper(I) bromide In methoxybenzene |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,1,4,7,10,10-hexamethyltriethylenetetramine; copper(I) bromide In methoxybenzene |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With 1,1,4,7,10,10-hexamethyltriethylenetetramine; copper(I) bromide In methoxybenzene |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
93% | at 120℃; for 12h; Inert atmosphere; | |
90% | at 140℃; for 24h; Inert atmosphere; | |
88% | Inert atmosphere; Reflux; |
88% | at 140℃; for 24h; Inert atmosphere; | |
85% | at 160℃; Inert atmosphere; | |
85% | Reflux; Inert atmosphere; | I.6 6) 4,4'-bis(diethyl methylphosphonate)-2,2'-bipyridine, Intermediate Compound 6.Compound 5 (2.6 g, 10.3 mmol) was refluxed overnight under N2 in triethylphosphite (50 ml). Excess P(OEt)3 was evaporated and the resulting brown oil was column chromatographed (Al2O3, CH2Cl2/MeOH: 98/2). The yellow oil thus obtained was dissolved in a mixture of CH2Cl2/hexane (1/50 ml) and let stand in the freezer to afford after filtration 4 g (85%) of compound 6 as a slightly yellow crystalline solid.1H-NMR (CDCl3, 298K, 200 MHz, δ ppm) 1.27 (t, J=7 Hz, 12H), 3.18 (s, 2H), 3.29 (s, 2H), 4.08 (m, 8H), 7.33 (d, J=5 Hz, 2H), 8.34 (s, 2H), 8.60 (d, J=5 Hz, 2H). |
at 120℃; Inert atmosphere; | ||
Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 120 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 3 steps 1: 120 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 20 °C / Inert atmosphere 3: hydrogenchloride; water / methanol / Inert atmosphere; Reflux |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 120 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
In toluene Heating; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: toluene / Heating 2: water / 20 °C |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Reflux; Inert atmosphere 2: potassium <i>tert</i>-butylate / N,N-dimethyl-formamide / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Reflux; Inert atmosphere 2: potassium <i>tert</i>-butylate / N,N-dimethyl-formamide / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 24 h / 140 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 24 h / 70 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 24 h / 140 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 24 h / 70 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: 24 h / 140 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 24 h / 70 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Multi-step reaction with 2 steps 1: Heating 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
48% | Stage #1: 2-(hydroxymethyl)-12-crown-4 With sodium hydride In tetrahydrofuran for 1h; Inert atmosphere; Stage #2: 4,4’-bis(chloromethyl)-2,2’-bipyridine In tetrahydrofuran at 20℃; for 4h; Inert atmosphere; |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
Stage #1: 2-phenylpyridine; 4,4’-bis(chloromethyl)-2,2’-bipyridine; cyclometalated Ir(III) dimer In methanol; dichloromethane Reflux; Stage #2: ammonium hexafluorophosphate In methanol; dichloromethane |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
55% | Stage #1: rhodium(III) chloride hydrate; 4,4’-bis(chloromethyl)-2,2’-bipyridine In N,N-dimethyl-formamide Inert atmosphere; Reflux; Stage #2: ammonium hexafluorophosphate |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
80% | Stage #1: [Ru(1,10-phenanthroline)2Cl2]; 4,4’-bis(chloromethyl)-2,2’-bipyridine In methanol Inert atmosphere; Reflux; Stage #2: ammonium hexafluorophosphate |
Tags: 138219-98-4 synthesis path| 138219-98-4 SDS| 138219-98-4 COA| 138219-98-4 purity| 138219-98-4 application| 138219-98-4 NMR| 138219-98-4 COA| 138219-98-4 structure
Precautionary Statements-General | |
Code | Phrase |
P101 | If medical advice is needed,have product container or label at hand. |
P102 | Keep out of reach of children. |
P103 | Read label before use |
Prevention | |
Code | Phrase |
P201 | Obtain special instructions before use. |
P202 | Do not handle until all safety precautions have been read and understood. |
P210 | Keep away from heat/sparks/open flames/hot surfaces. - No smoking. |
P211 | Do not spray on an open flame or other ignition source. |
P220 | Keep/Store away from clothing/combustible materials. |
P221 | Take any precaution to avoid mixing with combustibles |
P222 | Do not allow contact with air. |
P223 | Keep away from any possible contact with water, because of violent reaction and possible flash fire. |
P230 | Keep wetted |
P231 | Handle under inert gas. |
P232 | Protect from moisture. |
P233 | Keep container tightly closed. |
P234 | Keep only in original container. |
P235 | Keep cool |
P240 | Ground/bond container and receiving equipment. |
P241 | Use explosion-proof electrical/ventilating/lighting/equipment. |
