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[ CAS No. 10025-82-8 ] {[proInfo.proName]}

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Chemical Structure| 10025-82-8
Chemical Structure| 10025-82-8
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Product Details of [ 10025-82-8 ]

CAS No. :10025-82-8 MDL No. :MFCD00011058
Formula : Cl3In Boiling Point : -
Linear Structure Formula :- InChI Key :PSCMQHVBLHHWTO-UHFFFAOYSA-K
M.W : 221.18 Pubchem ID :24812
Synonyms :

Safety of [ 10025-82-8 ]

Signal Word:Danger Class:8
Precautionary Statements:P261-P280-P305+P351+P338-P310 UN#:3260
Hazard Statements:H302-H314 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 10025-82-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 10025-82-8 ]

[ 10025-82-8 ] Synthesis Path-Downstream   1~27

  • 1
  • [ 7732-18-5 ]
  • [ 10025-82-8 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With ammonia 1.017g InCb was dissolved in 10 mL of pure water. 10 mL of NH4OH 1OM was added dropwise to the solution while stirring and a precipitate was formed. Ch and NH4+ ions were remove by successive washing (5 -10 times with 50 mL of water each time) until no smell of ammonia was detectable.0.92 mL HNO3OM) was then added to peptise the precipitate and the suspension stirred overnight at 55+5 0C. A further 0.45 mL of HNO3I mol/L was added and the suspension stirred again overnight at 55+50C. The final pH was measured at 2.284 and the TEM showed 50nm*10 nm crystallites with well defined facets.The crystals were then coated using the following method. A solution A containing 6 mmol of NP-9, 6 mmol of 1-pentanol, 30 mL of cyclohexane, 0.972 mL of NH4OH 6.667 mol/L, was stirred until clear.
With hydrogenchloride In hydrogenchloride; ethanol HCl soln. was added to EtOH soln. of InCl3, reflux at 60 °C for 1h, keeping for 3 d, sol-gel coating onto glass substrate, air-drying an d heat-treatment;
spray pyrolysis technique using aq. InCl3 and glass substrate at 400°C; carrier gas: compressed purified air; detn. by XRD;
In methanol; water spray pyrolysis technique; aq. HCl soln. of InCl3 diluted with MeOH sprayed on preheated substrate at 400°C (spray time 1 s; spray interval 20 s);
With KOH In water High Pressure; mixing of InCl3 soln. with NaOH soln., addn. of EtOH and H2O, heating to180 °C for 24 h; collection of the powder, rinsing in EtOH, annealing at 300 °C inair for 2 h;
With NaBH4; citric acid In water Sonication; colloidal SiO2 spheres with modified surface put into aq. soln. of InCl3and citric acid with sonication; aq. soln. of NaBH4 slowly dropped into mixt.; ppt. washed with water, EtOH, dried in air at 100°C and a nnealed in O2 at 450°C for 3 h; inner SiO2 spheres dissolved in aq. HF; XRD;

  • 2
  • [ 547-91-1 ]
  • [ 10025-82-8 ]
  • In(3+)*C5H3NC(SO3)CHCIC(O)(2-)=[In(C5H3NC(SO3)CHCIC(O))](1+) [ No CAS ]
  • In(3+)*H(1+)*C5H3NC(SO3)CHCIC(O)(2-)=[In(C5H3NHC(SO3)CHCIC(O))](2+) [ No CAS ]
  • 3
  • [ 7440-74-6 ]
  • [ 10025-82-8 ]
  • [ 13465-10-6 ]
YieldReaction ConditionsOperation in experiment
In neat (no solvent) mixt. heating until colour changes to orange;
  • 4
  • [ 10025-82-8 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
With Na3C6H5O7*2H2O In water Electrochem. Process; electrodeposition by three-probe dc method in a soln. containing InCl3 and Na3C6H5O7*2H2O at room temp., annealed in air at different temperatures;
With ammonium hydroxide In water hydrolysis, pptn., drying (100°C, 12 h), calcining in air (850°C, 5 h);
With air; ethanolamine In further solvent(s) a soln. of ethanolamine and InCl3 in methoxyethanol stirred for 30 min at room temp., spin-coated onto a substrate, annealed at 400°C for10 min under air; obtained as a film;
In methanol; water spray pyrolysis deposition of H2O/EtOH (3:1) soln. of InCl3 onto Corning-1737 glass substrate at 450-550°C; postannealed at 550°C for 45 min under 1E4 mbar;
With air; citric acid In neat (no solvent) films electrodeposited at 65°C for 250 s from mixt. of InCl3 and citric acid bath; annealed in air for 1 h at 300° C; XRD;

