[ CAS No. 14024-18-1 ] {[proInfo.proName]}

Name: 14024-18-1|Iron(III) acetylacetonate|97%
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Quality Control of [ 14024-18-1 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 14024-18-1 ]

SDS Specification

Alternatived Products of [ 14024-18-1 ]

Product Details of [ 14024-18-1 ]

CAS No. :	14024-18-1	MDL No. :	MFCD00000020
Formula :	C₁₅H₂₁FeO₆	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	353.17	Pubchem ID :	-
Synonyms :

Calculated chemistry of [ 14024-18-1 ]

Physicochemical Properties

Num. heavy atoms :	22
Num. arom. heavy atoms :	0
Fraction Csp3 :	0.4
Num. rotatable bonds :	3
Num. H-bond acceptors :	6.0
Num. H-bond donors :	0.0
Molar Refractivity :	76.51
TPSA :	120.39 Å²

Pharmacokinetics

GI absorption :	High
BBB permeant :	No
P-gp substrate :	No
CYP1A2 inhibitor :	No
CYP2C19 inhibitor :	Yes
CYP2C9 inhibitor :	No
CYP2D6 inhibitor :	No
CYP3A4 inhibitor :	No
Log Kp (skin permeation) :	-6.84 cm/s

Lipophilicity

Log Po/w (iLOGP) :	0.0
Log Po/w (XLOGP3) :	2.27
Log Po/w (WLOGP) :	2.73
Log Po/w (MLOGP) :	-0.7
Log Po/w (SILICOS-IT) :	0.19
Consensus Log Po/w :	0.9

Druglikeness

Lipinski :	0.0
Ghose :	None
Veber :	0.0
Egan :	0.0
Muegge :	0.0
Bioavailability Score :	0.56

Water Solubility

Log S (ESOL) :	-3.26
Solubility :	0.193 mg/ml ; 0.000547 mol/l
Class :	Soluble
Log S (Ali) :	-4.43
Solubility :	0.013 mg/ml ; 0.0000367 mol/l
Class :	Moderately soluble
Log S (SILICOS-IT) :	-0.04
Solubility :	323.0 mg/ml ; 0.914 mol/l
Class :	Soluble

Medicinal Chemistry

PAINS :	0.0 alert
Brenk :	3.0 alert
Leadlikeness :	1.0
Synthetic accessibility :	2.99

Safety of [ 14024-18-1 ]

Signal Word:	Warning	Class:	N/A
Precautionary Statements:	P501-P270-P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313-P301+P312+P330	UN#:	N/A
Hazard Statements:	H302-H315-H319	Packing Group:	N/A
GHS Pictogram:

Application In Synthesis of [ 14024-18-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 14024-18-1 ]
Downstream synthetic route of [ 14024-18-1 ]

[ 14024-18-1 ] Synthesis Path-Upstream 1~17

1
[ 123-54-6 ]
[ 14024-18-1 ]

Yield	Reaction Conditions	Operation in experiment
73%	for 0.5 h;	General procedure: A metal solution of 0.15 mmol Fe(NO3)3 9H2O, was buffered with 0.45 mmol CH3COONa*3H2O (dissolved in 10 ml water). Ethanol was added to this solution, to produce an 1:1 volume ratio water:ethanol solution. 0.53 mmol of the relevant β-diketone was added [if the β-diketone was a liquid (Htfaa and Hhfaa), it was added as is, while the solid β-diketone (Hacac and Hdbm) was dissolved in 10 ml dichloromethane (DCM), before addition]. The resulting solution was stirred for 30 min, and left to stand overnight (in a fume hood), allowing slow evaporation of the solvent. The precipitate was collected by filtration and washing with water.

Reference： [1] Polyhedron, 2014, vol. 79, p. 52 - 59

2
[ 7705-08-0 ]
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983, p. 839 - 840
[2] Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 2000, vol. 30, p. 1236 - 1264[3] Synth. React. Inorg. Met.-Org. Chem.,
[4] Liebigs Annalen der Chemie, 1902, vol. 323, p. 13 - 13
[5] Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1887, vol. 105, p. 870
[6] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,
[7] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,

3
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Patent: US2004/127690, 2004, A1, . Location in patent: Page/Page column 5

4
[ 7439-89-6 ]
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2007, vol. 37, # 10, p. 813 - 815

5
[ 19393-11-4 ]
[ 14024-18-1 ]

Reference： [1] Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1988, vol. 33, p. 1459 - 1464[2] Zhurnal Neorganicheskoi Khimii, 1988, vol. 33, p. 2547 - 2554

6
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Journal of Physics and Chemistry of Solids, 2007, vol. 68, # 2, p. 162 - 167
[2] Journal of Alloys and Compounds, 2007, vol. 428, # 1-2, p. 322 - 326

7
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Inorganica Chimica Acta, 2003, vol. 342, p. 97 - 106

8
[ 7705-08-0 ]
[ 1118-67-8 ]
[ 14024-18-1 ]

Reference： [1] Russian Journal of Inorganic Chemistry, 2000, vol. 45, # 3, p. 328 - 331
[2] Russian Journal of Inorganic Chemistry, 2000, vol. 45, # 3, p. 328 - 331

9
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Russian Journal of Applied Chemistry, 2013, vol. 86, # 9, p. 1376 - 1382[2] Zh. Prikl. Khim. (S.-Peterburg, Russ. Fed.), 2013, vol. 86, # 9, p. 1407 - 1413,7

10
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Bulletin of the Chemical Society of Japan, 1980, vol. 53, # 2, p. 424 - 428

11
[ 13463-40-6 ]
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Sitzungsberichte der Heidelberger Akademie der Wissenschaften, Mathematisch-Naturwissenschaftliche Klasse, 1929, p. 5 - 5
[2] , Gmelin Handbook: Fe: MVol.B2, 88, page 495 - 496,
[3] Sitzungsberichte der Heidelberger Akademie der Wissenschaften, Mathematisch-Naturwissenschaftliche Klasse, 1929, p. 5 - 5
[4] Liebigs Annalen der Chemie, 1929, vol. 472, p. 275 - 275
[5] Liebigs Annalen der Chemie, 1929, vol. 472, p. 283 - 283
[6] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,

12
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1899, vol. 129, p. 303 - 303
[2] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,
[3] Dalton Transactions, 2016, vol. 45, # 19, p. 8278 - 8283

