[ CAS No. 1351272-41-7 ] {[proInfo.proName]}

Name: 1351272-41-7|(2-(4-Vinylphenyl)ethene-1,1,2-triyl)tribenzene|98% mix TBC as stabilizer
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Quality Control of [ 1351272-41-7 ]

COA NMR CNMR HPLC LC-MS

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Product Details of [ 1351272-41-7 ]

CAS No. :	1351272-41-7	MDL No. :	MFCD32667035
Formula :	C₂₈H₂₂	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	VDXVOUZXBSOCMM-UHFFFAOYSA-N
M.W :	358.47	Pubchem ID :	132575439
Synonyms :

Safety of [ 1351272-41-7 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P280-P301+P312-P302+P352-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1351272-41-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 1351272-41-7 ]

[ 1351272-41-7 ] Synthesis Path-Downstream 1~26

1
[ 1289218-74-1 ]
[ 1779-49-3 ]
[ 1351272-41-7 ]

Reference： [1]Tetrahedron Letters,2012,vol. 53,p. 196 - 199
[2]Chemistry - A European Journal,2015,vol. 21,p. 1149 - 1155

2
[ 1351272-41-7 ]
[ 4181-20-8 ]
C₁₀₂H₇₅N [ No CAS ]

Reference： [1]Tetrahedron Letters,2012,vol. 53,p. 196 - 199

3
[ 90-90-4 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1.1: 0 °C / Acidic conditions 2.1: n-butyllithium / benzene / 2 h / 60 °C 2.2: 6 h / 20 °C 3.1: n-butyllithium / tetrahydrofuran / 6 h / -20 - 20 °C
	Multi-step reaction with 3 steps 1: n-butyllithium 2: n-butyllithium 3: potassium <i>tert</i>-butylate / tetrahydrofuran / 10 h / 0 °C / Inert atmosphere

Reference： [1]Jana, Debabrata; Ghorai, Binay K. [Tetrahedron Letters, 2012, vol. 53, # 2, p. 196 - 199]
[2]Qi, Qingkai; Qian, Jingyu; Ma, Suqian; Xu, Bin; Zhang, Sean Xiao-An; Tian, Wenjing [Chemistry - A European Journal, 2015, vol. 21, # 3, p. 1149 - 1155]

4
[ 34699-28-0 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1.1: n-butyllithium / benzene / 2 h / 60 °C 1.2: 6 h / 20 °C 2.1: n-butyllithium / tetrahydrofuran / 6 h / -20 - 20 °C
	Multi-step reaction with 2 steps 1: n-butyllithium 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 10 h / 0 °C / Inert atmosphere

5
[ 881-42-5 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1.1: 0 °C / Acidic conditions 2.1: n-butyllithium / benzene / 2 h / 60 °C 2.2: 6 h / 20 °C 3.1: n-butyllithium / tetrahydrofuran / 6 h / -20 - 20 °C

Reference： [1]Jana, Debabrata; Ghorai, Binay K. [Tetrahedron Letters, 2012, vol. 53, # 2, p. 196 - 199]

6
[ 1607-57-4 ]
[ 2156-04-9 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
88%	With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; potassium carbonate; In water; toluene; at 90℃; for 24h;Inert atmosphere;	First of all bromotriphenylethylene (4 g, 11.94 mmol) and 4- vinylphenylboronic acid (2.12 g, 14.32 mmol) were dissolved in toluene (100 ml) into a 250 ml three neck round bottom flask. TBAB (0.32 g, 0.1 mmol) and 2M aqueous solution of K2CO3 (24 ml) were added in above solution. The mixture was stirred 0.5 h under N2 atmosphere. During the purging of N2 Pd(PPh3)4 (0.01 g, 8.65 10 3 mmol) was added into the flask. N2 purging was continued for 20 min and then mixturewas stirred at 90 C for 24 h. The product was extracted with DCM and washed with water, organic layer was dried over anhydrous magnesium sulfate. Finally, the solvent was evaporated under vacuum and the crude product was passing through the silica column using Petroleum ether-DCM (4: 1 by volume) as an eluent give TPEE (Yield 3.15 g, 88%). 1H NMR (CDCl3, ppm): 5.22 (d, 1H of CH2 group in vinyl), 5.69 (d, 1H of CH2 group in vinyl), 6.65 (dd,1H of CH group in vinyl) 6.97e7.19 (m, 19H of aromatic part) ppm.
88%	With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; potassium carbonate; In water; toluene; at 90℃; for 24h;Inert atmosphere;	The TPE was prepared by the method already reported (Scheme 2)in excellent yield [31]. The 4-vinylphenylboronic acid (2.120 g,14.32 mmol), Ph3Br (4 g, 11.94 mmol) were dissolved in toluene(100 mL) in a round bottom flask then TBAB (0.320 g, 0.1 mmol) andK2CO3 (aqueous solution, 2 M, 24 mL) were added with stirringfollowed by addition of Pd(PPh3)4 (0.010 g, 8.65 × 10-3 mmol) undernitrogen gas. The reaction lasted for 24 h at 90 C. After cooled downto room temperature, the toluene was removed via vacuum distillationand then dissolved the product in dichloromethane (DCM, 150mL). Theproduct was extracted by washing with deionized water (three times)and drying over magnesium sulfate (anhydrous). The obtainedcrude productwas further purified by from silica column chromatographyusing the mixture of DCM and petroleum ether (4: 1 v/v) andTPE was obtained with excellent yield (88%) after the solvent wasevaporated. The 1H NMR of TPE is given in supporting information(Fig. S4).

