[ CAS No. 867-36-7 ] {[proInfo.proName]}

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Quality Control of [ 867-36-7 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

Alternatived Products of [ 867-36-7 ]

Product Details of [ 867-36-7 ]

CAS No. :	867-36-7	MDL No. :	MFCD00053213
Formula :	C₆H₁₄Cl₂Sn	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	CTRHCENQKGMZLE-UHFFFAOYSA-L
M.W :	275.79	Pubchem ID :	93562
Synonyms :

Safety of [ 867-36-7 ]

Signal Word:	Danger	Class:	6.1
Precautionary Statements:	P280-P264-P270-P330-P301+P310-P501	UN#:	3146
Hazard Statements:	H300-H315-H319	Packing Group:	Ⅱ
GHS Pictogram:

Application In Synthesis of [ 867-36-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 867-36-7 ]

[ 867-36-7 ] Synthesis Path-Downstream 1~50

1
[ 2176-98-9 ]
[ 23267-68-7 ]
[ 867-36-7 ]

Yield	Reaction Conditions	Operation in experiment
90%	With thionyl chloride from 0 deg C up to room temp.; reflux, 30 min;

Reference： [1]Narula, Suraj P.; Sharma, R. K.; Lata, Sneh; Walia, Rita [Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983, vol. 22, # 3, p. 246 - 247]

Yield	Reaction Conditions	Operation in experiment
	With potassium hydroxide Behandeln der erhaltenen flockigen Niederschlaege mit Salzsaeure;

Yield	Reaction Conditions	Operation in experiment
	at 190 - 200℃;

4
[ 867-36-7 ]
[ 67936-77-0 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide; sodium azide In water; acetone	5 EXAMPLE 5 EXAMPLE 5 27.6 g (0.10 mol) of di-propyl-tin-dichloride are dissolved in 100 ml of ether and let flow into a solution of 7.15 g (0.11 mol) of NaN3 in 60 ml of water and 40 ml of acetone. After stirring for 4 hours at room temperature, 4 g of NaOH (0.1 mol) are added. The ether phase is separated in a separatory funnel and freed of ether after drying over Na2 SO4. A solid white residue of bis-(azido-di-propyl-tin)-oxide remains in 24.2 g yield: that is 91.8 % of theory. IR spectrum clearly shows the azide bands at 2080-2095 cm-1. The sample melts at 87° C but first clearly flows together only at 160° C. Analysis: C found = 28.53 (27.30%); H = 5.69 (5.69); N = 13.78 (15.93%); Sn = 45.65 (45.01%).

Reference： [1]Current Patent Assignee: LANXESS AG - US4112084, 1978, A

5
[ 688-73-3 ]
[ 867-36-7 ]
[ 16561-43-6 ]

Yield	Reaction Conditions	Operation in experiment
	In not given reaction in a mol-ratio of 1:1;;

Reference： [1]Sawyer et al. [Journal of Organometallic Chemistry, 1968, vol. 11, p. 192] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.5.4.7, page 62 - 63]

6
[ 688-73-3 ]
[ 867-36-7 ]
[ 2406-60-2 ]

Yield	Reaction Conditions	Operation in experiment
	In not given reaction in a mol-ratio of 2:1;;
	In not given determination with NMR-spectroscopy;;
	In not given determination with NMR-spectroscopy;;

Reference： [1]Sawyer et al. [Journal of Organometallic Chemistry, 1968, vol. 11, p. 192] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.5.4.7, page 62 - 63]
[2]Sawyer et al. [Journal of Organometallic Chemistry, 1968, vol. 11, p. 192]
[3][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.3, page 102 - 103]

7
[ 867-36-7 ]
[ 7304-31-6 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium fluoride or potassium fluoride In acetone Pr2SnCl2 was heated in acetone with NaF or KF;

Reference： [1]Crowe, Alan J.; Smith, Peter J. [Journal of Organometallic Chemistry, 1982, vol. 224, # 3, p. 223 - 236]

8
[ 867-36-7 ]
[ 1664-67-1 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium thiocyanate or potassium thiocyanate In acetone Pr2SnCl2 was heated in acetone with NaSCN or KSCN;