13
[ 7705-08-0 ]
[ 14024-18-1 ]

Reference： [1] Journal of the Chemical Society, 1928, p. 565
[2] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,

14
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Chemistry Letters, 1983, p. 1669 - 1672

15
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Inorganic Chemistry, 2013, vol. 52, # 14, p. 8218 - 8227

16
[ 7439-89-6 ]
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Sitzungsberichte der Heidelberger Akademie der Wissenschaften, Mathematisch-Naturwissenschaftliche Klasse, 1929, p. 6 - 6
[2] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,

17
[ 13463-40-6 ]
[ 123-54-6 ]
[ 14024-18-1 ]

Reference： [1] Liebigs Annalen der Chemie, 1929, vol. 472, p. 275 - 275
[2] , Gmelin Handbook: Fe: MVol.B3, 22, page 554 - 556,

[ 14024-18-1 ] Synthesis Path-Downstream 1~53

1
[ 14024-18-1 ]
[ 14024-58-9 ]
zinc bis(2,4-pentanedionate) monohydrate [ No CAS ]
Mn(1-x)Zn(x)Fe₂O₄ x:0-1; [ No CAS ]

Reference： [1]Itoh, Hideaki; Yamaguchi, Hirofumi; Naka, Shigeharu [Nippon Kagaku Kaishi/Journal of the Chemical Society of Japan][Nippon Kagaku Kaishi, 1987, vol. 62, p. 2004 - 2005]

2
[ 14024-18-1 ]
[ 14024-58-9 ]
manganese ferrite [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In neat (no solvent, solid phase) thermal decompn. of mixt. in air, at heating rate of 10°C/min, held 1 min at 500°C, quickly cooled (20°C/min); elem. anal., detd. by XRD, TGA;
	With oleylamine; oleic acid; 1,2-octanediol In diphenylether Mn complex, Co complex, oleylamine, oleic acid, 1,2-octanediol, diphenylether were mixed and vigorously stirred under flow of N2; mixt. heated to 578 K; refluxed for 2 h; EtOH added; centrifuged (7000 rpm for 10 min);

Reference： [1]Antic, Bratislav; Kremenović, Aleksandar; Nikolic, Aleksandar S.; Stoiljkovic, Milovan [Journal of Physical Chemistry B, 2004, vol. 108, # 34, p. 12646 - 12651]
[2]Arelaro; Lima Jr.; Rossi; Kiyohara; Rechenberg [Journal of Magnetism and Magnetic Materials, 2008, vol. 320, # 14, p. e335-e338]

3
[ 14024-18-1 ]
[ 22306-37-2 ]
bismuth ferrite [ No CAS ]

Reference： [1]Journal of Magnetism and Magnetic Materials,2004,vol. 283,p. 415 - 421
[2]Journal of Magnetism and Magnetic Materials,2008,vol. 320,p. 2215 - 2220
[3]Inorganic Materials,2011,vol. 47,p. 1029 - 1032

4
[ 14024-63-6 ]
[ 14024-18-1 ]
zinc ferrite [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2004,vol. 108,p. 12646 - 12651

5
[ 14024-18-1 ]
[ 499-44-5 ]
[ 31396-80-2 ]

Reference： [1]Bulletin of the Chemical Society of Japan,1985,vol. 58,p. 1125 - 1129

6
[ 14024-18-1 ]
[ 201230-82-2 ]
[ 67533-12-4 ]
[ 220024-66-8 ]

Yield	Reaction Conditions	Operation in experiment
72%	In acetonitrile (N2); using Schlenk techniques; stirring of Fe(acac)3 and Et4NOAc*4H2O in MeCN under CO; addn. of N(CH2CH2SH)3 in MeCN; absorbtion of CO for 20 min; filtration, washing of residue with MeCN, addn. of ether, crystn. overnight, filtration, washing with ether, drying in vac.; elem. anal.;

Reference： [1]Davies, Sian C.; Durrant, Marcus C.; Hughes, David L.; Richards, Raymond L.; Roger Sanders [Journal of the Chemical Society, Dalton Transactions, 2000, # 24, p. 4694 - 4701]

7
[ 14024-18-1 ]
[ 4201-86-9 ]
[ 10581-12-1 ]
[ 75-05-8 ]
[(CH₃)4N]⁽¹⁺⁾*4Fe⁽²⁺⁾*3(N(CH₂CH₂S)3)^(3-)*CH₃CN=[(CH₃)4N][Fe₄(N(CH₂CH₂S)3)3]*CH₃CN [ No CAS ]

Reference： [1]Journal of the Chemical Society, Dalton Transactions,2000,p. 4694 - 4701

8
[ 14024-18-1 ]
[ 4201-86-9 ]
[ 67533-12-4 ]
[ 75-05-8 ]
[(C₂H₅)4N]⁽¹⁺⁾*4Fe⁽²⁺⁾*3(N(CH₂CH₂S)3)^(3-)*CH₃CN=[(C₂H₅)4N][Fe₄(N(CH₂CH₂S)3)3]*CH₃CN [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
24%	In acetonitrile (N2); using Schlenk techniques; reflux of Fe(acac)3 and Et4NOAc*4H2O in MeCN; addn. of N(CH2CH2SH)3 in MeCN, reflux for 20 min; hot filtration; cooling overnight, crystn., filtration, washing with MeCN and ether, drying in vac., elem. anal.;

Reference： [1]Davies, Sian C.; Durrant, Marcus C.; Hughes, David L.; Richards, Raymond L.; Roger Sanders [Journal of the Chemical Society, Dalton Transactions, 2000, # 24, p. 4694 - 4701]

9
[ 14024-18-1 ]
tetrabutylammonium octamolybdate [ No CAS ]
[ 75-05-8 ]
[ 126-11-4 ]
3(C₄H₉)4N⁽¹⁺⁾*FeMo₆O₁₈((OCH₂)3CNO₂)2^(3-)*CH₃CN=((C₄H₉)4N)3FeMo₆O₁₈((OCH₂)3CNO₂)2*CH₃CN [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
35%	In acetonitrile (Bu4N)4Mo8O26, 1.5 equiv. of metal salt and 3 equiv. of alc. were refluxed overnight (ca. 17 h), soln. was filtered, Et2O was diffunded into thesoln., solid was washed with ether, air-dried, recrystd. from DMF/ether; elem. anal.;