P242 | Use only non-sparking tools. |
P243 | Take precautionary measures against static discharge. |
P244 | Keep reduction valves free from grease and oil. |
P250 | Do not subject to grinding/shock/friction. |
P251 | Pressurized container: Do not pierce or burn, even after use. |
P260 | Do not breathe dust/fume/gas/mist/vapours/spray. |
P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. |
P262 | Do not get in eyes, on skin, or on clothing. |
P263 | Avoid contact during pregnancy/while nursing. |
P264 | Wash hands thoroughly after handling. |
P265 | Wash skin thouroughly after handling. |
P270 | Do not eat, drink or smoke when using this product. |
P271 | Use only outdoors or in a well-ventilated area. |
P272 | Contaminated work clothing should not be allowed out of the workplace. |
P273 | Avoid release to the environment. |
P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
P281 | Use personal protective equipment as required. |
P282 | Wear cold insulating gloves/face shield/eye protection. |
P283 | Wear fire/flame resistant/retardant clothing. |
P284 | Wear respiratory protection. |
P285 | In case of inadequate ventilation wear respiratory protection. |
P231 + P232 | Handle under inert gas. Protect from moisture. |
P235 + P410 | Keep cool. Protect from sunlight. |
Response | |
Code | Phrase |
P301 | IF SWALLOWED: |
P304 | IF INHALED: |
P305 | IF IN EYES: |
P306 | IF ON CLOTHING: |
P307 | IF exposed: |
P308 | IF exposed or concerned: |
P309 | IF exposed or if you feel unwell: |
P310 | Immediately call a POISON CENTER or doctor/physician. |
P311 | Call a POISON CENTER or doctor/physician. |
P312 | Call a POISON CENTER or doctor/physician if you feel unwell. |
P313 | Get medical advice/attention. |
P314 | Get medical advice/attention if you feel unwell. |
P315 | Get immediate medical advice/attention. |
P320 | |
P302 + P352 | IF ON SKIN: wash with plenty of soap and water. |
P321 | |
P322 | |
P330 | Rinse mouth. |
P331 | Do NOT induce vomiting. |
P332 | IF SKIN irritation occurs: |
P333 | If skin irritation or rash occurs: |
P334 | Immerse in cool water/wrap n wet bandages. |
P335 | Brush off loose particles from skin. |
P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. |
P337 | If eye irritation persists: |
P338 | Remove contact lenses, if present and easy to do. Continue rinsing. |
P340 | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P341 | If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P342 | If experiencing respiratory symptoms: |
P350 | Gently wash with plenty of soap and water. |
P351 | Rinse cautiously with water for several minutes. |
P352 | Wash with plenty of soap and water. |
P353 | Rinse skin with water/shower. |
P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. |
P361 | Remove/Take off immediately all contaminated clothing. |
P362 | Take off contaminated clothing and wash before reuse. |
P363 | Wash contaminated clothing before reuse. |
P370 | In case of fire: |
P371 | In case of major fire and large quantities: |
P372 | Explosion risk in case of fire. |
P373 | DO NOT fight fire when fire reaches explosives. |
P374 | Fight fire with normal precautions from a reasonable distance. |
P376 | Stop leak if safe to do so. Oxidising gases (section 2.4) 1 |
P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. |
P378 | |
P380 | Evacuate area. |
P381 | Eliminate all ignition sources if safe to do so. |
P390 | Absorb spillage to prevent material damage. |
P391 | Collect spillage. Hazardous to the aquatic environment |
P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
P301 + P312 | IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. |
P302 + P334 | IF ON SKIN: Immerse in cool water/wrap in wet bandages. |
P302 + P350 | IF ON SKIN: Gently wash with plenty of soap and water. |
P303 + P361 + P353 | IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
P304 + P312 | IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell. |
P304 + P340 | IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. |
P304 + P341 | IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
P306 + P360 | IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes. |
P307 + P311 | IF exposed: call a POISON CENTER or doctor/physician. |
P308 + P313 | IF exposed or concerned: Get medical advice/attention. |
P309 + P311 | IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician. |
P332 + P313 | IF SKIN irritation occurs: Get medical advice/attention. |
P333 + P313 | IF SKIN irritation or rash occurs: Get medical advice/attention. |
P335 + P334 | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
P337 + P313 | IF eye irritation persists: Get medical advice/attention. |
P342 + P311 | IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