Reference： [1]Crowe, Alan J.; Smith, Peter J. [Journal of Organometallic Chemistry, 1982, vol. 224, # 3, p. 223 - 236]

9
[ 867-36-7 ]
[ 1655-80-7 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium bromide or potassium bromide In acetone Pr2SnCl2 was heated in acetone with NaBr or KBr;

Reference： [1]Crowe, Alan J.; Smith, Peter J. [Journal of Organometallic Chemistry, 1982, vol. 224, # 3, p. 223 - 236]

10
[ 867-36-7 ]
[ 3091-33-6 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium iodide or potassium iodide In acetone Pr2SnCl2 was heated in acetone with NaI or KI;

Reference： [1]Crowe, Alan J.; Smith, Peter J. [Journal of Organometallic Chemistry, 1982, vol. 224, # 3, p. 223 - 236]

11
[ 867-36-7 ]
[ 2129-89-7 ]
(C₃H₇)2SnCl₂*MPPO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform 25°C; not isolated, monitored by (31)P NMR;

Reference： [1]Yoder, Claude H.; Coley, Suzanne M.; Kneizys, Steven P.; Spencer, J. N. [Journal of Organometallic Chemistry, 1989, vol. 362, p. 59 - 62]

12
[ 85324-78-3 ]
[ 867-36-7 ]
(C₃H₇)2SnCl₂*EDPO [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In chloroform 25°C; not isolated, monitored by (31)P NMR;

Reference： [1]Yoder, Claude H.; Coley, Suzanne M.; Kneizys, Steven P.; Spencer, J. N. [Journal of Organometallic Chemistry, 1989, vol. 362, p. 59 - 62]

13
[ 2176-98-9 ]
[ 867-36-7 ]

Yield	Reaction Conditions	Operation in experiment
45%	With tetrachloromethane Irradiation (UV/VIS); 46 h;
45%	With CCl₄ Irradiation (UV/VIS); 46 h;

14
[ 2176-98-9 ]
[ 867-36-7 ]
[ 2279-76-7 ]

Yield	Reaction Conditions	Operation in experiment
1: 34.6% 2: 40.6%	With chloroform Irradiation (UV/VIS); 26 h;
1: 34.6% 2: 40.6%	With CHCl₃ Irradiation (UV/VIS); 26 h;
	With hydrogenchloride In benzene

With HCl In benzene

Reference： [1]Razuvaev, G. A.; Vyazankin, N. S.; Gladyshev, E. N.; Borodavko, I. A. [Zhurnal Obshchei Khimii, 1962, vol. 32, p. 2154 - 2160]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.3.4.5, page 87 - 88]
[3]Abraham, M. H.; Hill, J. A. [Chemistry and industry][Chemistry and Industry (London, United Kingdom), 1965, p. 561 - 562] Abraham, M. H.; Hill, J. A. [Journal of Organometallic Chemistry, 1967, vol. 7, p. 11 - 21] Gielen, M.; Nasielski, J. [Journal of Organometallic Chemistry, 1963, vol. 1, p. 173 - 190] Gielen, M.; Nasielski, J. [Recueil des Travaux Chimiques des Pays-Bas, 1963, vol. 82, p. 228 - 231]
[4][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.3.4.5, page 87 - 88]

15
[ 7719-09-7 ]
[ 2176-98-9 ]
[ 23267-68-7 ]
[ 867-36-7 ]

Yield	Reaction Conditions	Operation in experiment
90%	In not given dropwise addn. of thionyl chloride to tetraalkyltin(IV) compd. under dry N2 atmosphere under ice cooling, warming to room temp., refluxing for 30 min; distn. (removal of excess of SOCl2), cooling resulting liquids, sepn., elem. anal.;

16
[ 60080-20-8 ]
[ 2234-82-4 ]
[ 867-36-7 ]

Yield	Reaction Conditions	Operation in experiment
74.5%	In diethyl ether; benzene byproducts: (CH3COCHCOCH3)MgCl; Grignard reagent:Gmelin educt in 2:1 molar ratio, reflux for 2-3 h; by-product filtered off, solvent distd. off, product vac. distd.;

Reference： [1]Chandrasekaran, R. K.; Venkataraman, S.; Koola, Johnson D. [Journal of Organometallic Chemistry, 1981, vol. 215, # 3, p. C43 - C44]