Reference： [1]Hasenknopf, Bernold; Delmont, Renaud; Herson, Patrick; Gouzerh, Pierre [European Journal of Inorganic Chemistry, 2002, # 5, p. 1081 - 1087]

10
[ 14024-18-1 ]
[ 56-34-8 ]
[ 213127-45-8 ]
potassium hydroxide [ No CAS ]
5K⁽¹⁺⁾*7(C₂H₅)4N⁽¹⁺⁾*Fe₄((C₆H₃(O)2CONH)2C₁₀H₆)6^(12-)*4H₂O=K₅((C₂H₅)4N)7Fe₄((C₆H₃O₂CONH)2C₁₀H₆)6*4H₂O [ No CAS ]

Reference： [1]Journal of the American Chemical Society,2001,vol. 123,p. 8923 - 8938

11
[ 14024-18-1 ]
[ 685498-28-6 ]
[ 4201-86-9 ]
[ 67533-12-4 ]
[ 75-05-8 ]
[ 374689-22-2 ]

Yield	Reaction Conditions	Operation in experiment
38%	In acetonitrile (N2); Fe complex, Et4NOAc*4H2O and MeNC stirred in MeCN for minutes, N(C2H4SH)3/MeCN added, reacted for 1 h; filtered, MeCN and ether added as a layer, crystd. for 3 d, filtered off, washed (MeCN/ether, then ether), dried (vac.); elem. anal.;

Reference： [1]Cooper; Davies; Dilworth; Hughes; Konkol; Richards; Sanders; Sobota [Canadian Journal of Chemistry, 2001, vol. 79, # 5-6, p. 490 - 494]

12
[ 14024-63-6 ]
[ 14024-18-1 ]
[ 14024-58-9 ]
Zn_0.70Mn_0.23Fe_1.89O₄ [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2004,vol. 108,p. 12646 - 12651

13
[ 14024-63-6 ]
[ 14024-18-1 ]
[ 14024-58-9 ]
Zn_0.41Mn_0.50Fe_1.84O₄ [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2004,vol. 108,p. 12646 - 12651

14
[ 14024-63-6 ]
[ 14024-18-1 ]
[ 14024-58-9 ]
Zn_0.18Mn_0.67Fe_1.85O₄ [ No CAS ]

Reference： [1]Journal of Physical Chemistry B,2004,vol. 108,p. 12646 - 12651

15
[ 14024-18-1 ]
[ 813-76-3 ]
iron diethylphosphinate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
99%	In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;
99%	In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;

Reference： [1]Rosca, I.; Sutiman, D.; Cailean, A.; Vizitiu, M.; Rusu, I.; Sibiescu, D. [Thermochimica Acta, 1995, vol. 269 - 270, p. 295 - 306]
[2]Rosca, I.; Sutiman, D.; Cailean, A.; Vizitiu, M.; Rusu, I.; Sibiescu, D. [Thermochimica Acta, 1995, vol. 269 - 270, p. 295 - 306]

16
[ 67-56-1 ]
[ 28384-96-5 ]
[ 14024-18-1 ]
potassium hydroxide [ No CAS ]
K₃[Fe(enterobactin(-6H))]*4H₂O*2(methanol) [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	In methanol a soln. of Fe complex added to a soln. of ligand, a soln. of KOH added; dried, chromd. (Sephadex LH-20, MeOH), dried (vac.); elem. anal.;

Reference： [1]Abergel, Rebecca J.; Warner, Jeffrey A.; Shuh, David K.; Raymond, Kenneth N. [Journal of the American Chemical Society, 2006, vol. 128, # 27, p. 8920 - 8931]

17
[ 28384-96-5 ]
[ 14024-18-1 ]
[Fe(enterobactin(-3H))] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
61%	In methanol a soln. of Fe complex added to a soln. of ligand; evapd., chromd. (Sephadex LH-20, MeOH), dried (vac.);

Reference： [1]Abergel, Rebecca J.; Warner, Jeffrey A.; Shuh, David K.; Raymond, Kenneth N. [Journal of the American Chemical Society, 2006, vol. 128, # 27, p. 8920 - 8931]

18
scandium(III) nitrate [ No CAS ]
[ 14024-18-1 ]
[ 22306-37-2 ]
Bi_0.7Sc_0.3FeO₃ [ No CAS ]

Reference： [1]Journal of Magnetism and Magnetic Materials,2008,vol. 320,p. 2215 - 2220

19
scandium(III) nitrate [ No CAS ]
[ 14024-18-1 ]
[ 22306-37-2 ]
BiFe_0.7Sc_0.3O₃ [ No CAS ]

Reference： [1]Journal of Magnetism and Magnetic Materials,2008,vol. 320,p. 2215 - 2220

20
[ 28384-96-5 ]
[ 14024-18-1 ]
[ 121-44-8 ]
C₃₀H₂₁FeN₃O₁₅^(3-)*3C₆H₁₆N⁽¹⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol at 20℃; for 24h;

Reference： [1]Baramov, Todor; Keijzer, Karlijn; Irran, Elisabeth; Moesker, Eva; Baik, Mu-Hyun; Suessmuth, Roderich [Chemistry - A European Journal, 2013, vol. 19, # 32, p. 10536 - 10542]

21
[ 30652-11-0 ]
[ 14024-18-1 ]
Fe⁽³⁺⁾*3C₅H₂N(CH₃)2O₂^(1-)=Fe(C₅H₂N(CH₃)2O₂)3 [ No CAS ]

Reference： [1]Chemical Communications,2013,vol. 49,p. 11260 - 11262

22
[ 14024-18-1 ]
[ 15280-58-7 ]
[ 14284-89-0 ]
YbFe_0.8Mn_0.2O₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: h-YbFe1-xMexO3 was prepared by the solvothermal (ST) method. Ytterbium acetatetetrahydrate (Yb(OAc)3•4H2O, Wako), tris(acetylacetonato)iron (Fe(acac)3, Dojin) and transition metal acetylacetonates (Me(acac)n; Me = Mn, Ni, Co and Cu) were used without further purification. Yb(OAc)3•4H2O(15 mmol), and Fe(acac)3, and Me(acac)n (Fe + Me; 15mmol) were suspended with the aid of ultrasonication in 120 mL of 1,4-butanediol (1,4-BG)in a test tube serving as an autoclave liner. The test tube was placed in a 300-mL autoclave. An additional 30 mL of 1,4-BG was placed in the gap between the autoclave wall and the test tube. The autoclave was purged with nitrogen, heated to 315 C at a rate of 2.3 C min-1 and kept at that temperature for 2 h. After the assembly was cooled to room temperature, the resulting product was centrifuged. To the sedimented part of the product, methanol was added. The mixture was stirred to peptize the colloidal particles, and then centrifuged saving the supernatant. This procedure was repeated for several times, finally discarding the sediment. All the supernatant parts were gathered together, and a small amount (30 mL) of the concentrated aqueous ammonia solution (28 %) was added to coagulate the particles. The product was repeatedly washed with methanol and dried in air. The ceramic yield of the product was ~80 % for the charged ratio of x = 0 and 0.2, and >40 % for the charged ratio x≥0.4. The catalysts were obtained by the calcination of the product at 500 C for 30 min and aredesignated h-YbFe1-xMexO3 (ST), in which nominal composition was described.

