Alternatived Products of [ 14064-21-2 ]
Product Details of [ 14064-21-2 ]
CAS No. : | 14064-21-2 |
MDL No. : | MFCD00010685 |
Formula : |
C7H10N2O
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
138.17
|
Pubchem ID : | - |
Synonyms : |
|
Application In Synthesis of [ 14064-21-2 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 14064-21-2 ]
- 1
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[ 4144-22-3 ]
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[ 14064-21-2 ]
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C15H21N3O3
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
In water; at 25℃; for 1.3h; |
General procedure: A) In a 10 mL round-bottom flask the maleimide (ca. 0.5 g)was dissolved in the minimum quantity of furan 6a-c (0.5-1.7 mL); H2O (3 mL) was added, and the resulting mixturewas subjected to vigorous magnetic vigorous at 25 C. Afterthe time specified in Table 1, 1H NMR spectroscopicanalysis and TLC (EtOAc-hexane, 1:1) revealed the absenceof starting materials and appearance of the respectivecycloadducts. The products either immediately precipitated,from the reaction medium or after overnight storage in therefrigerator, and were filtered and washed on the filter withcold H2O. In the case of reaction between 5b and 6b, thereaction mixture was diluted with brine (5 mL), extractedwith CH2Cl2 (3 × 5 mL), the combined extracts dried overMgSO4, filtered, and evaporated to afford an oil thatcrystallized after 24 h into the freezer. Then, the solid wascollected by filtration and washed on the filter with coldH2O.Yields were quantitative and, in all cases, analytically puresamples of each one of the adducts could be isolated bypreparative TLC. The exo adduct 7b was the only productobtained after refluxing an aqueous suspension of a mixtureof 7a and 7b for 45 min.B) Following the same procedure above, reactions werecomplete after stirring at 65 C for times specified in Table1. Then, the adducts, which precipitated in the reactionmixture, were filtered and collected as indicated above. |
- 2
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[ 2973-09-3 ]
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[ 14064-21-2 ]
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2-butyl-4-((2,2-dimethylhydrazono)methyl)isoindoline-1,3-dione
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
48% |
at 100℃; for 2h; Inert atmosphere; Microwave irradiation; Ionic liquid; Green chemistry; |
|
Reference:
[1]Karaluka, Valerija; Murata, Kengo; Masuda, Shinto; Shiramatsu, Yuto; Kawamoto, Takuji; Hailes, Helen C.; Sheppard, Tom D.; Kamimura, Akio
[RSC Advances, 2018, vol. 8, # 40, p. 22617 - 22624]
- 3
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[ 2973-17-3 ]
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[ 14064-21-2 ]
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2-allyl-4-((2,2-dimethylhydrazono)methyl)isoindoline-1,3-dione
[ No CAS ]