17
[ 931-19-1 ]
[ 867-36-7 ]
(C₃H₇)2SnCl₂(C₅H₄(CH₃)NO)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
82%	In chloroform Sn-compd. added to soln. of ligand, refluxed on a water-bath for about 2h; solvent removed under reduced pressure, crystd. from CHCl3; elem. anal.;

Reference： [1]Sandhu, G. K.; Dass, S.; Boparoy, N. S. [Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990, vol. 20, p. 393 - 408]

18
[ 998-40-3 ]
[ 867-36-7 ]
(C₃H₇)2SnCl₂*tributylphosphine [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In benzene under Ar at 25°C; (31)P NMR anal., calorimetric detn.;

Reference： [1]Yoder, Claude H.; Otter, Julie C.; Grushow, Alex; Ganunis, Travis F.; Enders, Belinda G.; et al. [Journal of Organometallic Chemistry, 1990, vol. 385, # 1, p. 33 - 37]

19
[ 135578-51-7 ]
[ 867-36-7 ]
(n-Pr)2SnCl(O₂CC₄H₃O) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
89%	In benzene addn. of chloride soln. to soln. of Sn-complex (molar ratio 1:1), refluxing (3 h); vol. redn., recrystn. (hexane); elem. anal.;

Reference： [1]Vatsa, Charu; Jain, Vimal K.; Kesavadas, T.; Tieking, Edward R. T. [Journal of Organometallic Chemistry, 1991, vol. 410, # 2, p. 135 - 142]

20
[ 16853-85-3 ]
[ 867-36-7 ]
[ 2406-60-2 ]

Yield	Reaction Conditions	Operation in experiment
72%	In diethyl ether reaction in N2-atmosphere on boiling for 2.5 h on reflux;;
72%	In diethyl ether reaction in N2-atmosphere on boiling for 2.5 h on reflux;;

Reference： [1]Noltes, J. G.; Kerk, G. J. M. van der [Functionally Substituted Organotin Compounds, Tin Research Institute, Greenford 1958, S. 1 - 128] Kerk, G. J. M. van der; Noltes, J. G.; Luijten, J. G. A. [Journal of Applied Chemistry, 1957, vol. 7, p. 366 - 369]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.3, page 102 - 103]

21
EDTA silver salt [ No CAS ]
[ 867-36-7 ]
[ 144889-83-8 ]
silver(I) chloride [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	In ethanol addn. of Sn-compd. soln. to EDTA salt soln. (molar ratio 2:1), refluxing (water bath, 4 h); filtration, washing (ethanol), filtrate distn., drying (vac.), recrystn. (ethanol); elem. anal.;

Reference： [1]Sandhu, G. K.; Hundal, R. [Journal of Organometallic Chemistry, 1992, vol. 436, # 3, p. 287 - 298]

22
[ 867-36-7 ]
[ 931-50-0 ]
[ 5764-56-7 ]

Yield	Reaction Conditions	Operation in experiment
76%	In diethyl ether boiling;;
76%	In diethyl ether boiling;;

Reference： [1][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.3, page 36 - 40]
[2]Current Patent Assignee: M & T INTERNATIONAL B.V. - FR2179552, 1973, B1 [C. A., 1974, vol. 80, p. 108671]

23
[ 867-36-7 ]
[ 41246-05-3 ]
[ 5054-43-3 ]

Yield	Reaction Conditions	Operation in experiment
66%	In diethyl ether boiling, 2h;;

Reference： [1]Ibekwe,S.D.; Newlands,M.J. [Journal of the Chemical Society, 1965, p. 4608 - 4610] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.3, page 36 - 40]

24
[ 867-36-7 ]
[ 2406-60-2 ]
[ 16561-43-6 ]

Yield	Reaction Conditions	Operation in experiment
	In not given reaction at room temperature;;
	In not given reaction at room temperature;;

Reference： [1]Sawyer et al. [Journal of Organometallic Chemistry, 1968, vol. 11, p. 192] Baukov, Yu. I.; Belavin, I. Yu.; Lutsenko, I. F. [Zhurnal Obshchei Khimii, 1965, vol. 35, p. 1096 - 1098][Zhurnal Obshchei Khimii, 1965, vol. 35, p. 1092 - 1094]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.3, page 102 - 103]