  • 5
  • [ 10025-82-8 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In not given Electrolysis; in the presence of pyridine;
With hydrogenchloride In water byproducts: In(OH)3; Electrochem. Process; InCl3 (0.9 mmol) dissolved in H2O (30 ml); pH adjusted to 3 with 0.1 N HCl; electrodeposition on Mo coated glass cathode (In anode, 20 min, 1 or2 V); removed from soln. dried in air; XRD; SEM;
With sodium; sodium chloride explosion;
With sodium cyanide; zinc In not given Electrochem. Process; electrolytical deposition of In on Zn from soln. of (in g/l): 32.8 In (as chloride), 90 NaCN, 15 dextrose; anode: carbon or Pt; current density: 1 - 11 A/dm*dm;;
With zinc In ethanol High Pressure; anhydrous InCl3 and Zn powder added to a Teflon-lined stainless steel autoclave; autoclave filled with 90% absolute ethanol and the solution stirred for 30 min; autoclave sealed and maintained at 120°C for 20 h; cooled to room temp. naturally; product filtered, washed several times with distilled water and absolute ethanol; dried at 70°C for 4 h;
In gaseous matrix metal compd. in discharge tube, passing an intense current pulse throught it (produced by discharging a capacitor across the tube, E=0.15-0.20 kJ), ballast gas N2; according to V. G. Mishakov et al., Opt. Spektrosk.32, 1006 (1972); density of metal atoms detd. by Rozhdestvenskii hook method;
In not given Electrolysis; in the presence of formic acid;
In not given Electrolysis; in the presence of hydroxylamine-HCl;
In not given Electrolysis; in the presence of hydroxylamine;
With poly(vinyl pyrrolidone); sodium tetrahydroborate In further solvent(s) InCl3 and poly(vinyl pyrrolidone) dissolved in isopropanol, purged with Ar, a soln. of NaBH4 in tetraethylene glycol added dropwise at room temp., stirred for 10 min; centrifuged, washed (EtOH); obtained as nanoparticles;
With sodium naphthalenide; trioctylphosphine or trioctylamine In tetrahydrofuran byproducts: NaCl; room temp.; centrifugation, TEM, XRD;
With potassium citrate In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With acetamide In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With acetate In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With chloride In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With ethanol In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With iodide In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With oxalate In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With sodium citrate In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With sulphate In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With thiocyanate In water Electrolysis; pH 2-5, current density 2-25 mA/cm**2, 30°C, metal ion concn. 0.2 mol/l; purity of the In is better than 99 %;
With {(Li((CH3)2NC2H4N(CH3)2))2((CH3)3SiCHCH)2} In diethyl ether byproducts: LiCl, ((CH3)3SiCHCH)2; Ar or N2 atm.;;
In water Electrochem. Process; electrodeposition (Bi electrode substrate, pH 1.3, current density 2.4-21.4 A/sqm, 1.2 - 8.3 h);
In hydrogenchloride Electrochem. Process; electrodeposition (Sb electrode subtrate, pH 1.3, current densities between 2 - 20 A/sqm, room temp.); scanning electron microscopy;
In further solvent(s) Electrolysis; electrolysis of 0.1 M InCl3 in 1-butyl-1-ethyl-piperidinium bis(trifluoromethylsulfonyl)imide at 60°C and potential from -100 to -1080 mVvs. AgCl/Ag; XRD; SEM;
In further solvent(s) Electrochem. Process; deposited on Ni from 1-ethyl-3-methylimidazolium chloride-tetrafluoroborate ionic liquid at 120°C;
In further solvent(s) Electrochem. Process; electrodeposited at 25°C at -1.75 V versus Pt from 1-butyl-1-methyl pyrrolidinium bis(trifluoromethylsulfonyl)amide containing InCl3;
With LiCl In water Electrochem. Process; electrodeposited onto Mo/Cu at pH 3;
With HCl; citric acid; sodium citrate In water Electrochem. Process; according to Phys. Chem. Chem. Phys. 13(2011)6662-6669, US Patent 20090283415 (2009); electrodeposited at 24+/-1°C from 30 mM InCl3 + 10 mM citric acid + 35 mM Na citrate (pH 2.2, HCl) at potential -0.98 V (vs. Ag/AgCl) (charge 0.96 C/cm2);
With HCl; citric acid In water Electrochem. Process; according to Phys. Chem. Chem. Phys. 13(2011)6662-6669, US Patent 20090283415 (2009); electrodeposited potentiostatically at 24+/-1°C from 30 mM InCl3 + 10 mM citric acid (pH 2.2, HCl) at potential -0.98 V (vs. Ag/AgCl) (charge 0.96 C/cm2);
With HCl In water Electrochem. Process; according to Phys. Chem. Chem. Phys. 13(2011)6662-6669, US Patent 20090283415 (2009); electrodeposited potentiostatically at 24+/-1°C from 30 mM InCl3 (pH 2.2 adjusted with HCl) at potential of -0.80 V (vs. Ag/AgCl) and charge of 0.96 C/cm2;