P370 + P376 | In case of fire: Stop leak if safe to Do so. |
P370 + P378 | In case of fire: |
P370 + P380 | In case of fire: Evacuate area. |
P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. |
Storage | |
Code | Phrase |
P401 | |
P402 | Store in a dry place. |
P403 | Store in a well-ventilated place. |
P404 | Store in a closed container. |
P405 | Store locked up. |
P406 | Store in corrosive resistant/ container with a resistant inner liner. |
P407 | Maintain air gap between stacks/pallets. |
P410 | Protect from sunlight. |
P411 | |
P412 | Do not expose to temperatures exceeding 50 oC/ 122 oF. |
P413 | |
P420 | Store away from other materials. |
P422 | |
P402 + P404 | Store in a dry place. Store in a closed container. |
P403 + P233 | Store in a well-ventilated place. Keep container tightly closed. |
P403 + P235 | Store in a well-ventilated place. Keep cool. |
P410 + P403 | Protect from sunlight. Store in a well-ventilated place. |
P410 + P412 | Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF. |
P411 + P235 | Keep cool. |
Disposal | |
Code | Phrase |
P501 | Dispose of contents/container to ... |
P502 | Refer to manufacturer/supplier for information on recovery/recycling |
Physical hazards | |
Code | Phrase |
H200 | Unstable explosive |
H201 | Explosive; mass explosion hazard |
H202 | Explosive; severe projection hazard |
H203 | Explosive; fire, blast or projection hazard |
H204 | Fire or projection hazard |
H205 | May mass explode in fire |
H220 | Extremely flammable gas |
H221 | Flammable gas |
H222 | Extremely flammable aerosol |
H223 | Flammable aerosol |
H224 | Extremely flammable liquid and vapour |
H225 | Highly flammable liquid and vapour |
H226 | Flammable liquid and vapour |
H227 | Combustible liquid |
H228 | Flammable solid |
H229 | Pressurized container: may burst if heated |
H230 | May react explosively even in the absence of air |
H231 | May react explosively even in the absence of air at elevated pressure and/or temperature |
H240 | Heating may cause an explosion |
H241 | Heating may cause a fire or explosion |
H242 | Heating may cause a fire |
H250 | Catches fire spontaneously if exposed to air |
H251 | Self-heating; may catch fire |
H252 | Self-heating in large quantities; may catch fire |
H260 | In contact with water releases flammable gases which may ignite spontaneously |
H261 | In contact with water releases flammable gas |
H270 | May cause or intensify fire; oxidizer |
H271 | May cause fire or explosion; strong oxidizer |
H272 | May intensify fire; oxidizer |
H280 | Contains gas under pressure; may explode if heated |
H281 | Contains refrigerated gas; may cause cryogenic burns or injury |
H290 | May be corrosive to metals |
Health hazards | |
Code | Phrase |
H300 | Fatal if swallowed |
H301 | Toxic if swallowed |
H302 | Harmful if swallowed |
H303 | May be harmful if swallowed |
H304 | May be fatal if swallowed and enters airways |
H305 | May be harmful if swallowed and enters airways |
H310 | Fatal in contact with skin |
H311 | Toxic in contact with skin |
H312 | Harmful in contact with skin |
H313 | May be harmful in contact with skin |
H314 | Causes severe skin burns and eye damage |
H315 | Causes skin irritation |
H316 | Causes mild skin irritation |
H317 | May cause an allergic skin reaction |
H318 | Causes serious eye damage |
H319 | Causes serious eye irritation |
H320 | Causes eye irritation |
H330 | Fatal if inhaled |
H331 | Toxic if inhaled |
H332 | Harmful if inhaled |
H333 | May be harmful if inhaled |
H334 | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
H335 | May cause respiratory irritation |
H336 | May cause drowsiness or dizziness |
H340 | May cause genetic defects |
H341 | Suspected of causing genetic defects |
H350 | May cause cancer |
H351 | Suspected of causing cancer |
H360 | May damage fertility or the unborn child |
H361 | Suspected of damaging fertility or the unborn child |
H361d | Suspected of damaging the unborn child |
H362 | May cause harm to breast-fed children |
H370 | Causes damage to organs |
H371 | May cause damage to organs |
H372 | Causes damage to organs through prolonged or repeated exposure |
H373 | May cause damage to organs through prolonged or repeated exposure |
Environmental hazards | |
Code | Phrase |
H400 | Very toxic to aquatic life |
H401 | Toxic to aquatic life |
H402 | Harmful to aquatic life |
H410 | Very toxic to aquatic life with long-lasting effects |
H411 | Toxic to aquatic life with long-lasting effects |
H412 | Harmful to aquatic life with long-lasting effects |
H413 | May cause long-lasting harmful effects to aquatic life |
H420 | Harms public health and the environment by destroying ozone in the upper atmosphere |
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