25
2Ag⁽¹⁺⁾*(OOCCH₂)2HNCH₂CH₂NH(CH₂COO)2^(2-)=(OOCCH₂)2HNCH₂CH₂NH(CH₂COO)2Ag₂ [ No CAS ]
[ 867-36-7 ]
[ 144889-79-2 ]
silver(I) chloride [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
87%	In ethanol addn. of Sn-compd. soln. to EDTA salt soln. (molar ratio 1:1), refluxing (water bath, 4 h); filtration, washing (ethanol), filtrate distn., drying (vac.), recrystn. (ethanol); elem. anal.;

Reference： [1]Sandhu, G. K.; Hundal, R. [Journal of Organometallic Chemistry, 1992, vol. 436, # 3, p. 287 - 298]

26
[ 7647-01-0 ]
[ 2406-60-2 ]
[ 867-36-7 ]

Yield	Reaction Conditions	Operation in experiment
	In diethyl ether
	In diethyl ether

Reference： [1]Noltes, J. G.; Kerk, G. J. M. van der [Functionally Substituted Organotin Compounds, Tin Research Institute, Greenford 1958, S. 1 - 128]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.3, page 102 - 103]

27
diacetylbis(4-methoxybenzoylhydrazone) [ No CAS ]
[ 867-36-7 ]
Sn(CH₃OC₆H₄CONNC(CH₃)C(CH₃)NNCOC₆H₄OCH₃)(CH₂CH₂CH₃)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	In methanol; acetone addn. of a soln. of (n-Pr)2SnCl2 in anhyd. acetone to a boiling suspension of the hydrazone in dry CH3OH under N2 atm.; refluxing for several minutes;; filtration; pptn. from filtrate on standing in a vac. desiccator for several days; the ppt. was filtered off, washed with CH3OH and dried undervac.; elem. anal.;;

Reference： [1]Dey, Kamalendu; Ray, Satyabrata; Bhattacharyya, Prabir Kumar; Gangopadhyay, Amitava; Bhasin, Kuldip K.; Verma, Ravindra D. [Journal of the Indian Chemical Society, 1985, vol. 62, # 11, p. 809 - 814]

28
[ 867-36-7 ]
[ 15929-52-9 ]

Yield	Reaction Conditions	Operation in experiment
	With [2,2]bipyridinyl In not given hot methanolic or dry ethereal solns. of Pr2SnCl2 and bipy were mixed in 1:1 molar ratio; the complex was collected by filtration and dried in air; elem. anal.;

Reference： [1]Crowe, Alan J.; Smith, Peter J. [Journal of Organometallic Chemistry, 1982, vol. 224, # 3, p. 223 - 236]

29
[ 867-36-7 ]
[ 21018-71-3 ]
[ 110140-48-2 ]

Yield	Reaction Conditions	Operation in experiment
83%	In hexane addn. of (C5H4N)C5H7N2 in hexane to stirred hexane soln. of dipropyltindichloride; heating under reflux with stirring for 30 min; cooling;; pptn.; washing with hexane and drying under vacuum; recrystallization from C6H6/hexane; elem. anal.;;

Reference： [1]Visalakshi, R.; Jain, V. K.; Kulshreshtha, S. K.; Rao, G. S. [Inorganica Chimica Acta, 1986, vol. 118, p. 119 - 124]

30
[ 867-36-7 ]
[ 93-91-4 ]
di-n-propyltin(IV) benzoylacetonate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide In 1,4-dioxane; water to soln. of dialkyltin dichloride and ligand in dioxane-water NaOH added till precipitation is complete (pH=10.75); separated, recrystd. from benzene/n-hexane;

Reference： [1]Singh, G.; Gupta, V. D. [Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 5, p. 440 - 443]

31
[ 867-36-7 ]
[ 791-28-6 ]
[ 108696-03-3 ]

Yield	Reaction Conditions	Operation in experiment
	In benzene equilibrium react. in soln.; not isolated, detected by NMR;