Reference： [1]Macromolecular Bioscience,2014,vol. 14,p. 235 - 243
[2]New Journal of Chemistry,2019,vol. 43,p. 617 - 621
[3]Journal of Molecular Liquids,2019,vol. 296
[4]Journal of Molecular Liquids,2020,vol. 308
[5]RSC Advances,2015,vol. 5,p. 89472 - 89477
[6]Chinese Journal of Chemistry,2021,vol. 39,p. 1599 - 1605

7
[ 101-81-5 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 3 steps 1: n-butyllithium 2: n-butyllithium 3: potassium <i>tert</i>-butylate / tetrahydrofuran / 10 h / 0 °C / Inert atmosphere

Reference： [1]Qi, Qingkai; Qian, Jingyu; Ma, Suqian; Xu, Bin; Zhang, Sean Xiao-An; Tian, Wenjing [Chemistry - A European Journal, 2015, vol. 21, # 3, p. 1149 - 1155]

8
[ 1351272-41-7 ]
1,3,3-trimethylindolino-7’-bromobenzopyrylospiran [ No CAS ]
C₄₇H₃₉NO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
39%	With potassium phosphate; palladium diacetate In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;

Reference： [1]Qi, Qingkai; Qian, Jingyu; Ma, Suqian; Xu, Bin; Zhang, Sean Xiao-An; Tian, Wenjing [Chemistry - A European Journal, 2015, vol. 21, # 3, p. 1149 - 1155]

9
[ 1351272-41-7 ]
[ 16650-14-9 ]
C₄₇H₃₉NO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
34%	With potassium phosphate; palladium diacetate In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;

Reference： [1]Qi, Qingkai; Qian, Jingyu; Ma, Suqian; Xu, Bin; Zhang, Sean Xiao-An; Tian, Wenjing [Chemistry - A European Journal, 2015, vol. 21, # 3, p. 1149 - 1155]

10
[ 1351272-41-7 ]
C₂₆H₂₄F₂N₂O₂ [ No CAS ]
6,7-difluoro-2,3-bis(4-propoxyphenyl)-5,8-bis((E)-4-(1,2,2-triphenylvinyl)styryl)quinoxaline [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	With 1,10-Phenanthroline; palladium(II) trifluoroacetate; silver fluoride In N,N-dimethyl-formamide at 130℃; for 7h; Inert atmosphere;

Reference： [1]Zhang, Zeyuan; Zheng, Yiwen; Sun, Zuobang; Dai, Zhen; Tang, Ziqiang; Ma, Jiangshan; Ma, Chen [Advanced Synthesis and Catalysis, 2017, vol. 359, # 13, p. 2259 - 2268]

11
[ 1289218-74-1 ]
[ 2065-66-9 ]
[ 1351272-41-7 ]

Reference： [1]Advanced Synthesis and Catalysis,2017,vol. 359,p. 2259 - 2268

12
[ 1607-57-4 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; tetrabutylammomium bromide / water; toluene / 24 h / 90 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 24 h / 20 °C