Reference: [1]Dennis, L. M.; Geer, W. C. [Chemische Berichte, 1904, vol. 37, p. 962] Dennis, L. M.; Geer, W. C. [Journal of the American Chemical Society, 1904, vol. 26, p. 437] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: In: MVol., 1.1, page 12 - 16]
[2]Datta, Anuja; Panda, Subhendu K.; Gorai, Soma; Ganguli, Dibyendu; Chaudhuri, Subhadra [Materials Research Bulletin, 2008, vol. 43, # 4, p. 983 - 989]
[3]Winkler, C. [Journal fur praktische Chemie (Leipzig 1954), 1867, vol. 102, p. 278] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: In: MVol., 1.1, page 12 - 16]
[4]Ludwick, M. T. [Metal Finishing, 1942, vol. 40, p. 13 - 17] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Zn: SVol., 213, page 702 - 706] Current Patent Assignee: INDIUM CORPORATION - CA425447, 1945, A [C. A., 1945, p. 1618]
[5]Zhang, Yunxia; Li, Guanghai; Zhang, Lide [Inorganic Chemistry Communications, 2004, vol. 7, # 3, p. 344 - 346]
[6]Shukhtin, A. M.; Tkachenko, T. L.; Mishakov, V. G. [Optics and Spectroscopy, 1985, vol. 58, p. 178 - 180][Opt. Spectrosc. (Transl. Of. Opt. Spektrosk.), 1985, vol. 58, p. 298 - 301]
[7]Dennis, L. M.; Geer, W. C. [Chemische Berichte, 1904, vol. 37, p. 962] Dennis, L. M.; Geer, W. C. [Journal of the American Chemical Society, 1904, vol. 26, p. 437] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: In: MVol., 1.1, page 12 - 16]
[8]Dennis, L. M.; Geer, W. C. [Chemische Berichte, 1904, vol. 37, p. 962] Dennis, L. M.; Geer, W. C. [Journal of the American Chemical Society, 1904, vol. 26, p. 437] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: In: MVol., 1.1, page 12 - 16]
[9]Dennis, L. M.; Geer, W. C. [Chemische Berichte, 1904, vol. 37, p. 962] Dennis, L. M.; Geer, W. C. [Journal of the American Chemical Society, 1904, vol. 26, p. 437] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: In: MVol., 1.1, page 12 - 16]
[10]Chou, Nam Hawn; Ke, Xianglin; Schiffer, Peter; Schaak, Raymond E. [Journal of the American Chemical Society, 2008, vol. 130, # 26, p. 8140 - 8141]
[11]Carenco, Sophie; Demange, Matthieu; Shi, Jing; Boissiere, Cedric; Sanchez, Clement; Le Floch, Pascal; Mezailles, Nicolas [Chemical Communications, 2010, vol. 46, # 30, p. 5578 - 5580]
[12]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[13]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[14]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[15]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[16]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[17]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[18]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[19]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[20]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[21]Fouda, A. S.; Madkour, L. H.; Ahmed, A. I. [Bulletin de la Societe Chimique de France, 1987, # 2, p. 270 - 272]
[22]Gardiner, Michael G.; Raston, Colin L. [Organometallics, 1993, vol. 12, # 1, p. 81 - 86]
[23]Canegallo, Stefano; Demeneopoulos, Vassilis; Peraldo Bicelli, Luisa; Serravalle, Giovanni [Journal of Alloys and Compounds, 1995, vol. 228, p. 23 - 30]