Reference： [1]Yoder, Claude H.; Mokrynka, Dian; Coley, Suzanne M.; Otter, Julie C.; Haines, Ronald E.; Grushow, Alex; Ansel, Lori J.; Hovick, James W.; Mikus, Joseph; Shermak, Michele A.; Spencer [Organometallics, 1987, vol. 6, # 8, p. 1679 - 1684]

32
[ 867-36-7 ]
[ 27258-04-4 ]
[ 110167-93-6 ]

Yield	Reaction Conditions	Operation in experiment
80%	In hexane addn. of (C3H3N2)2CH2 in hexane to stirred hexane soln. of dipropyltin dichloride; heating under reflux with stirring for 30 min; evapn. under vacuum; standing of soln. at 0°C for 18 - 24 h;; pptn.; drying under vacuum; recrystallization from hexane; elem. anal.;;

Reference： [1]Visalakshi, R.; Jain, V. K.; Kulshreshtha, S. K.; Rao, G. S. [Inorganica Chimica Acta, 1986, vol. 118, p. 119 - 124]

33
[ 867-36-7 ]
di-n-propyltin dichloride pyridine 1:2 complex [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With pyridine In not given hot methanolic or dry ethereal solns. of Pr2SnCl2 and pyridine were mixed in 1:2 molar ratio; the complex was collected by filtration and dried in air; elem. anal.;

Reference： [1]Crowe, Alan J.; Smith, Peter J. [Journal of Organometallic Chemistry, 1982, vol. 224, # 3, p. 223 - 236]

34
[ 1215-43-6 ]
[ 867-36-7 ]
di-n-propyltin(IV) monothiodibenzoylmethanate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With sodium hydroxide In 1,4-dioxane; water to soln. of dialkyltin dichloride and ligand in dioxane-water NaOH added till precipitation is complete (pH=10.55); separated, recrystd. from benzene/n-hexane;

Reference： [1]Singh, G.; Gupta, V. D. [Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 5, p. 440 - 443]

35
[ 867-36-7 ]
[ 534-17-8 ]
4C₃H₇^(1-)*2Sn⁽⁴⁺⁾*O^(2-)*CO₃^(2-)*H₂O=((C₃H₇)2Sn)2OCO₃*H₂O [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With water In methanol byproducts: cesium chloride; Sn compd. in MeOH added dropwise to stirred MeOH soln. of equimolar amt. of Cs2CO3 at room temp.; ppt. filtered off, vigorously stirred in water for 10-15 min, filtered off, dried in air at room temp.; elem. anal.;

Reference： [1]Smith, Peter J.; Hill, Robin; Nicolaides, Anna; Donaldson, John D. [Journal of Organometallic Chemistry, 1983, vol. 252, # 2, p. 149 - 152]

36
[ 867-36-7 ]
[ 22318-01-0 ]
dipropylbis(diethylthiocarbamato)tin(IV) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
90%	In acetone byproducts: diethylammonium chloride; under N2, stoich. amt. of (n-Pr)2SnCl2 was added dropwise with stirringinto acetone soln. of thiocarbamate salt, stirred for ca. 6 h; filtered, volatiles removed under reduced pressure, dried at ca. 30°C (0.1 mmHg) for ca. 6 h; elem. anal.;

Reference： [1]Gupta, Virendra Kumar; Kanjolia, Ravindra Kumar; Gupta, Vishnu Deo [Bulletin of the Chemical Society of Japan, 1982, vol. 55, # 11, p. 3630 - 3632]

37
[ 78129-68-7 ]
[ 867-36-7 ]
[ 2406-60-2 ]
[ 203740-77-6 ]
2,4,6,9-tetra-tert-butyl-8-dipropylstanna-1,3,5,7-tetraphosphapentacyclo[4.3.0.0(2,5).0(3,9).0(4,7)]nonane [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
85%	In toluene; pentane Ar atmosphere, addn. of diorganotin hydride to n-pentane/toluene soln. of diorganotin dichloride at 0°C, stirring (15 min), addn. of phosphaalkyne, 20°C (14 d); removement of solvent (vacuum), dissolution (pentane), crystn. of (C3H7)2SnH2 (-20°C);