Reference： [1]Chemistry Letters,2014,vol. 43,p. 874 - 876

23
[ 14024-18-1 ]
[ 15280-58-7 ]
[ 14284-89-0 ]
YbFe_0.6Mn_0.4O₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: h-YbFe1-xMexO3 was prepared by the solvothermal (ST) method. Ytterbium acetatetetrahydrate (Yb(OAc)3•4H2O, Wako), tris(acetylacetonato)iron (Fe(acac)3, Dojin) and transition metal acetylacetonates (Me(acac)n; Me = Mn, Ni, Co and Cu) were used without further purification. Yb(OAc)3•4H2O(15 mmol), and Fe(acac)3, and Me(acac)n (Fe + Me; 15mmol) were suspended with the aid of ultrasonication in 120 mL of 1,4-butanediol (1,4-BG)in a test tube serving as an autoclave liner. The test tube was placed in a 300-mL autoclave. An additional 30 mL of 1,4-BG was placed in the gap between the autoclave wall and the test tube. The autoclave was purged with nitrogen, heated to 315 C at a rate of 2.3 C min-1 and kept at that temperature for 2 h. After the assembly was cooled to room temperature, the resulting product was centrifuged. To the sedimented part of the product, methanol was added. The mixture was stirred to peptize the colloidal particles, and then centrifuged saving the supernatant. This procedure was repeated for several times, finally discarding the sediment. All the supernatant parts were gathered together, and a small amount (30 mL) of the concentrated aqueous ammonia solution (28 %) was added to coagulate the particles. The product was repeatedly washed with methanol and dried in air. The ceramic yield of the product was ~80 % for the charged ratio of x = 0 and 0.2, and >40 % for the charged ratio x≥0.4. The catalysts were obtained by the calcination of the product at 500 C for 30 min and aredesignated h-YbFe1-xMexO3 (ST), in which nominal composition was described.

Reference： [1]Chemistry Letters,2014,vol. 43,p. 874 - 876

24
[ 14024-18-1 ]
[ 15280-58-7 ]
[ 14284-89-0 ]
YbFe_0.5Mn_0.5O₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: h-YbFe1-xMexO3 was prepared by the solvothermal (ST) method. Ytterbium acetatetetrahydrate (Yb(OAc)3•4H2O, Wako), tris(acetylacetonato)iron (Fe(acac)3, Dojin) and transition metal acetylacetonates (Me(acac)n; Me = Mn, Ni, Co and Cu) were used without further purification. Yb(OAc)3•4H2O(15 mmol), and Fe(acac)3, and Me(acac)n (Fe + Me; 15mmol) were suspended with the aid of ultrasonication in 120 mL of 1,4-butanediol (1,4-BG)in a test tube serving as an autoclave liner. The test tube was placed in a 300-mL autoclave. An additional 30 mL of 1,4-BG was placed in the gap between the autoclave wall and the test tube. The autoclave was purged with nitrogen, heated to 315 C at a rate of 2.3 C min-1 and kept at that temperature for 2 h. After the assembly was cooled to room temperature, the resulting product was centrifuged. To the sedimented part of the product, methanol was added. The mixture was stirred to peptize the colloidal particles, and then centrifuged saving the supernatant. This procedure was repeated for several times, finally discarding the sediment. All the supernatant parts were gathered together, and a small amount (30 mL) of the concentrated aqueous ammonia solution (28 %) was added to coagulate the particles. The product was repeatedly washed with methanol and dried in air. The ceramic yield of the product was ~80 % for the charged ratio of x = 0 and 0.2, and >40 % for the charged ratio x≥0.4. The catalysts were obtained by the calcination of the product at 500 C for 30 min and aredesignated h-YbFe1-xMexO3 (ST), in which nominal composition was described.

Reference： [1]Chemistry Letters,2014,vol. 43,p. 874 - 876

25
[ 14024-18-1 ]
[ 15280-58-7 ]
[ 14284-89-0 ]
YbFe_0.4Mn_0.6O₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: h-YbFe1-xMexO3 was prepared by the solvothermal (ST) method. Ytterbium acetatetetrahydrate (Yb(OAc)3•4H2O, Wako), tris(acetylacetonato)iron (Fe(acac)3, Dojin) and transition metal acetylacetonates (Me(acac)n; Me = Mn, Ni, Co and Cu) were used without further purification. Yb(OAc)3•4H2O(15 mmol), and Fe(acac)3, and Me(acac)n (Fe + Me; 15mmol) were suspended with the aid of ultrasonication in 120 mL of 1,4-butanediol (1,4-BG)in a test tube serving as an autoclave liner. The test tube was placed in a 300-mL autoclave. An additional 30 mL of 1,4-BG was placed in the gap between the autoclave wall and the test tube. The autoclave was purged with nitrogen, heated to 315 C at a rate of 2.3 C min-1 and kept at that temperature for 2 h. After the assembly was cooled to room temperature, the resulting product was centrifuged. To the sedimented part of the product, methanol was added. The mixture was stirred to peptize the colloidal particles, and then centrifuged saving the supernatant. This procedure was repeated for several times, finally discarding the sediment. All the supernatant parts were gathered together, and a small amount (30 mL) of the concentrated aqueous ammonia solution (28 %) was added to coagulate the particles. The product was repeatedly washed with methanol and dried in air. The ceramic yield of the product was ~80 % for the charged ratio of x = 0 and 0.2, and >40 % for the charged ratio x≥0.4. The catalysts were obtained by the calcination of the product at 500 C for 30 min and aredesignated h-YbFe1-xMexO3 (ST), in which nominal composition was described.