Reference： [1]Zhang, Zeyuan; Zheng, Yiwen; Sun, Zuobang; Dai, Zhen; Tang, Ziqiang; Ma, Jiangshan; Ma, Chen [Advanced Synthesis and Catalysis, 2017, vol. 359, # 13, p. 2259 - 2268]

13
[ 87199-17-5 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; tetrabutylammomium bromide / water; toluene / 24 h / 90 °C / Inert atmosphere 2: potassium <i>tert</i>-butylate / tetrahydrofuran / 24 h / 20 °C

Reference： [1]Zhang, Zeyuan; Zheng, Yiwen; Sun, Zuobang; Dai, Zhen; Tang, Ziqiang; Ma, Jiangshan; Ma, Chen [Advanced Synthesis and Catalysis, 2017, vol. 359, # 13, p. 2259 - 2268]

14
[ 1351272-41-7 ]
[ 74388-46-8 ]
C₅₀H₄₀N₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
20%	With potassium phosphate; palladium diacetate In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;

Reference： [1]Peng, Shanchao; Wen, Jiahui; Hai, Mingtan; Yang, Zhou; Yuan, Xiaotao; Wang, Dong; Cao, Hui; He, Wanli [New Journal of Chemistry, 2019, vol. 43, # 2, p. 617 - 621]

15
[ 1351272-41-7 ]
[ 227471-78-5 ]
C₅₃H₃₈O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
39%	With potassium phosphate; palladium diacetate In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;

Reference： [1]Peng, Shanchao; Wen, Jiahui; Hai, Mingtan; Yang, Zhou; Yuan, Xiaotao; Wang, Dong; Cao, Hui; He, Wanli [New Journal of Chemistry, 2019, vol. 43, # 2, p. 617 - 621]

16
[ 1351272-41-7 ]
[ 92874-17-4 ]
(E)–2–butyl–6–(4–(1,2,2–triphenylvinyl)styryl)–1H–benzo[de]isoquinoline–1,3(2H)–dione [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61.3%	With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 90℃; Inert atmosphere;	Synthesis of NTPEs 3 and 4: General procedure: Compound 7 or 8 (0.2 g, 0.60 mmol),(2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene (0.226 g, 0.63 mmol),Pd(OAc)2 (0.0167 g, 0.00746 mmol), and P(o-tolyl)3 (0.01 g,0.031 mmol) were dissolved in N,N-dimethylformamide (DMF) (10 mL)and triethylamine (3 mL). The reaction mixture was left for 24 h under anitrogen atmosphere at 90 °C. After completion of the reaction, thereaction mixture was cooled to room temperature and poured intowater (50 mL), followed by extraction with diethyl ether (50 two times. Subsequently, the organic layer was separated, washed withsaturated brine solution, dried over Na2SO4, and concentrated undervacuum. The resulting residue was purified by column chromatographyon silica gel with hexane/chloroform (3:7, v/v) as the eluent.

Reference： [1]Reddy, T. Sheshashena; Lee, Seungae; Choi, Myung–Seok [Dyes and Pigments, 2019, vol. 168, p. 49 - 58]