[24]Kozlov, Valentin M.; Agrigento, Valeria; Bontempi, Danilo; Canegallo, Stefano; Moraitou, Cleanthi; Toussimi, Aikaterini; Bicelli, Luisa Peraldo; Serravalle, Giovanni [Journal of Alloys and Compounds, 1997, vol. 259, # 1-2, p. 234 - 240]
[25]Traore, Youssouf; Legeai, Sophie; Diliberto, Sébastien; Arrachart, Guilhem; Pellet-Rostaing, Stéphane; Draye, Micheline [Electrochimica Acta, 2011, vol. 58, # 1, p. 532 - 540]
[26]Hsiu, Shu-I; Tai, Chia-Cheng; Sun, I-Wen [Electrochimica Acta, 2006, vol. 51, # 13, p. 2607 - 2613]
[27]Zein El Abedin; Saad; Farag; Borisenko; Liu; Endres [Electrochimica Acta, 2007, vol. 52, # 8 SPEC. ISS., p. 2746 - 2754]
[28]Valderrama; Miranda-Hernández; Sebastian; Ocampo [Electrochimica Acta, 2008, vol. 53, # 10, p. 3714 - 3721]
[29]Lee, Sun Min; Ikeda, Shigeru; Otsuka, Yasunari; Septina, Wilman; Harada, Takashi; Matsumura, Michio [Electrochimica Acta, 2012, vol. 79, p. 189 - 196]
[30]Lee, Sun Min; Ikeda, Shigeru; Otsuka, Yasunari; Septina, Wilman; Harada, Takashi; Matsumura, Michio [Electrochimica Acta, 2012, vol. 79, p. 189 - 196]
[31]Lee, Sun Min; Ikeda, Shigeru; Otsuka, Yasunari; Septina, Wilman; Harada, Takashi; Matsumura, Michio [Electrochimica Acta, 2012, vol. 79, p. 189 - 196]
  • 6
  • [ 17654-68-1 ]
  • [ 10025-82-8 ]
  • [InCl(phthalocyanine(4-Cl)4)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
In melt fusing of InCl3 with C6H3Cl(CN)2 at 210-220°C; alternate treatment with diluted HCl and H2O; extn. with organic solvents in Soxhlet app., heating at 250-350°C in vac. for 4-6 h; fractional vac. sublimation at 430-520°C;
  • 7
  • [ 7783-06-4 ]
  • [ 10025-82-8 ]
  • [ 12030-24-9 ]
YieldReaction ConditionsOperation in experiment
deposited by spray-ILGAR process: 25 mM InCl3 sprayed; sulfurized in Ar:H2S (95:5) at 200°C; SEM;
  • 8
  • [ 10025-82-8 ]
  • [ 91-15-6 ]
  • [ 19631-19-7 ]
YieldReaction ConditionsOperation in experiment
62% In quinoline under exclusion of water; mixt. of phthalonitrile, anhyd. InCl3 and distd. deoxygenated quinoline refluxed for 1 h; cooled to ca. 273 K; filtered; washed with toluene and MeOH; dried at 383 K; elem. anal.;
In quinoline
In quinoline; benzene heating (Ar), benzene distn., addn. of InCl3 to the cold (0°C.) reaction mixt., stirring, refluxing (210°C, 4h, Ar), cooling, according to: Owens, J. E.; Kenney, M. E. Inorg. Chem. 1962, 1, 331; filtn. (fine fritted glass), rinsing (benzene and acetonitrile), drying (vac.), sublimating (.apprx. 1E-5 Torr), elem. anal.;
  • 9
  • [ 10025-82-8 ]
  • [ 62-55-5 ]
  • [ 12030-24-9 ]
YieldReaction ConditionsOperation in experiment
In water film grown by chemichal bath deposition at 345 K;
With hydrochloric acid; acetic acid deposited from acidic soln. (HCl+HAc) off thioacetamide and indium(III) chloride at 70°C for 25-35 min; XRD;
With HCl In water thermal soln. method;
  • 10
  • sodium sulfide [ No CAS ]
  • [ 10025-82-8 ]
  • [ 12030-24-9 ]
YieldReaction ConditionsOperation in experiment