Reference： [1]Chemistry Letters,2014,vol. 43,p. 874 - 876

26
[ 14024-18-1 ]
[ 244193-52-0 ]
iron(II) fluoride [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In diphenylether at 250℃; for 10h; Inert atmosphere;

Reference： [1]Dong, Bing; Zhang, Hengqiang; Kong, Aiguo; Kong, Yingying; Yang, Fan; Shan, Yongkui [European Journal of Inorganic Chemistry, 2014, vol. 2014, # 28, p. 4779 - 4787]

27
[ 14024-63-6 ]
[ 14024-18-1 ]
ZnFe₂O_3.98 [ No CAS ]

Reference： [1]RSC Advances,2015,vol. 5,p. 10267 - 10274

28
[ 14024-63-6 ]
[ 14024-18-1 ]
Zn_0.9Fe_2.1O_4.05 [ No CAS ]

Reference： [1]RSC Advances,2015,vol. 5,p. 10267 - 10274

29
[ 14024-63-6 ]
[ 14024-18-1 ]
Zn_1.2Fe_1.8O_3.9 [ No CAS ]

Reference： [1]RSC Advances,2015,vol. 5,p. 10267 - 10274

30
[ 14024-63-6 ]
[ 14024-18-1 ]
Zn_0.9Fe_2.1O_3.95 [ No CAS ]

Reference： [1]RSC Advances,2015,vol. 5,p. 10267 - 10274

31
[ 20237-92-7 ]
[ 14024-18-1 ]
[iron(III)(acetylacetonato)(2-(2'-hydroxyphenyl)oxazoline)2] [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
75%	In ethanol at 20℃; for 4h;	To a solution of Fe(acac)3 (0.353 g, 1.00 mmol) in ethanol (15 mL) was added a solution of 2-(2'-hydroxyphenyl)oxazoline and (0.326 g, 2.00 mmol) of the ethanol (10 mL). After stirring at room temperature for 4 h, the solution was filtered and evaporated under reduced pressure to give a precipitate. Recrystallization from acetonitrile yielded the complex as dark brown crystals. Yield: 0.361 g, 75 %. Anal. Calcd for C23H23FeN2O6: C, 57.6;H, 4.8; N, 5.8. Found: C, 57.5; H, 4.8; N, 5.9 %. Selected IR frequency (KBr disk, cm-1): 1611 (mC=N); KM (X-1cm2 mol-1): 11.5.

Reference： [1]Amini, Mojtaba; Khaksar, Mostafa; Arab, Ali; Jahandizi, Reza Masoomi; Bagherzadeh, Mojtaba; Boghaei, Davar M.; Ellern, Arkady; Keith Woo [Transition Metal Chemistry, 2016, vol. 41, # 1, p. 97 - 105]

32
[ 14024-63-6 ]
[ 14024-18-1 ]
Fe_0.6Zn_0.4Fe₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With cis-Octadecenoic acid; dibenzyl ether; for 0.5h;Schlenk technique; Inert atmosphere; Reflux;	In this case, the synthesis of Fe0.6Zn0.4Fe2O4 nanoclusters was areform of a previously described method[25,26]. In a typical experiment for synthesis of Fe-Zn ferrite, Fe(III) acetylacetonate (2.60 mmol), and Zn(II) acetylacetonate (0.40 mmol) were mixedwith benzyl ether (30 mL) and oleic acid (1.7 mL, 4.00 mmol) in a 250 mL three-neck flask to form a homogeneous solution. The flask was evacuated three times using a vacuum Schlenk line andrefilled with nitrogen. Then, this mixture was heated to 110C and degassed at this temperature for 1 h. With change in the amountof solvent, the size of magnetic nanoparticles can be changed, so, in this article 3 batches include 10 mL (F1), 20 mL (F2) and 30 mL(F3) of benzyl ether were used. The solution was heated to the reflux temperature of the solution at the rate of 20C/min with vigorous magnetic stirring. The reaction mixture was maintained at this temperature for 30 min. After refluxing, the solution was cooled to the room temperature, and a mixture of toluene (40 ml)and hexane (10 ml) was added to the solution. Using the magneticdecantation technique, magnetic nanoclusters were separated and washed three times by a mixture of chloroform/methane and redispersed in chloroform (or left to dry overnight for the case of the magnetic and structural characterization measurements).

Reference： [1]Journal of Magnetism and Magnetic Materials,2016,vol. 412,p. 107 - 113

33
[ 14024-63-6 ]
[ 14024-18-1 ]
zinc ferrite [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: The starting materials were nickel (II), zinc (II)and iron (III) acetylacetonate with the mole ratio of Ni:Zn:Fe=1-x:x:2.Each mixture was dissolved together with oleic acid of 6 mmol, oleylamineof 6 mmol and 1,2-Hexadecanediol in benzyl ether of 40 ml intoa 3-necked spherical flask and mechanically stirred under argon flow.The solution was heated up to 200 C and kept at this temperature for30 min. It was reheated to 298 C and maintained at that temperaturefor 1 h. Next, the temperature was decreased to 200 C for 30 min, inorder to disperse the nanoparticles. Then, the solution was cooled downto room temperature, and ethanol of 40 ml was added. After that, thenanoparticles were separated by centrifugation, and washed severaltimes with hexane and ethanol. Powders were obtained from the vacuumdried oven for overnight. The prepared nanoparticles weretreated with plasma for 30 min.

Reference： [1]Catalysis science and technology,2016,vol. 6,p. 2296 - 2304
[2]Journal of Magnetism and Magnetic Materials,2019,vol. 484,p. 14 - 20

34
[ 14024-63-6 ]
[ 14024-18-1 ]
potassium hydroxide [ No CAS ]
zinc ferrite [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In ethanol; water; ethylene glycol; at 200℃; for 0.333333h;Microwave irradiation;	Solutions of 1 mmol of Zn(acac)2 and 2 mmol of Fe(acac)3 in 25 ml of ethanol was dissolved in 20 mL of Ethylene glycol with constant stirring for 20min. Then KOH (0.178 M in 2 ml of water) was added into the above mixed solution. After further stirring for 5 min, the reaction mixture was put into a CEM microwave synthesizer to irradiate for 20 min with the power set at 250W, Temperature at 200 C and Pressure 200 C. After completion of reaction, the black precipitate was collected by centrifugation, washed twice with deionized water, ethanol, acetone and dried in vacuum oven at 60C for 5h.