Reference： [1]Schmitz, Marion; Goeller, Rudolf; Bergstraesser, Uwe; Leininger, Stefan; Regitz, Manfred [European Journal of Inorganic Chemistry, 1998, # 2, p. 227 - 235]

38
[ 867-36-7 ]
[ 35329-20-5 ]
[ 163979-99-5 ]

Yield	Reaction Conditions	Operation in experiment
	In benzene byproducts: NH4Cl; N2 atmosphere; vigorous stirring (room temp., 4 h, pptn.); filtration of byproduct, cocn. (vac.); elem. anal.;

Reference： [1]Mokal, Vijaya B.; Jain, Vimal K. [Bulletin of the Chemical Society of Japan, 1995, vol. 68, # 4, p. 1149 - 1154]

39
[ 867-36-7 ]
[ 35329-22-7 ]
[ 163980-03-8 ]

Yield	Reaction Conditions	Operation in experiment
	In benzene byproducts: NH4Cl; N2 atmosphere; vigorous stirring (room temp., 4 h, pptn.); filtration of byproduct, cocn. (vac.); elem. anal.;

Reference： [1]Mokal, Vijaya B.; Jain, Vimal K. [Bulletin of the Chemical Society of Japan, 1995, vol. 68, # 4, p. 1149 - 1154]

40
[ 1941-19-1 ]
[ 867-36-7 ]
[ 690268-78-1 ]

Yield	Reaction Conditions	Operation in experiment
88%	In neat (no solvent) under inert gas (N2 or Ar) atm.; equimolar amt. of tetraorganylphosphonium chloride and diorganyltin dichloride were heated at 180°C for 120 min until homogeneous liq. was obtained; recrystd. (EtOH); elem. anal.;

Reference： [1]Weber, Dirk; Hausner, Sven H.; Eisengräber-Pabst, Axel; Yun, Sanghee; Krause-Bauer, Jeanette A.; Zimmer, Hans [Inorganica Chimica Acta, 2004, vol. 357, # 1, p. 125 - 134]

41
tetra(n-butyl)phosphonium chloride [ No CAS ]
[ 867-36-7 ]
[ 690268-84-9 ]

Yield	Reaction Conditions	Operation in experiment
96%	In neat (no solvent) under inert gas (N2 or Ar) atm.; equimolar amt. of tetraorganylphosphonium chloride and diorganyltin dichloride were heated at 100°C for 120 min until homogeneous liq. was obtained; recrystd. (Et2O); elem. anal.;

Reference： [1]Weber, Dirk; Hausner, Sven H.; Eisengräber-Pabst, Axel; Yun, Sanghee; Krause-Bauer, Jeanette A.; Zimmer, Hans [Inorganica Chimica Acta, 2004, vol. 357, # 1, p. 125 - 134]

42
ammonium O,O-dimethyl phosphorothioate [ No CAS ]
[ 867-36-7 ]
[ 163979-95-1 ]

Yield	Reaction Conditions	Operation in experiment
	In benzene byproducts: NH4Cl; N2 atmosphere; vigorous stirring (room temp., 4 h, pptn.); filtration of byproduct, cocn. (vac.); elem. anal.;

Reference： [1]Mokal, Vijaya B.; Jain, Vimal K. [Bulletin of the Chemical Society of Japan, 1995, vol. 68, # 4, p. 1149 - 1154]

43
[ 867-36-7 ]
[ 2001-45-8 ]
[ 690268-98-5 ]

Yield	Reaction Conditions	Operation in experiment
90%	In neat (no solvent) under inert gas (N2 or Ar) atm.; equimolar amt. of tetraorganylphosphonium chloride and diorganyltin dichloride were heated at 200°C for 240 min until homogeneous liq. was obtained; recrystd. (EtOH); elem. anal.;

Reference： [1]Weber, Dirk; Hausner, Sven H.; Eisengräber-Pabst, Axel; Yun, Sanghee; Krause-Bauer, Jeanette A.; Zimmer, Hans [Inorganica Chimica Acta, 2004, vol. 357, # 1, p. 125 - 134]

44
[ 7028-03-7 ]
[ 867-36-7 ]
[ 1263196-65-1 ]