17
[ 1351272-41-7 ]
5–bromo–2–butyl–1H–benzo[de]isoquinoline–1,3(2H)–dione [ No CAS ]
(E)–2–butyl–5–(4–(1,2,2–triphenylvinyl)styryl)–1H–benzo[de]isoquinoline–1,3(2H)–dione [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
57.2%	With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 90℃; Inert atmosphere;	Synthesis of NTPEs 3 and 4: General procedure: Compound 7 or 8 (0.2 g, 0.60 mmol),(2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene (0.226 g, 0.63 mmol),Pd(OAc)2 (0.0167 g, 0.00746 mmol), and P(o-tolyl)3 (0.01 g,0.031 mmol) were dissolved in N,N-dimethylformamide (DMF) (10 mL)and triethylamine (3 mL). The reaction mixture was left for 24 h under anitrogen atmosphere at 90 °C. After completion of the reaction, thereaction mixture was cooled to room temperature and poured intowater (50 mL), followed by extraction with diethyl ether (50 two times. Subsequently, the organic layer was separated, washed withsaturated brine solution, dried over Na2SO4, and concentrated undervacuum. The resulting residue was purified by column chromatographyon silica gel with hexane/chloroform (3:7, v/v) as the eluent. (E)-2-Butyl-5-(4-(1,2,2-triphenylvinyl)styryl)-1H-benzo[de]isoquinoline-1,3(2H)-dione, 3: NTPE 3 was obtained in 57.2% yield(0.21 g).1H NMR (CDCl3, 600 MHz) δ 8.802 (1H, d, J=1.651 Hz, aromatic), 8.518 (1H, dd, J1-2=0.825 Hz, J1-3=7.153 Hz, aromatic),8.148 (1H, d, J=7.428 Hz, aromatic), 8.112 (1H, d,J=1.651 Hz, aromatic), 7.719 (1H, t, J=7.978 Hz, aromatic),7.334-7.298 (3H, m, aromatic), 7.215 (1H, d, J=16.231 Hz, =CH,ethylene), 7.147-7.029 (17H, m, aromatic), 4.196 (2H, t, J=7.428 Hz,-NCH2), 1.752-1.702 (2H, m, -CH2), 1.491-1.429 (2H, m, -CH2),0.987 (3H, t, J=7.428 Hz, -CH3).13C NMR (CDCl3, 150 MHz) δ164.26, 164.18, 144.13, 143.64, 143.62, 143.55, 141.44, 140.41,136.45, 134.52, 133.63, 132.15, 131.88, 131.40, 131.36, 131.34,131.30, 131.03, 130.53, 128.81, 127.82, 127.75, 127.65, 127.41,127.33, 126.62, 126.57, 126.51, 126.43, 126.17, 123.08, 122.75,40.29, 30.24, 20.39, 13.86. HRMS (ESI-TOF): m/Z calculated forC44H36NO2 610.2740 [M+H]+, measured 610.2738 [M+H]+.

Reference： [1]Reddy, T. Sheshashena; Lee, Seungae; Choi, Myung–Seok [Dyes and Pigments, 2019, vol. 168, p. 49 - 58]

18
[ 19063-55-9 ]
[ 1351272-41-7 ]
(E)-6-(4-(1,2,2-triphenylvinyl)styryl)-2H-chromen-2-one [ No CAS ]

Reference： [1]New Journal of Chemistry,2020,vol. 44,p. 4992 - 5000

19
[ 19063-56-0 ]
[ 1351272-41-7 ]
(E)-7-(4-(1,2,2-triphenylvinyl)styryl)-2H-chromen-2-one [ No CAS ]

Reference： [1]New Journal of Chemistry,2020,vol. 44,p. 4992 - 5000

20
[ 38169-99-2 ]
[ 1351272-41-7 ]
(E)-5-(4-(1,2,2-triphenylvinyl)styryl)-2H-chromen-2-one [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
69%	With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 90℃; Inert atmosphere;

Reference： [1]Reddy, T. Sheshashena; Moon, Hyungkyu; Choi, Myung-Seok [New Journal of Chemistry, 2020, vol. 44, # 13, p. 4992 - 5000]

21
[ 1351272-41-7 ]
[ 60-24-2 ]
2-((4-(1,2,2-triphenylvinyl)phenethyl)thio)ethanol [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	With 2,2'-azobis(isobutyronitrile) In toluene at 70℃; for 24h; Inert atmosphere; Sealed tube;	2.3. Synthesis of 2-((4-(1,2,2-triphenylvinyl)phenethyl)thio)ethanol (TPEOH) The TPE-OH was prepared by reacting TPE and mercapto ethanol inthe presence of AIBN as initiator as shown in Scheme 2. To a round bottomflask added TPE (2.255 g, 6.3 mmol), mercapto ethanol (3.938 g,50.4 mmol), and AIBN (517.3 mg, 3.15 mmol) and toluene (160 mL)and dissolved under nitrogen gas. The reaction flask sealed using rubberstopper after purging (30min) with nitrogen gas. Then reacted for 24 hat 70 °C. After cooling to room temperature, excess mercapto ethanoland toluene were removed by vacuum distillation. The product TPEOHwas obtained after placing overnight in a vacuum oven at 40 °C(yield 70% approximately). The 1H NMR of TPE-OH is given insupporting information (Fig. S5).