Reference： [1]Tetrahedron Letters,2016,vol. 57,p. 4046 - 4049

35
[ 14024-18-1 ]
[ 14024-58-9 ]
manganese(II) ferrite [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	With lauric acid; n-Dodecylamine for 1h; Inert atmosphere;	2.2. Synthesis of Magnetic Nanovectors First, monodispersed manganese ferrite (MnFe2O4) MNPs were synthesized by thermal decomposition of metal-organic precursors in the presence of nonpolarorganic solvents.43 44 In detail, iron(III) acetylacetonate(2 mmol), manganese(II) acetylacetonate (1 mmol),1,2-hexadecanediol (10 mmol), lauric acid (6 mmol), andlaurylamine (6 mmol) were dissolved in 20 mL of benzylether. The solution was preheated to 200 C for 2 hunder an ambient nitrogen atmosphere and refluxed at300 C for 1 h. After cooling the reactants to room temperature,the products were purified using an excess ofpure ethanol. Approximately 11-nm MNPs were synthesizedusing the seed-mediated growth method.45 46 Thereafter,nitrosyl tetrafluoroborate (NOBF4) dispersed in DMF(1 mL) was added to MNPs (1 mg) dispersed in hexane(1 mL), and the mixture was shaken for 10 min. Afterevaporating hexane, 1 mL of acetone was added and thesolution was centrifuged at 4,000 rpm for 15 min.The precipitated MNPs were dispersed in ultra-purewater containing PEG-SH and miRNA-34a (1:1 molarratio), and this mixture was sonicated to create miRNAmodifiedMNPs with high colloidal stability.47 ControlmiRNA-modified MNPs (control nanovectors) were preparedin the same manner.

Reference： [1]Lee, Hwunjae; Kim, Hyun-Ouk; Son, Hye-Young; Lee, Sang-Bock; Jang, Eunji; Kang, Byunghoon; Haam, Seungjoo; Lim, Eun-Kyung; Huh, Yong-Min [Journal of Nanoscience and Nanotechnology, 2016, vol. 16, # 12, p. 12939 - 12946]

36
[ 28384-96-5 ]
[ 14024-18-1 ]
enantioenterobactin [ No CAS ]
potassium hydroxide [ No CAS ]
3K⁽¹⁺⁾*Fe((C₆H₃O₂C(O)NH)3C₉H₉O₆)^(3-)=K₃FeC₃₀H₂₁N₃O₁₅ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In methanol

Reference： [1]Johnstone, Timothy C.; Nolan, Elizabeth M. [Journal of the American Chemical Society, 2017, vol. 139, # 42, p. 15245 - 15250]

37
bis(acetylacetonate)nickel(II) [ No CAS ]
[ 14024-63-6 ]
[ 14024-18-1 ]
Ni_0.75Zn_0.25Fe₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: The starting materials were nickel (II), zinc (II)and iron (III) acetylacetonate with the mole ratio of Ni:Zn:Fe=1-x:x:2.Each mixture was dissolved together with oleic acid of 6 mmol, oleylamineof 6 mmol and 1,2-Hexadecanediol in benzyl ether of 40 ml intoa 3-necked spherical flask and mechanically stirred under argon flow.The solution was heated up to 200 C and kept at this temperature for30 min. It was reheated to 298 C and maintained at that temperaturefor 1 h. Next, the temperature was decreased to 200 C for 30 min, inorder to disperse the nanoparticles. Then, the solution was cooled downto room temperature, and ethanol of 40 ml was added. After that, thenanoparticles were separated by centrifugation, and washed severaltimes with hexane and ethanol. Powders were obtained from the vacuumdried oven for overnight. The prepared nanoparticles weretreated with plasma for 30 min.

Reference： [1]Journal of Magnetism and Magnetic Materials,2019,vol. 484,p. 14 - 20

38
bis(acetylacetonate)nickel(II) [ No CAS ]
[ 14024-63-6 ]
[ 14024-18-1 ]
nickel zinc ferrite [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: The starting materials were nickel (II), zinc (II)and iron (III) acetylacetonate with the mole ratio of Ni:Zn:Fe=1-x:x:2.Each mixture was dissolved together with oleic acid of 6 mmol, oleylamineof 6 mmol and 1,2-Hexadecanediol in benzyl ether of 40 ml intoa 3-necked spherical flask and mechanically stirred under argon flow.The solution was heated up to 200 C and kept at this temperature for30 min. It was reheated to 298 C and maintained at that temperaturefor 1 h. Next, the temperature was decreased to 200 C for 30 min, inorder to disperse the nanoparticles. Then, the solution was cooled downto room temperature, and ethanol of 40 ml was added. After that, thenanoparticles were separated by centrifugation, and washed severaltimes with hexane and ethanol. Powders were obtained from the vacuumdried oven for overnight. The prepared nanoparticles weretreated with plasma for 30 min.

Reference： [1]Journal of Magnetism and Magnetic Materials,2019,vol. 484,p. 14 - 20

39
bis(acetylacetonate)nickel(II) [ No CAS ]
[ 14024-63-6 ]
[ 14024-18-1 ]
Ni_0.25Zn_0.75Fe₂O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		General procedure: The starting materials were nickel (II), zinc (II)and iron (III) acetylacetonate with the mole ratio of Ni:Zn:Fe=1-x:x:2.Each mixture was dissolved together with oleic acid of 6 mmol, oleylamineof 6 mmol and 1,2-Hexadecanediol in benzyl ether of 40 ml intoa 3-necked spherical flask and mechanically stirred under argon flow.The solution was heated up to 200 C and kept at this temperature for30 min. It was reheated to 298 C and maintained at that temperaturefor 1 h. Next, the temperature was decreased to 200 C for 30 min, inorder to disperse the nanoparticles. Then, the solution was cooled downto room temperature, and ethanol of 40 ml was added. After that, thenanoparticles were separated by centrifugation, and washed severaltimes with hexane and ethanol. Powders were obtained from the vacuumdried oven for overnight. The prepared nanoparticles weretreated with plasma for 30 min.