Yield	Reaction Conditions	Operation in experiment
89%	In methanol byproducts: NaCl; MeOH soln. of ligand added with stirring to MeOH soln. of Sn compd. (2:1molar ratio), mixt. stirred for 2 h; ppt. filtered off, dissolved (CHCl3), layered (petroleum ether), crystd.in 2 d, septd., elem. anal.;

Reference： [1]Singh, Suryabhan; Bhattacharya, Subrato; Noeth, Heinrich [European Journal of Inorganic Chemistry, 2010, # 36, p. 5691 - 5699]

45
[ 867-36-7 ]
(C₃H₇)2Sn(SC₂H₅)2 [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: diethyl ether
	Multi-step reaction with 2 steps 1: diethyl ether

Reference： [1][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.3, page 36 - 40]
[2][Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.3, page 36 - 40]

46
[ 867-36-7 ]
[ 20128-72-7 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: diethyl ether 2: chloroform

Reference： [1]Current Patent Assignee: M & T INTERNATIONAL B.V. - FR2179552, 1973, B1 [C. A., 1974, vol. 80, p. 108671] [Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.3, page 36 - 40]

47
[ 867-36-7 ]
[ 20128-74-9 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: diethyl ether 2: chloroform

48
[ 867-36-7 ]
[ 157261-62-6 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: benzene 2: NaOH / water; acetone

Reference： [1]Mokal, V. B.; Jain, Vimal K.; Tiekink, Edward R. T. [Journal of Organometallic Chemistry, 1994, vol. 471, # 1-2, p. 53 - 62]

49
[ 1358915-35-1 ]
[ 867-36-7 ]
[ 1358915-29-3 ]

Yield	Reaction Conditions	Operation in experiment
89%	In methanol soln. of org. ligand added to soln. of Pr2SnCl2 (0.5 equiv.) (stirring, room temp.); stirred (4 h); evapd.; solid extd. with benzene; filtered; crystd. (room temp., few d);elem. anal.;

Reference： [1]Singh, Neetu; Bhattacharya, Subrato [Journal of Organometallic Chemistry, 2012, vol. 700, p. 69 - 77]

50
[ 69945-42-2 ]
[ 867-36-7 ]
C₃₉H₅₁N₃O₆S₆Sn₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
85%	Stage #1: pyridine-2,6-bis(monothiocarboxylic acid) With triethylamine In methanol for 0.0833333h; Stage #2: di(n-propyl)tin dichloride In methanol for 2h;	General procedure: To a solution of pyridine-2,6-bis-thiocarboxylic acid (0.200 g, 1.0 mmol) in methanol added triethylamine (0.202 g, 2.0 mmol) with stirring. After five minutes a solution of Me2SnCl2 (0.219 g, 1.0 mmol) in methanol was added and the reaction mixture was stirred for 2 h then precipitate was filtered and dried under reduced pressure. The yellow product was dissolved in toluene and kept for crystallization. After two days yellow rod shape crystals were obtained. Same procedure used as in 1, however, instead of Me2SnCl2, n-Pr2SnCl2 (0.276 g, 1.0 mmol) was taken. Yield: 0.341 g (85%). Anal. Cal. for C43H61O7N3S6Sn: C, 40.33, H, 4.80, N, 3.28. Found: C, 39.68, H, 4.59, N, 3.22. IR spectra (KBr, cm- 1): 1623, 1581 ν(CO), 1260 ν(C-Py), 938 ν(CS). 1H NMR (CDCl3, ppm) 0.91, 1.85, 2.35 [2J(119Sn,1H) 59 Hz] (n-Pr), 8.45 [t, J(H, H) 7.5 Hz], 8.59 [d, J(H, H) 7.5 Hz], 8.72 [d, J(H, H) 7.5 Hz] (Py ring).13C NMR (CDCl3, ppm) 17.80, 19.25, 21.44 [1J(119Sn,13C) 1084 Hz] (n-Pr), 125.26, 128.19, 129.00, 145.12, 149.75 (Py ring), 190.54 (COS).119Sn NMR (CDCl3, ppm) - 191

Reference： [1]Singh, Suryabhan; Bhattacharya, Subrato [Inorganic Chemistry Communications, 2012, vol. 24, p. 144 - 147,4]

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[ 867-36-7 ] Synthesis Path-Downstream 1~50

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