95% In ammonia byproducts: NaCl; NH3 (liquid); from InCl3 and Na2S in molar ratio 2:3 by stirring at room temp. in liq.NH3 for 36 h; trituration with water and CS2 and annealing at 250°C for 48 h; powder XRD, SEM/EDXA, Raman-, IR-spectroscopies;
In water glass substarate immersed into InCl3 soln (pH=5.5) for 30 s, washed (H2O), immersed into Na2S soln. (pH=12) for 30 s, washed (H2O), repeated for75 times;
  • 12
  • [ 10025-82-8 ]
  • [ 25596-24-1 ]
  • μ-chloro-bis{tris(dimethylsulfoxonium methylide)indium} pentachloride [ No CAS ]
  • 13
  • [ 120-70-7 ]
  • [ 10025-82-8 ]
  • [ 151995-09-4 ]
YieldReaction ConditionsOperation in experiment
90% With N(C2H5)3 In methanol addn. of a soln. containing ligand and NEt3 in methanol to a soln. of InCl3 in methanol, refluxing for 2 h; evapn. to dryness, washing with water, followed by methanol, drying at 60°C under vacuum, elem. anal.;
  • 14
  • [ 782-76-3 ]
  • [ 10025-82-8 ]
  • [ 91709-40-9 ]
YieldReaction ConditionsOperation in experiment
78% With triethylamine In tetrahydrofuran byproducts: triethylamine hydrochloride; mixt. of educts and dry Et3N (1:1:1 molar ratio) stirred in dry THF for25 h at room temp.; filtered, evapd. in vac., recrystd. from THF/n-hexane; elem. anal.;
  • 15
  • [ 782-76-3 ]
  • [ 10025-82-8 ]
  • [ 91709-41-0 ]
YieldReaction ConditionsOperation in experiment
80% With triethylamine In tetrahydrofuran byproducts: triethylamine hydrochloride; mixt. of educts and dry Et3N (1:2:2 molar ratio) stirred in dry THF for35 h at room temp.; filtered, evapd. in vac., recrystd. from THF/n-hexane; elem. anal.;
  • 17
  • [ 961-38-6 ]
  • [ 10025-82-8 ]
  • In[N(H)(2,4,6-tri-tert-butylphenyl)]3 [ No CAS ]
  • 18
  • [ 32703-80-3 ]
  • [ 10025-82-8 ]
  • 2,(3)-tetra-tert-butyl-phthalocyaninato indium(III) chloride [ No CAS ]
  • 19
  • [ 32703-80-3 ]
  • [ 10025-82-8 ]
  • [ 84234-66-2 ]
  • 20
  • [ 1835-65-0 ]
  • [ 10025-82-8 ]
  • [ 618852-52-1 ]
  • 21
  • lithium cyclopentadienide [ No CAS ]
  • [ 10025-82-8 ]
  • [ 18115-70-3 ]
  • 2C5H5(1-)*In(3+)*CH3COCHCOCH3(1-)=(C5H5)2InCH3COCHCOCH3 [ No CAS ]
  • 22
  • [ 176763-62-5 ]
  • [ 10025-82-8 ]
  • [InCl3(Co((R,R)-C6H10(NCHC6H2O(tert-butyl)2)2))] [ No CAS ]
  • 23
  • [ 176763-62-5 ]
  • [ 10025-82-8 ]
  • [InCl3(Co((R,R)-C6H10(NCHC6H2O(tert-butyl)2)2))2] [ No CAS ]
  • 24
  • [ 53103-03-0 ]
  • [ 10025-82-8 ]
  • [ 256217-65-9 ]
YieldReaction ConditionsOperation in experiment
90% In toluene (N2); stirring (80°C, 2 h); crystn. (CH2Cl2/pentane); elem. anal.;
  • 25
  • [ 10025-82-8 ]
  • [ 70484-01-4 ]
  • [InCl(phthalocyanine(4-Br)4)] [ No CAS ]
  • 26
  • [ 30757-50-7 ]
  • [ 10025-82-8 ]
  • [ 889887-03-0 ]
  • 27
  • [ 76241-79-7 ]
  • [ 10025-82-8 ]
  • [InCl(phthalocyanine(3-Cl)4)] [ No CAS ]
YieldReaction ConditionsOperation in experiment
In melt fusing of InCl3 with C6H3Cl(CN)2 at 210-220°C; alternate treatment with diluted HCl and water; extn. with dried organicsolvents in Soxhlet app., heating at 250-350°C in vac. for 4-6 h ; vac. sublimation at 430-520°C;
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