Reference： [1]Journal of Magnetism and Magnetic Materials,2019,vol. 484,p. 14 - 20

40
[ 110-89-4 ]
[ 89-73-6 ]
[ 14024-18-1 ]
terbium nitrate monohydrate [ No CAS ]
(piperidinium)₃[Fe₆Tb(salicylhydroxamate)₉]*1.5(piperidine)*xH₂O [ No CAS ]

Reference： [1]Dalton Transactions,2019,vol. 48,p. 4779 - 4783

41
[ 110-89-4 ]
[ 89-73-6 ]
[ 14024-18-1 ]
yttrium(III) nitrate monohydrate [ No CAS ]
(piperidinium)₃[Fe₆Y(salicylhydroxamate)₉]*1.5(piperidine)*xH₂O [ No CAS ]

Reference： [1]Dalton Transactions,2019,vol. 48,p. 4779 - 4783

42
[ 110-89-4 ]
[ 89-73-6 ]
[ 14024-18-1 ]
gadolinium(III) nitrate hydrate [ No CAS ]
(piperidinium)₃[Fe₆Gd(salicylhydroxamate)₉]*1.5(piperidine)*xH₂O [ No CAS ]

Reference： [1]Dalton Transactions,2019,vol. 48,p. 4779 - 4783

43
[ 110-89-4 ]
[ 89-73-6 ]
[ 14024-18-1 ]
dysprosium(III) nitrate hydrate [ No CAS ]
(piperidinium)₃[Fe₆Dy(salicylhydroxamate)₉]*1.5(piperidine)*xH₂O [ No CAS ]

Reference： [1]Dalton Transactions,2019,vol. 48,p. 4779 - 4783

44
[ 14024-18-1 ]
[ 13963-57-0 ]
Fe₂₈₅₀Al₀₁₅₀O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In benzyl alcohol; at 199.84℃; for 48.0h;Autoclave;	General procedure: Sample preparation was performed similar to the procedure given in our previous report [15]. Oxide precursors (Fe1-xAlx)3O4 were prepared from a mixture of Fe(acac)3 and Al(acac)3 in an autoclave at 473K for 48h.

Reference： [1]Journal of Alloys and Compounds,2019,vol. 789,p. 697 - 703

45
[ 14024-18-1 ]
[ 13963-57-0 ]
Al_0.6Fe_2.4O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In benzyl alcohol; at 199.84℃; for 48.0h;Autoclave;	General procedure: Sample preparation was performed similar to the procedure given in our previous report [15]. Oxide precursors (Fe1-xAlx)3O4 were prepared from a mixture of Fe(acac)3 and Al(acac)3 in an autoclave at 473K for 48h.

Reference： [1]Journal of Alloys and Compounds,2019,vol. 789,p. 697 - 703

46
[ 14024-18-1 ]
[ 13963-57-0 ]
(Fe_0.97Al_0.03)3O₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In benzyl alcohol; at 199.84℃; for 48.0h;Autoclave;	General procedure: Sample preparation was performed similar to the procedure given in our previous report [15]. Oxide precursors (Fe1-xAlx)3O4 were prepared from a mixture of Fe(acac)3 and Al(acac)3 in an autoclave at 473K for 48h.

Reference： [1]Journal of Alloys and Compounds,2019,vol. 789,p. 697 - 703

47
[ 1762-34-1 ]
[ 14024-18-1 ]
C₂₇H₃₃FeN₂O₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
68%	In ethanol at 60℃; Inert atmosphere; Schlenk technique;	5 Example 5: Synthesis of substituted bipyridine iron complex 5. The structural formula of the substituted bipyridine trivalent iron complex 5 described in this embodiment is as follows:Under an argon atmosphere, add anhydrous Fe (acac) 3 (176.6mg, 0.5mmol) to a 50mL Schlenk bottle and dissolve it in 6mL of absolute ethanol at 60 ° C;Then, a solution of 5,5'-dimethyl-2,2'-bipyridine (92.1 mg, 0.5 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 ° C for half an hour, and then returned to room temperature and stirred overnight.The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h.To give a red-brown solid product 5, in 68% yield.
64%	In ethanol at 60℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;	4 Example 4. Preparation of a pyrimide-based iron complex catalyst 4 (the structural formula is as follows). Under an argon atmosphere, add anhydrous Fe(acac)3 (211.8mg, 0.6mmol) to a 50mL Schlenk flask, and dissolve it in 6mL of anhydrous ethanol at 60 ° C; Then, a solution of 5,5'-dimethyl-2,2'-bipyridine (110.4 mg, 0.6 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 ° C for half an hour, and then returned to room temperature and stirred overnight. The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h to obtain a red-brown solid product 4 with a yield of 64%.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN110305169, 2019, A Location in patent: Paragraph 0043-0047
[2]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN110452272, 2019, A Location in patent: Paragraph 0039; 0057-0061

48
[ 1134-35-6 ]
[ 14024-18-1 ]
C₂₇H₃₃FeN₂O₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
71%	In ethanol at 60℃; Inert atmosphere; Schlenk technique;	6 Example 6: Synthesis of substituted bipyridine trivalent iron complex 6. The structural formula of the substituted bipyridine trivalent iron complex 6 described in this embodiment is as follows:Under an argon atmosphere, add anhydrous Fe (acac) 3 (176.6mg, 0.5mmol) to a 50mL Schlenk bottle and dissolve it in 6mL of absolute ethanol at 60 ° C;A solution of 4,4'-dimethyl-2,2'-bipyridine (92.1 mg, 0.5 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 ° C for half an hour, and then returned to room temperature and stirred overnight.The filtrate was collected by filtration, concentrated, and washed twice with cold ethanol.Drying under vacuum for 12 h gave the product 6 as a yellow-brown solid with a yield of 71%.
60%	In ethanol at 60℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;	6 Example 6. Preparation of pyrimide-based iron complex catalyst 6 (the structural formula is as follows). Under an argon atmosphere, add anhydrous Fe(acac)3 (211.8mg, 0.6mmol) to a 50mL Schlenk flask, and dissolve it in 6mL of anhydrous ethanol at 60 ° C; Then, a solution of 4,4'-dimethyl-2,2'-bipyridine (110.4 mg, 0.6 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 ° C for half an hour, and then returned to room temperature and stirred overnight. The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h to obtain a red-brown solid product 6 with a yield of 60%.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN110305169, 2019, A Location in patent: Paragraph 0048-0052
[2]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN110452272, 2019, A Location in patent: Paragraph 0039; 0067-0071