Reference： [1]Khan, Salah Ud-Din; Mahmood, Muhammad Farhan; Nabeel, Faran; Rasheed, Tahir [Journal of Molecular Liquids, 2020, vol. 308]

22
[ 100-42-5 ]
[ 65-85-0 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: methanesulfonic acid; phosphorus pentoxide / 6 h / 0 - 20 °C 2: zinc; titanium tetrachloride / tetrahydrofuran / 6 h / 0 - 60 °C

Reference： [1]Current Patent Assignee: SUZHOU BAILING WEICHAO FINE MAT - CN111533637, 2020, A

23
[ 119-61-9 ]
[ 3139-85-3 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
86%	With titanium tetrachloride; zinc In tetrahydrofuran at 0 - 60℃; for 6h;	1.2-2.2 Step 2: Preparation of [1-(4-vinylphenyl)-1,2,2-triphenyl]ethylene Under stirring at room temperature, 600g of zinc powder and 8L of tetrahydrofuran were added to the 20L reaction kettle and stirred evenly.Further, the reaction liquid was cooled to 0 degrees, and 550 g of titanium tetrachloride was added dropwise thereto. After the dropping, the reaction solution was stirred and reacted for 2 hours.Furthermore, a solution of 560 g of the previous step intermediate (light yellow solid) and 540 g of benzophenone dissolved in 2 L of tetrahydrofuran was added dropwise to the reaction solution. After the dropping, the reaction solution was heated to 60 degrees and reacted for 6 hours, and the reaction was completed.Further, the reaction solution was cooled to room temperature, and then 5 L of 15% potassium carbonate aqueous solution was added to quench the reaction.Further, the reaction solution was subjected to pressure filtration to filter out the solids, the filtrate was collected, the filtrate was allowed to stand for layering, the organic phase was collected, and the aqueous phase was extracted twice with 3L of dichloromethane.Further, the organic phases are combined, and the solvent is recovered by distillation under normal pressure. The residue was recrystallized from toluene to obtain 832 g of a pale yellow solid powder product with a yield of 86%.Product HPLC purity: 98.7%.

Reference： [1]Current Patent Assignee: SUZHOU BAILING WEICHAO FINE MAT - CN111533637, 2020, A Location in patent: Paragraph 0039; 0048-0057; 0059; 0068-0077

24
[ 7677-24-9 ]
[ 1351272-41-7 ]
[ 22575-25-3 ]
C₆₃H₇₁NO₂ [ No CAS ]
C₆₃H₇₁NO₂ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
88 % de	With tert.-butylnitrite; tetrakis(actonitrile)copper(I) hexafluorophosphate; {3aS-[2(3'aR,8'aS),3aα,8aα]-2,2'-(cyclopropylidene)-bis{3a,8a-dihydro-8H-indeno[1,2-d]-oxazole} In acetonitrile at 25℃; for 48h; Sealed tube; Inert atmosphere; Overall yield = 52 percent; Overall yield = 43.8 mg;

Reference： [1]Chen, Pinhong; Liu, Guosheng; Zhuang, Weiwen [Chinese Journal of Chemistry, 2021, vol. 39, # 1, p. 50 - 54]

25
[ 108-05-4 ]
[ 34699-28-0 ]
[ 1351272-41-7 ]

Yield	Reaction Conditions	Operation in experiment
57%	With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); lithium iodide; zinc at 65℃; for 8h; Inert atmosphere; Sealed tube; Green chemistry;

Reference： [1]Su, Mincong; Huang, Xia; Lei, Chuanhu; Jin, Jian [Organic Letters, 2022, vol. 24, # 1, p. 354 - 358]

26
[ 1351272-41-7 ]
C₁₆H₁₄BrN₃Se [ No CAS ]
C₄₄H₃₅N₃Se [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62%	With tetrabutylammonium bromide; palladium diacetate; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 6h; Inert atmosphere;

Reference： [1]Yuan, Ying-Xue; Jia, Jing-Hui; Song, Yu-Pan; Ye, Feng-Ying; Zheng, Yan-Song; Zang, Shuang-Quan [Journal of the American Chemical Society, 2022, vol. 144, # 12, p. 5389 - 5399]

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P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Purity	Size	Price	VIP Price	USA Stock *0-1 Day	Global Stock *5-7 Days	Quantity
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Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 1351272-41-7 ] {[proInfo.proName]}

Quality Control of [ 1351272-41-7 ]

Related Doc. of [ 1351272-41-7 ]

Product Details of [ 1351272-41-7 ]

Safety of [ 1351272-41-7 ]

Application In Synthesis of [ 1351272-41-7 ]

[ 1351272-41-7 ] Synthesis Path-Downstream 1~26

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry