Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
{[ item.p_purity ]} | {[ item.pr_size ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]} | {[ item.pr_usastock ]} | Inquiry - | {[ item.pr_chinastock ]} | Inquiry - |
* Storage: {[proInfo.prStorage]}
CAS No. : | 131864-67-0 | MDL No. : | MFCD01321334 |
Formula : | C17H23N3O2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | CSGQGLBCAHGJDR-GJZGRUSLSA-N |
M.W : | 301.38 | Pubchem ID : | 688213 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | In acetonitrile; at 20℃; for 1h; | (R)-LiPr (50mg, 0.17mmol) was dissolved in acetonitrile (15cm3). Zinc(II) tetrafluoroborate hydrate (20mg, 0.083mmol) was then added and the solution stirred at room temperature for one hour. A large excess of diethyl ether was added and the resultant precipitate was isolated by vacuum filtration leaving a white powder. Single crystals suitable for X-ray diffraction analysis were grown by vapour diffusion of diethyl ether into a concentrated solution of the product in acetonitrile. Yield: 0.054g, 78%. Elemental microanalysis: found C, 48.4; H, 5.39; N, 10.0%: calcd for C34H46B2F8N6O4Zn C, 48.5; H, 5.51; N, 9.98%. 1H NMR (CD3CN): delta 0.52 (d, 12H, 6.7Hz, iPr CH3), 0.64 (d, 12H, 6.7Hz, iPr CH3), 1.40 (dq, 4H, 13.4, 6.7Hz, iPr CH), 3.89 (ddd, 4H, 10.0, 8.7, 6.6Hz, ox-H), 4.67 (t, 4H, 8.9Hz, ox-H), 4.97 (t, 4H, 9.7Hz, ox-H), 8.41 (d, 4H, 7.9Hz, Py H3/5), 8.66 (t, 2H, 7.9Hz, Py H4). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86% | In acetonitrile; at 20℃; for 1h; | General procedure: (R)-LiPr (50mg, 0.17mmol) was dissolved in acetonitrile (15cm3). Zinc(II) tetrafluoroborate hydrate (20mg, 0.083mmol) was then added and the solution stirred at room temperature for one hour. A large excess of diethyl ether was added and the resultant precipitate was isolated by vacuum filtration leaving a white powder. Single crystals suitable for X-ray diffraction analysis were grown by vapour diffusion of diethyl ether into a concentrated solution of the product in acetonitrile. Yield: 0.054g, 78%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
78% | In acetonitrile; at 20℃; for 1h; | General procedure: (R)-LiPr (50mg, 0.17mmol) was dissolved in acetonitrile (15cm3). Zinc(II) tetrafluoroborate hydrate (20mg, 0.083mmol) was then added and the solution stirred at room temperature for one hour. A large excess of diethyl ether was added and the resultant precipitate was isolated by vacuum filtration leaving a white powder. Single crystals suitable for X-ray diffraction analysis were grown by vapour diffusion of diethyl ether into a concentrated solution of the product in acetonitrile. Yield: 0.054g, 78%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86% | In acetonitrile; at 20℃; for 1h; | General procedure: (R)-LiPr (50mg, 0.17mmol) was dissolved in acetonitrile (15cm3). Zinc(II) tetrafluoroborate hydrate (20mg, 0.083mmol) was then added and the solution stirred at room temperature for one hour. A large excess of diethyl ether was added and the resultant precipitate was isolated by vacuum filtration leaving a white powder. Single crystals suitable for X-ray diffraction analysis were grown by vapour diffusion of diethyl ether into a concentrated solution of the product in acetonitrile. Yield: 0.054g, 78%. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
59% | In acetonitrile at 20℃; for 2h; |