49
[ 4411-80-7 ]
[ 14024-18-1 ]
C₂₇H₃₃FeN₂O₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%	In ethanol at 60℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;	8 Example 8. Preparation of a pyrimide-based iron complex catalyst 8 (the structural formula is as follows). Under an argon atmosphere, add anhydrous Fe(acac)3 (211.8mg, 0.6mmol) to a 50mL Schlenk flask, and dissolve it in 6mL of anhydrous ethanol at 60 ° C; Then, a solution of 6,6'-dimethyl-2,2'-bipyridine (110.4 mg, 0.6 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 ° C for half an hour, and then returned to room temperature and stirred overnight. The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h to obtain a red-brown solid product 8 with a yield of 80%.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN110452272, 2019, A Location in patent: Paragraph 0039; 0077-0081

50
[ 14024-18-1 ]
[ 18511-72-3 ]
C₂₅H₂₇FeN₄O₁₀ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62%	In ethanol; at 60℃;Inert atmosphere; Schlenk technique;	The structural formula of the substituted bipyridine trivalent iron complex 8 described in this embodiment is as follows:Under an argon atmosphere, add anhydrous Fe (acac) 3 (141.3mg, 0.4mmol) to a 50mL Schlenk bottle, and dissolve it in 6mL of absolute ethanol at 60 C;A solution of <strong>[18511-72-3]4,4'-dinitro-2,2'-bipyridine</strong> (98.5 mg, 0.4 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 C for half an hour, and then returned to room temperature and stirred overnight.The filtrate was collected by filtration, concentrated, and washed twice with cold ethanol.Drying under vacuum for 12 h gave reddish brown solid product 8 in 62% yield.
35%	In ethanol; at 60℃; for 0.5h;Inert atmosphere; Schlenk technique; Glovebox;	Under an argon atmosphere, add anhydrous Fe(acac)3 (211.8mg, 0.6mmol) to a 50mL Schlenk flask, and dissolve it in 6mL of anhydrous ethanol at 60 C; Then, a solution of <strong>[18511-72-3]4,4'-dinitro-2,2'-bipyridine</strong> (147.6 mg, 0.6 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 C for half an hour, and then returned to room temperature and stirred overnight. The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h to obtain dark brown solid product 12, with a yield of 35%.

Reference： [1]Patent: CN110305169,2019,A .Location in patent: Paragraph 0058-0062
[2]Patent: CN110452272,2019,A .Location in patent: Paragraph 0039; 0097-0101

51
[ 14024-18-1 ]
[ 92149-07-0 ]
C₂₉H₃₃FeN₂O₈ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
65%	In ethanol; at 60℃; for 0.5h;Inert atmosphere; Schlenk technique; Glovebox;	Under an argon atmosphere, add anhydrous Fe(acac)3 (211.8mg, 0.6mmol) to a 50mL Schlenk flask, and dissolve it in 6mL of anhydrous ethanol at 60 C; Then, a solution of <strong>[92149-07-0]4,7-dimethoxy-1,10-phenanthroline</strong> (144.0 mg, 0.6 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 C for half an hour, and then returned to room temperature and stirred overnight. The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h to obtain a red-brown solid product 8 with a yield of 65%.

Reference： [1]Patent: CN110452272,2019,A .Location in patent: Paragraph 0039; 0127-0131

52
[ 3248-05-3 ]
[ 14024-18-1 ]
C₂₉H₃₃FeN₂O₆ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
62%	In ethanol at 60℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;	20 Example 20. Preparation of a pyrimide-based iron complex catalyst 20 (the structural formula is as follows). Under an argon atmosphere, add anhydrous Fe(acac)3 (211.8mg, 0.6mmol) to a 50mL Schlenk flask, and dissolve it in 6mL of anhydrous ethanol at 60 ° C; Then, a solution of 4,7-dimethyl-1,10-phenanthroline (124.8 mg, 0.6 mmol) in ethanol (4 mL) was added dropwise to the system. The reaction was carried out at 60 ° C for half an hour, and then returned to room temperature and stirred overnight. The filtrate was collected by filtration, concentrated, washed twice with cold ethanol, and dried under vacuum for 12 h to obtain a red-brown solid product 20 with a yield of 62%.

Reference： [1]Current Patent Assignee: CHINESE ACADEMY OF SCIENCES - CN110452272, 2019, A Location in patent: Paragraph 0039; 0137-0141

53
[ 1036248-62-0 ]
[ 14024-18-1 ]
3C₁₂H₈N₄^(2-)*2Fe⁽³⁺⁾ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	In N,N-dimethyl-formamide at 150℃; for 72h; Sealed tube;

Reference： [1]Jaffe, Adam; Ziebel, Michael E.; Halat, David M.; Biggins, Naomi; Murphy, Ryan A.; Chakarawet, Khetpakorn; Reimer, Jeffrey A.; Long, Jeffrey R. [Journal of the American Chemical Society, 2020, vol. 142, # 34, p. 14627 - 14637]

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P241	Use explosion-proof electrical/ventilating/lighting/equipment.
P242	Use only non-sparking tools.
P243	Take precautionary measures against static discharge.
P244	Keep reduction valves free from grease and oil.
P250	Do not subject to grinding/shock/friction.
P251	Pressurized container: Do not pierce or burn, even after use.
P260	Do not breathe dust/fume/gas/mist/vapours/spray.
P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P262	Do not get in eyes, on skin, or on clothing.
P263	Avoid contact during pregnancy/while nursing.
P264	Wash hands thoroughly after handling.
P265	Wash skin thouroughly after handling.
P270	Do not eat, drink or smoke when using this product.
P271	Use only outdoors or in a well-ventilated area.
P272	Contaminated work clothing should not be allowed out of the workplace.
P273	Avoid release to the environment.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 14024-18-1 ] {[proInfo.proName]}

Quality Control of [ 14024-18-1 ]

Related Doc. of [ 14024-18-1 ]

Product Details of [ 14024-18-1 ]

Calculated chemistry of [ 14024-18-1 ]

Physicochemical Properties

Pharmacokinetics

Lipophilicity

Druglikeness

Water Solubility

Medicinal Chemistry

Safety of [ 14024-18-1 ]

Application In Synthesis of [ 14024-18-1 ]

[ 14024-18-1 ] Synthesis Path-Upstream 1~17

[ 14024-18-1 ] Synthesis Path-Downstream 1~53

Precautionary Statements-General

Prevention

Response

Storage

Disposal

Physical hazards

Health hazards

Environmental hazards

Inquiry